• 대한화학회지
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• 제58권1호
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• pp.76-79
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• 2014

Petroleum refinery effluents are waste originating from industries primarily engaged in refining crude oil. It is a very complex compound of various oily wastes, water, heavy metals and so on. Conventional processes are unable to effectively remove the chemical oxygen demand (COD) of petroleum refinery effluents. Supercritical water oxidation (SCWO) was proposed to treat petroleum refinery effluents. In this paper, methanol was used to investigate co-oxidative effect of methanol on petroleum refinery effluents treatment. The results indicated that supercritical water oxidation is an effective process for petroleum refinery effluents treatment. Adding methanol caused an increase in COD removal. When reaction temperature is $440^{\circ}C$, residence time is 20 min, OE is 0.5 and initial COD is 40000 mg/L, and COD removal increases 8.5%.

• 한국환경과학회지
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• 제13권7호
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• pp.703-710
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• 2004

Petroleum refineries have been considered as an important emission source for atmospheric volatile hazardous air pollutants(HAPs). The emission source includes petroleum refinery processes and process equipment. The control strategy for volatile HAPs requires emission estimations of these pollutants. However, systematic methods of volatile HAPs emission from petroleum refineries have not yet been established. Accordingly, present study surveyed the estimation method of volatile HAPs emitted from the petroleum refinery processes and process equipment. The emission estimation methods for the petroleum refinery processes are applied for 11 petroleum refining facilities: fluidized catalytic cracking, thermal cracking, moving bed catalytic cracking, compressed engine, blowdown system, vacuum distilled column condensator, natural gas or distilled boiler, natural gas or distilled heater, oil boiler, oil heater and flare. Four emission estimation methods applied for the petroleum refinery process equipment are as follows: average emission factor approach, screening ranges approach, EPA correlation approach and unit-specific correlation approach. The process equipment for which emission factors are available are valves, pump seals, connectors, flanges and open-ended lines.

• 한국산업보건학회지
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• 제15권1호
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• pp.27-35
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• 2005

This study was carried out to evaluate the characteristics of petroleum refinery workers' exposure to organic solvents. Exposure assessment was conducted by full shift-based long term personal sampling(TWA-P) and task-based short term personal sampling(STEL-P) strategy. Major organic solvents that workers can be exposed are various, varying from C3~C12, and this study focused on 11 kinds including benzene, considering toxicity and concentration level. In comparison with two sampling results, STEL-P shows a significant(p<0.001) excess of exposure level rather than TWA-P. As the potential risk index for benzene is calculated as 16, benzene should be set the highest priority for control in petroleum refinery industry. The tasks with the highest benzene exposure level were de-watering(AM;99.8 ppm), draining(AM;19.6ppm), sampling(AM;16.2ppm), and manual gauging(AM;15.02ppm). Petroleum refinery workers' exposure pattern to organic solvents differs by tasks performed, and some task has a high risk of temporary extreme exposure. Therefore, traditional 8-hour TWA sampling strategy have possibility of underestimation of exposure level of workers in petroleum refinery.

• Asian Journal of Atmospheric Environment
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• 제11권4호
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• pp.254-269
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• 2017

The work describes an assessment of the major air pollutants, $NO_2$, $SO_2$, CO, $O_3$, $NH_3$, coarse and fine particulate matter ($PM_{10}$, $PM_{2.5}$) in ambient air in and around a 3 million tonne Petroleum Refinery and the possible impacts on a pristine area marked by the presence of the world-famous Kajiranga National Park, a world heritage site and habitat for the most number of one-horned rhinos in the world. The Refinery is at an aerial distance of 20-25 km from the wildlife habitat. The assessment is based on regular monitoring at four stations around the Refinery and one station near the National Park. Heavy rains during June to August influence the pollutant concentrations while at other times of the year, large traffic volume adds to the pollutant concentrations that peak during November to March, the dry months of the year. Correlation analysis by scatter technique is utilised to obtain the enhancement ratios to predict the variations in the concentrations of the pollutants and their spatial distribution. Computation of air quality index (AQI) indicates that the coarse and the fine particulates in the ambient air could be a major hazard to wildlife in the area.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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• pp.255-257
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• 2014

The installation of light oil facilities or delayed cokers seems to be inevitable in the oil refinery industry due to the heavy crude oil reserves and the increased use of light fuels as petroleum products. Petroleum coke is a byproduct of oil refineries and it has higher fixed carbon content, higher calorific value, and lower ash content than coal. However, its sulfur content and heavy metal content are higher than coal. In spite of disadvantages, petroleum coke might be one of promising resources due to gasification processes. The gasification of petroleum coke can improve economic value of oil refinery industries by handling cheap, toxic wastes in an environment-friendly way. In this study, $CO_2$ gasification reaction kinetics of petroleum coke, various coals and mixing coal with petroleum coke have investigated and been compared by using TGA. The kinetics of $CO_2$ gasification has been performed with petroleum coke, 3 kinds of bituminous coal [BENGALLA, White Haven, TALDINSKY], and 3 kinds of sub-bituminous coal [KPU, LG, MSJ] at various temperature[$1100-1400^{\circ}C$].

• 대한안전경영과학회지
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• 제23권2호
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• pp.19-24
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• 2021

The petroleum refinery industry handles a variety of complex chemical substances and employs a large number of people around the world. According to previous research, diseases caused by exposure to chemicals were quite common among workers in refineries until the 1980s. More recently, it is unusual for oil refinery workers to suffer from these serious diseases. The objective of this study was to identify the occurrence level of general diseases and any differences in lifestyle habits of workers in refineries in Korea compared with the general population. In this study, we used the results of health examinations from 2014 for workers at a large oil refinery in South Korea. In addition, based on the results of KNHANES from 2014 as representative of the population, hypertension, diabetes, anemia, hyperlipidemia, liver function abnormality, and kidney function abnormality were calculated using the standardized incidence rate. Hypertension showed a low result with an SIR of less than 1, but a high result in the case of abnormal liver function. The workers' occurrence rates of hypertension, hyperlipidemia, kidney dysfunction, and anemia were lower than those of ordinary salaried employees. however, their occurrence rate for abnormal liver function was markedly higher. In lifestyle habits, the smoking rate of workers was low while the alcohol consumption rate was quite high. This study has improved the understanding of the health status of workers in a large oil refinery in Korea, and has shown the impact of lifestyle habits related to the work environment on chronic diseases.

• 석유와에너지
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• 2호통권180호
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• pp.76-83
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• 1996

이 자료는 최근 하와이의 동서문화 센터가 마련한 「Asia - Pacific Refinery Balance and Product Flows to 2000」중 석유제품 품질규격 부분을 발췌한 것이다. <편집자 주>

• 자원ㆍ환경경제연구
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• 제17권2호
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• pp.381-418
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• 2008

동북아 3국(한국, 중국, 일본)의 원유시장 수급과, 원유수급에 영향을 주는 석유제품별 수급 현황을 살펴보는 것은 원유와 석유제품수급에서 발생할 수 있는 석유안보의 의미를 검토하는데 도움을 준다. 2006년 동북아 3국의 석유시장에서는 1,060만 배럴/일의 수급불균형이 발생하였고, 2030년에는 1,550~2,200만 배럴/일의 불균형이 발생할 것으로 전망되며, 이러한 수급불균형은 국가간 교역으로 해결되고 있다. 원유소비는 다양한 석유제품의 수요로 나타나는데, 2005년 중국은 경유>휘발유>연료유>LPG>나프타>등 항공유, 일본은 경유>휘발유>나프타>등 항공유>연료유>LPG, 한국은 나프타>경유>연료유>LPG>등 항공유>휘발유 순의 수요패턴을 보였다. 수요가 주어진 경우, 석유제품의 공급을 담당하는 각국의 주어진 정제시설규모는 공급 측면에서 석유제품의 수불균형에 영향을 미친다. 본 연구는 관련하여 3국의 상압증류시설과 이용률에 관해서 함께 살펴본다. 본 연구는 원유와 석유제품의 수급, 그리고 정제설비시장의 국가별 분포와 계획 등과 석유안보의 개념이 무관하지 않음을 실제 자료를 통해 평가해 보고, 석유안보 확보를 위한 다양한 방안마련에 대해 논의한다.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2007년도 추계학술대회 논문집
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• pp.324-326
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• 2007

• 한국물환경학회지
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• 제36권5호
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• pp.453-467
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• 2020

This study aimed to inventory the water pollutant discharge of wastewater from two facilities, one primary steel manufacturing facility and one petroleum refinery, both of which are located in Korea, and to identify ways to improve the wastewater treatment process through field investigation. Probability evaluation was used to inventory the substances in polluted water. The samples collected in this study included original wastewater, on processing wastewater, and treated water. The general description of wastewater occurrence, major sources, and treatment facilities were also investigated to obtain an integrated database of the pollutants created by different industrial categories. Based on our analysis of raw wastewater and final effluent, the detected pollutants were confirmed by analyzing their presence in the raw or supplemental materials, the potential of formation as byproducts, and the possibility of inclusion as impurities. The compounds detected for each category were screened via investigation of their possible sources and confirmed as the final water pollutant inventories. Thirty kinds of water pollutants were emitted by the primary steel manufacturing facility (reference in case A), including 14 specified hazardous water pollutants. The petroleum refinery (reference in case B) emitted 36 water pollutants, including 16 specified hazardous water pollutants.