• Title/Summary/Keyword: Petroleum emulsion

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Preparation and Properties of Bio-inspired Waterborne Polyurethanes Containing Different Amount of Paraffin Wax

  • Kim, Hye-Lin;Kim, Ae-Li;Lee, Young-Hee;Kim, Sung Yeol;Park, Cha-Cheol;Rahman, Mohammad Mizanur;Kim, Han-Do
    • Textile Coloration and Finishing
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    • v.30 no.1
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    • pp.9-19
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    • 2018
  • To prepare bio-inspired antifouling coating materials having similar structure with lotus, self-crosslinkable waterborne polyurethanes emulsions containing paraffin wax (CWPU/P0, 0.25, 0.5, 1.0, 1.5, 2.0, the number indicated the wt% of wax) were prepared by an emulsifier-free/solvent free prepolymer mixing process. The as-polymerized CWPU/P emulsions containing 0 - 1.00wt% of paraffin wax were found to be stable after 4 months, however, CWPU/P emulsions containing 1.50 and 2.00wt% of paraffin wax were unstable within 1 month storage. Considering the stability of emulsions, the optimum paraffin wax content was found to be about 1wt% to obtain stable antifouling coating emulsion material. The surface topology of CWPU/P film samples was characterized by atomic force microscopy (AFM). This study examined the effect of paraffin wax content on the surface roughness, water contact angle/surface energy, water swelling, light transmittance and tensile properties of CWPU/P film samples.