• Title/Summary/Keyword: Pesticide analysis

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Development, Validation, and Application of a Portable SPR Biosensor for the Direct Detection of Insecticide Residues

  • Yang, Gil-Mo;Cho, Nam-Hong
    • Food Science and Biotechnology
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    • v.17 no.5
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    • pp.1038-1046
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    • 2008
  • This study was carried out to develop a small-sized biosensor based on surface plasmon resonance (SPR) for the rapid identification of insecticide residues for food safety. The SPR biosensor module consists of a single 770 nm-light emitting diodes (LED) light source, several optical lenses for transferring light, a hemisphere sensor chip, photo detector, A/D converter, power source, and software for signal processing using a computer. Except for the computer, the size and weight of the sensor module are 150 (L)$\times$70 (W)$\times$120 (H) mm and 828 g, respectively. Validation and application procedures were designed to assess refractive index analysis, affinity properties, sensitivity, linearity, limits of detection, and robustness which includes an analysis of baseline stability and reproducibility of ligand immobilization using carbamate (carbofuran and carbaryl) and organophosphate (cadusafos, ethoprofos, and chlorpyrifos) insecticide residues. With direct binding analysis, insecticide residues were detected at less than the minimum 0.01 ppm and analyzed in less than 100 sec with a good linear relationship. Based on these results, we find that the binding interaction with active target groups in enzymes using the miniaturized SPR biosensor could detect low concentrations which satisfy the maximum residue limits for pesticide tolerance in Korea, Japan, and the USA.

Simultaneous Analysis of Pesticide Priority Pollutants in Soil (토양 중의 Pesticide Priority Pollutants 동시 분석에 관한 연구)

  • Lee, Seung-Seok;Park, Young-Joo;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.8 no.3
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    • pp.237-248
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    • 1995
  • The simultaneous analysis of 16 organic pesticides, which are listed as a part of 129 priority pollutants by EPA(Environmental Protection Agency), was performed by GC-ECD(electron capture detector) and GC/MS-SIM(selected ion monitoring). Two extraction procedures from SW-846, sonication extraction and Soxhlet extraction, were somewhat modified and compared as an extraction and concentration method for the analysis of priority pollutants in soil. Accuracy and precision of the methods were reported from the calculation of mean recovery, mean relative standard deviation, and method detection limit.

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An Analysis of Causes of the Management Inefficiency of Forest Products Farms - The Case of Jujube, Bitter Persimmon, and Chestnut Farms - (임산물 농가의 경영 비효율성 원인 분석 - 대추, 떫은감, 밤 농가를 대상으로 -)

  • Lee, Choon-Soo;Chong, Ho-Gun
    • Korean Journal of Organic Agriculture
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    • v.31 no.4
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    • pp.357-380
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    • 2023
  • This study analyzed the management efficiency of jujube, bitter persimmon, and chestnut farms using data envelopment analysis (DEA). And this study analyzed causes affecting management inefficiency of those farms using the two-step method. The main findings are as follows. First, as self and employment labor costs are increased, it is important to reduce labor costs which account for 60~70% of the total production cost. Second, efforts to improve management efficiency are needed as overall efficiency of farms were decreased. Third, a pesticide cost per 10a representing a level of pesticide had a negative effect or did not have a statistically significant effect on the management efficiency. This implies that expanding environment-friendly production by reducing pesticides is effective for improving the management efficiency. Fourth, as leading farms were more efficient than general farms, technology dissemination and education through leading farms are important for improving efficiency, and efforts are needed to promote exchange between leading and general farms.

Effects of Consumer Awareness of Organic Agricultural Products on Repurchase Intention (유기농산물 소비자인식이 재구매의사에 미치는 영향)

  • Seo, Yong-Sil;Seo, Yoon-Jeong;Lee, Jin-Hong;Lee, Byung-Oh
    • Journal of Distribution Science
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    • v.13 no.11
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    • pp.59-67
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    • 2015
  • Purpose - The number of consumers adopting a lifestyle of health and sustainability has recently increased with the rise of trends in healthy living. The size of the organic agricultural product market has also increased given that these consumers prefer consuming environmentally friendly products that promote family health. However, awareness of organic agricultural products remains insufficient because of the characteristics of the Korean organic agriculture system, which only focuses on food safety inspection. The object of this research is to suggest a policy approach to increase understanding and to expand the purchasing of organic agricultural products by analyzing the influence of customer recognition of such products on their willingness to repurchase. Research design, data, and methodology - This study used binomial logistic regression analysis with the aim of explaining the effects of consumers' socio-demographic characteristics, their awareness of the equivalence arrangement for organic food and of the abolishment of low-pesticide agricultural product certification, and their viewing of negative broadcasts about organic agricultural products on their repurchase intention of such products. A questionnaire survey was conducted with 655 respondents who were in their 20s, lived either in Seoul or in its metropolitan area, and had purchased organic agricultural products. Result - From the results of the analysis, the majority of the respondents recognized organic agricultural products, but they found their prices to be expensive. The majority of the respondents were also aware of the certification system and the reliability of organic agricultural products. However, the results indicate that efforts need to be made to recover consumer trust as many respondents stated that their trust levels in these products were low. In general, those purchasing organic agricultural products were satisfied, but those answering "very satisfied" were not in the majority. Binomial logistic regression analysis results revealed that repurchase intention decreased as consumers viewed a greater number of negative broadcasts about these products. On the other hand, repurchase intention increased as they became more aware of the abolishment of low-pesticide certification. Repurchase intention also increased as income increased, as the number of family members decreased, and when a consumer was a member of a consumer organization. In addition, the older the consumers were who watched the TV programs, the smaller the number of family members that were aware of the abolishment of low-pesticide agricultural product certification and, the higher the income of the consumers aware of organic equivalence arrangement, the greater their repurchase intention. Conclusion - External stimuli, such as negative TV programs on organic agricultural products and the abolishment of the low-pesticide agricultural product certification, relevant social issues and systems, influence consumer repurchase intention. To that end, positive environmental and ecological broadcasting about organic agricultural products would contribute to an increase in purchasing. Additionally, this could be used for promotion and marketing plans as the results indicate that trust in organic agricultural products would cause a positive repurchasing effect.

Establishment of Simultaneous Analysis Method for the Detection of Multi-Pesticide Residue Used in Golf Courses (골프장 농약 검사를 위한 다성분 동시분석방법 확립에 관한 연구)

  • Yun, Jeong-Ki;Lee, Min-Hyo;Noh, Hoe-Jung;Park, Jong-Gyum;Kim, Hyuk;Kim, Chan-Sub
    • Journal of Soil and Groundwater Environment
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    • v.11 no.4
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    • pp.18-24
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    • 2006
  • The possibility of multiresidue analysis of 24 pesticides out of 30 residual pesticides which are subjected to test in the golf courses was examined. The utility of multiresidue method for pesticide residue test was evaluated by recovery test through a standard addition method of pesticides in water, soil, and lawn grass. The experimental results of the recovery test for individual pesticides are as follows : The number of pesticide of which average recovery rate was over 70% regardless of media was 16 pesticides. These pesticides were composed of 8 organophosphorus pesticides (chlorpyrifos, chlorpyrifosmethyl, diazinon, EPN, fenitrothion, phenthoate, phosalone, and toclofos-methyl). 4-organochlorinated pesticides (daconil, captan, endosulfan, and tetradifon), 2-pyrethroid pesticides(fenpropathrin, lambda-cyhalothrin) and 2 other pesticides (bromopropylate, pendimethalin). On the other hand, in case of dicofol, average recovery rate was over 70% for water and lawn grass but only 53.3% for soil. Therefore, the multiresidue method applied in this experiment is not appropriate for analysis of dicofol in soil. Furthermore, among 7 pesticides, 2 pesticides(amitraz and pyraclofos) showed that theirs average recovery rate deviated from criteria($70{\sim}130%$) in almost ail media, while 5 pesticides(bensulide, deltamethrin, iprodione, phosphamidon and tralomethlin) were not detected from all media by GC/NPD or GC/ECD.

Analysis of Organochlorine Pesticide, in the Presence of Polychlorinated Biphenyls(PCBs) I. Florisil Column Separation of the Pesticides-PCBs Mixture (Polychlorinated Biphenyls(PCBs) 존재하에 유기염소계 살충제의 잔류분 분석 1. Florisil Column에 의한 농약과 PCBs의 분리)

  • Park C. K.;Lee C. Y.;Park R. D.
    • Korean journal of applied entomology
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    • v.16 no.4 s.33
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    • pp.221-227
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    • 1977
  • Polychlorinated Biphenyls (PCBs) interfere with gas chromatographic analysis of multiple organochlorine pesticide residues. In the present work, existing Florisil column chromatographic method has been modified as to improve separation of organochlorine pesticides and their metabolites from PCBs. It was amply demonstrated that separation of $\alpha-BHC,\; \gamma-BHC$ Heptachlor epoxide Dieldrin, p.p-DDD, p.p'-DDT from PCBs such as Aroclor 1254 is complete and recovery of the pesticides is found quantitative. Aldrin and Heptachlor in the Aroclor eluant can be separately analyzed by comparison of the chromatographic pattern of standard Aroclor 1254 with that of Aroclor 1254 a dmixed with the two pesticides. The Florsil column technique can be utilized in the routine evaluation of the organochlorine pesticide residues by gas chromatography.

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Quality Characteristics of Yanggeng added with Pesticide Free Wild Grape (Vitis amurensis) Juice (무농약 산머루 즙을 첨가한 양갱의 품질특성)

  • Kang, Chang-Soo
    • Korean Journal of Organic Agriculture
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    • v.23 no.2
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    • pp.301-309
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    • 2015
  • This study was performed to investigate the quality characteristics of Yanggeng added wild grape (Vitis amurensis) juice. The yanggeng was prepared with pesticide-free wild grape juice, agar, sugar and salt. The yanggeng was made with various levels (0, 50, 100, 150, 200 g of wild grape juice in yanggeng, respectively) based on the total weight of water. It was estimated on Hunter's color value, texture profile analysis, and sensory characteristics of the Yanggeng. As the content of wild grape juice increased, The lightness (L) and yellowness (b) decreased and redness (a) increased. In texture profile analysis, hardness was increased; however, springiness, cohesiveness, gumminess and chewiness decreased with increasing levels of wild grape juice. The results of the sensory evaluation indicated that the Yanggeng containing the 150 g level of wild grape juice showed the highest preference scores in terms of color, taste, texture, flavor and overall acceptance. These results show that the yanggeng containing 150 g of wild grape juice is the better.

Analysis of Organochlorine Pesticide Residues in the Presence of Polychlorinated Biphenyls (PCBs) -Part II. Analysis of River Sediments and Cultivating Soils in the Peripheries of Several Industrial Estates- (Polychlorinated Biphenyls(PCBs) 존재하(存在下)에 유기염소계(有機鹽素系) 살충제의 잔류분(殘留分) 분석(分析) -제2보(第2報), 공단주변(工團周邊)의 하천(河川) 및 전답토양(田畓土壤) 분석(分析)-)

  • Park, Chang-Kyu;Park, No-Dong
    • Applied Biological Chemistry
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    • v.23 no.1
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    • pp.58-63
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    • 1980
  • Present investigation is undertaken to evaluate residues of organochlorine pesticides and PCBs in river sediments and cultivated soils by GLC. Main sampling areas chosen were three industrial estates, Suwon, Iri and Kumi. Samples consist of river sediments and cultivated soils, in Suwon, Iri and Chilgok, which are likely to be accumulated with PCBs from nearby factories. Organochlorine pesticide residues were found in all sediments and soil samples while no PCBs residue was detected in all samples analyzed. The pesticide residues were greatest in the Suwon and least in Chilgok soils. p,p'-DDT and BHC isomers $({\alpha}-,\;and\;{\gamma}-)$ were found in all soil samples. p,p'-DDT, at the range of 0.006-0.840 ppm, was the most abundant residues among organochlorine insecticides.

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Analysis of Multiple Pesticide Residues in Raw Materials Used in Dietary Supplements by GC/ECD and NPD (GC/ECD와 NPD를 이용한 건강기능식품 주요 원료 중 다성분 잔류농약 분석)

  • Park, Sun-Young;Oh, Sang-Suk
    • Korean Journal of Food Science and Technology
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    • v.36 no.6
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    • pp.863-871
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    • 2004
  • Analyses of residual pesticides in raw materials used for dietary supplements were performed using multi-ingredients simultaneous analysis method. Pesticides such as BHC, chlorpyrifos, and quintozene were detected in 12 domestic and 7 imported samples, suggesting need for monitoring pesticides in domestic and imported raw materials and establishing residual limit of each pesticide.

A Study on the causes of farmer's disease and greenhouse disease in a rural area of Kyungnam province (경남 일부지역의 농부증 및 하우스증 발생에 미치는 요인분석)

  • Hong, Dae-Yong;Kim, Jang-Rak;Lee, Myung-Soon;Kang, Kyung-Hee;Ha, Ho-Sung
    • Journal of agricultural medicine and community health
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    • v.21 no.2
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    • pp.173-193
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    • 1996
  • This study was carried out to elucidate the causes of farmer's disease and greenhouse disease in the rural area of Kyungnam province during 1996. 2,171 (69.1%) of the 3,140 adults above 20 years old who had lived in the selected 20 villages in Uiryong County of Kyungnam Province were selected in order to over both residents who live in the green house distracts and conventional rural area. The results were as follows: 1. Among the subjects, the male was 42.2% and female was 57.6%. The average age for the male was 52.3, 55.6 for the female. 2. The proportion of the farmers in the subjects was 81.5%. Among these 78.0% were engaged in the greenhouse farming. 3. Among the eight symptoms of Nofusho(japanese farmer's comples), lumbago was the most frequently complained and followed by shoulder stiffness and parenthesis of hand or foot. 4. The total score of farmer's disease was evidently higher in the female and the older the score was clearly bigger. 5. The prevalence of Nofusho(Japanese farmer's comples)was 26.8% and 43.15% was for the suspected Nofusho. In the male, the prevalence of Nofusho was 13.6% and 40.9% for the suspected Nofusho and in the female 36.5% and 44.7% were shown, comparatively. 6. According to the multiple classification analysis, sex, age, and occupation were selected as significant variables to explain the total score of Nofusho. 7. The correlations between the total score of Nofusho and the number of sick day, working years, and age were significant, comparatively. 8. According to the multiple classification analysis corolling interaction between independent variables, age was the only variable which was significant in the male and age, pesticide work in the female. 9. The score of greenhouse disease was highest in the group who engaged in greenhouse farming and conventional farming(2.76 for male, 3.77 for female) followed by the group who engaged only in greening house farming(2.66 for male, 3.49 for female) and by the group who engaged only in conventional farming(2.27 for male, 3.05 for female) 10. According to the multiple classification analysis with the total score of greenhouse disease as dependent variable, corolling interaction between independent variables, age and pesticide work were revealed as significant variables in the male, while, pesticide work and farming type were significant in the female. According to the above results, the following could be suggested. Because lumbago, shoulder stiffness, paresthesia of hand and foot were the most frequently complained symptoms in the respondent, the development of farming tool to reduce the body burden and periodical physical exercise and rest is highly recommended. It is revealed that both in the farmer' disease and greenhouse disease the score was higher in the female than in the male. So the reasonables measures is recommended to reduce the working hours of the female. Pesticide work was revealed as the significant variable in the female in farmer's disease and both in the male and the female in greenhouse disease. So the development of the safe method of pesticide spraying including safety education should be introduced. Particularly the female should be excluded in pesticide spraying.

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