• Journal of agricultural medicine and community health
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• v.40 no.4
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• pp.228-239
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• 2015

Objectives: The purpose of this study was to measure the symptom prevalence of acute pesticide poisoning among farmers in Gyeong-gi province and to investigate the occupational risk factors. Methods: The subjects were 663 farmers using pesticide directly or indirectly and the survey was performed during 2013. 7. 11 - 2014. 8. 27. The data were analyzed by SPSS 21.0. Results: The prevalence of acute pesticide poisoning was 6.63% and dizziness was the most common symptom. Acute pesticide poisoning was related with 'days of pesticide use per year', 'lifetime pesticide application days', 'the number of pesticide mixture' and 'type of farming'. Conclusions: It is necessary to manage and educate the pesticide poisoning-vulnerable group more systematically. Afterward additional study is needed to investigate the farming safety behavior and delicate amount of pesticide exposure.

• Environmental Engineering Research
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• v.14 no.4
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• pp.226-236
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• 2009

The performance of phytoremediation has proven effective in the removal of nutrients and metals from aqueous systems. However, little information is available regarding the behavior of pesticides and their removal pathways in aquatic environments involving plant-uptake. A detailed understanding of the kinetics of pesticide removal by plants and information on compound/plant partition coefficients can lead to an effective design of the phytoremediation process for anthropogenic pesticide reduction. It was determined that the reduction rates of four organophosphorus (OP) and two organochlorine (OC) pesticides (diazinon, fenitrothion, malathion, parathion, dieldrin, hexachlorobenzene [HCB]) could be simulated by first-order reaction kinetics. The magnitude of k was dependent on the pesticide species and found within the range of 0.409 - 0.580 $d^{-1}$. Analytical results obtained by mass balances suggested that differential chemical stability, including diversity of molecular structure, half-lives, and water solubility, would greatly influence the removal mechanisms and pathways of OPs and OCs in a phytoreactor (PR). In the case of OP pesticides, plant accumulation was an important pathway for the removal of fenitrothion and parathion from water, while pesticide sorption in suspended matter (SM) was an important pathway for removal of dieldrin and HCB. The magnitude of the pesticide migration factor (${\Large M}_p^{pesticide}$) is a good indication of determining the tendency of pesticide movement from below- to above-ground biomass. The uncertainties related to the different phenomena involved in the laboratory phyto-experiment are also discussed.

• The Korean Journal of Community Living Science
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• v.17 no.4
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• pp.49-56
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• 2006

The purpose of this study was to evaluate the thermal and subjective comfort of various pesticide-proof clothes made from different material. Seven male adults took part in the study, conducted in a climate-chamber controlled with an ambient temperature of $30^{\circ}C$ and a relative humidity of 60%RH. The thermal and subjective responses of subjects wearing pesticide-proof clothing made of Goretex(coating treatment), polyester (water-repellent treatment), non-woven(coating) and nylon(coating) were measured. The main results were summarized as follows: (1) Change of rectal temperature and clothing microclimate were inhibited more effectively in pesticide-proof clothing made of Goretex, polyester and non-woven than nylon materials. (2) Mean skin temperature at the end of the experiment was significantly higher in subjects who wore nylon than non-woven and Goretex, and was lowest in those with pesticide-proof clothing made of polyester. (3) Change of heart rate was significantly lower in subjects with Goretex and polyester clothiing than those with non-woven, and in those with nylon, it was highest. (4) Subjective comfort was greater in subjects with Goretex, polyester and nonwoven clothing than nylon, except for thermal sensation. Thermal sensation was greater in order of polyester, Goretex, non-woven and nylon. Thus, it was concluded that pesticide-proof clothing made of Goretex, polyester and non-woven material could reduce thermal stress during the spraying of pesticides in summer.

• Journal of the Korean Society of Clothing and Textiles
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• v.17 no.4
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• pp.577-586
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• 1993

Pesticide protective clothing has not been frequently worn due to its lack of thermal comfort. It is important to develop fabrics which can allow the wearer to work in comfort. One of the possible way to achieve the goal is to produce fabrics with a water- and oil-repellent finish which would resist pesticide penetration but maintain some breathability. The purpose of this study were to evaluate the pesticide barrier properties of untreated and water- and oil-repellent finished nonwoven fabrics. Three types of nonwoven fabrics(Tyvek, Sontara and Kimlon) were used as test specimens. By pad-dry-cure method, each of the specimen was treated with fluorocarbon. The pesticide barrier properties (amount of pesticide penetration and residue) were measured by the gas chromatography. The performance properties of untreated and treated specimens were evaluated with respects to water pepellency(KS K 0590), oil repellency(AATCC 118), water resistance(KS K 0591, AATCC 42), water vapor transmission (KS A 1013) and air permeability(KS K 0570). The results of this study were as follows : 1) The untreated Sontara showed much more amount of pesticide penetration than untreated Tyvek and Kimlon, while the treated Sontara showed little amount of pesticide penetration. 2) After laundering, the amount of pesticide residue in the untreated and treated Sontara was less than that in Tyvek and in Kimlon. 3) Water- and oil-repellent finish improved water repellency, oil repellency, and water resistance of specimens. 4) The untreated Sontara and Kimlon showed higher water vapor transmission and air permeability than untreated Tyvek. Water vapor transmission and air permeability of treated specimen decreased compared to those of untreated.

• Journal of the Korean Society of Clothing and Textiles
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• v.31 no.11
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• pp.1611-1620
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• 2007

The precaution to spray with agricultural chemicals is very important, in particular personal protective equipment against pesticide in order to protect farmers# pesticide poisoning. The Ministry of Agriculture and Forestry has proclaimed the announcement of pesticide proof clothing(PPC) in 1983, and revised it in 1987. The announcement had many performance items to achieve the high-quality protective clothing for pesticide including weight, density, force strength, dimensional change(in washing and drying), fastness(dyeing, washing, sweating and rubbing) and water resistance of clothes. Announcement of the PPC has better durability and penetration resistance function than former days, but the plenty of farmers didn#t wear it because of the intolerable heat. To increase wearing rates, the pesticide proof clothing must be estimated the water-vapour resistance. From the results, the developed PPC with polyester treated water-repellent showed the more excellent comfort than an existing PPC with nylon coated polyurethane. But the developed PPC appeared to have the low water-vapour resistance. Therefore, it is suggested that the property of pesticide penetration must be evaluated through the field test in the future study.

• Journal of the Korean Society of Clothing and Textiles
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• v.26 no.11
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• pp.1672-1681
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• 2002

To evaluate the thermal environments and the workload of farmers in the rice field in summer, this study investigated rice farmers' physiological, psychological responses, work postures, work clothes, air temperature and air humidity during the spraying pesticide in the rice field. Five career farmers (3 males, 2 females) volunteered as the subjects. During the spraying pesticide in the rice field, physiological responses were monitored continuously. The results were as follows. l. Farmers wore only raincoats not pesticide-proof clothing. 2. The value of WBGT, rectal temperature($T_{re}$), mean skin temperature(${\={T}}_{sk}$) were $24.9∼28.9^{\circ}C,\;37.8({\pm}0.3)^{\circ}C\;and\;33.6({\pm}0.6)^{\circ}C$, respectively. Clothing microclimate temperature($T_{cl}$) on the chest and back were $32.5({\pm}2.6)^{\circ}C\;and\;33.6({\pm}2.6)^{\circ}C$, respectively(p<0.00l). Humidity inside of the clothing ($H_{cl}$) was over 80%RH and heart rate(HR) was 112(${\pm}27$)bpm. We evaluated that the spraying pesticide was 'heavy work' by the Tre and HR. To four subjective questionnaires, all farmers expressed 'hard, hot, humid and uncomfortable' without individual difference at the end of works. We suggested that 1) the spraying pesticide in the rice field was a heavy work, 2) because the workload of farmers in the raincoat/pesticide-proof clothing can't be evaluated by only WBGT, assessors should measure physiological, psychological responses as well as thermal environments, 3) to alleviate farmers' heat strain, clothing manufacturers must consider not only the improvement of textile materials and clothing weight but also the designing of personal cooling equipment.

• Bulletin of the Korean Chemical Society
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• v.28 no.6
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• pp.929-935
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• 2007

The objective of this study was to develop a rapid, simple, and qualitative acetylcholinesterase (AChE)- detection kit, based on a modification of the Ellman and ELISA methods, for the detection of organophosphorus (OP) and carbamate (CB) pesticide. The developed kits were used to screen a large number of agricultural samples (spiked and real) for OP and CB pesticide residues. AChE was extracted from the heads of honeybees (Apis mellifera L.) using Triton X-100, and was purified through 3 steps: diethylaminoethylcellulose chromatography (DEAE), affinity chromatography and membrane filtering, and Mono-Q column chromatography. Epoxy-activated Sepharose 6B affinity chromatography was used for large-scale purification. The presence of OP and CB pesticide residues in agricultural samples was assayed on the basis of AchE inhibition value. The presence (6 bands) or absence of some colored bands on the test line indicated a negative or positive result, respectively. The limits of detection for measured organophosphorus (OP) and carbamates (CB) pesticide residues in standard pesticide solutions and fortified samples were ranged from 0.50 to 2.50 ppm and 0.50 to 4.75 ppm, respectively.

• Analytical Science and Technology
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• v.34 no.1
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• pp.1-8
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• 2021

An analytical method was developed and optimized for the quantification of a plant growth regulator, 2,6-diisopropylnaphthalene (2,6-DIPN), in agricultural products using gas chromatography-tandem mass spectrometry. The samples were extracted, partitioned, and were purified using a Florisil® cartridge. To validate the analytical method, its specificity, linearity, limit of detection (LOD) and limit of quantification (LOQ) of the instrument, LOQ of the analytical method (MLOQ), accuracy, and repeatability were considered. The method displayed excellent results during validation, and is suitable for the determination and quantification of the low residual levels of the analyte in the agricultural samples. All of the results with the optimized method were satisfactory and within the criteria ranges requested in the Codex Alimentarius Commission guidelines and the Ministry of Food and Drug Safety guidelines for pesticide residue analysis. The developed method is simple and accurate and can be used as a basis for safety management of 2,6-DIPN.

• Journal of Preventive Medicine and Public Health
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• v.57 no.1
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• pp.73-82
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• 2024

Objectives: The unsafe use of pesticides in agriculture represents a major hazard to human health. This study was conducted to investigate the association between pesticide exposure and health symptoms among chili farmers in northeast Thailand. Methods: This cross-sectional analytic study included 141 chili farmers in Sakon Nakhon Province, in northeast Thailand. Data regarding health symptoms were gathered using a self-report questionnaire. A medical technician tested blood cholinesterase activity using an erythrocyte method, and an occupational medicine specialist at Ramathibodi Hospital in Bangkok, Thailand reviewed the results. Associations between personal characteristics, pesticide exposure factors, and health symptoms were analyzed using multiple logistic regression. Results: Of the 141 chili farmers studied, 66.7% experienced pesticide poisoning, as indicated by below-normal cholinesterase levels. Fatigue was the most frequently reported symptom associated with pesticide exposure, affecting 37.6% of participants. This was followed by nausea and vomiting (31.9%), dizziness (14.9%), and dry throat (14.9%). Multivariate logistic regression analysis revealed that several factors were significantly associated with adverse symptoms: amount of work experience, volume of pesticides used, use of chemical pesticides, use of leaking containers during spraying, direct pesticide exposure while working, contact with pesticide-soaked clothing, consumption of food and drinks in the fields, and blood cholinesterase level indicating risk. Conclusions: This study suggests potential health risks for chili farmers stemming from exposure to and contamination by pesticides used in agricultural practices. To mitigate these risks, it is essential to supply personal protective equipment and to implement educational programs aimed at improving protective behaviors among farmers.

• The Korean Journal of Pesticide Science
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• v.16 no.4
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• pp.409-417
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• 2012