• Membrane Journal
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• v.7 no.4
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• pp.183-190
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• 1997

Composite membranes were prepared by the deposition of pentafluoropyridine(PFP) or pentafluorotoluene(PFT) plasma films onto porous Celgard and nonporous poly(dimethylsiloxane) [PDMS] films. Gas permeation measurements for the composite membranes were made in the temperature range of 35$^{\circ}$C to 75 $^{\circ}$C and the solubilities in plasma polymers were measured using a Cahn Microbalance. The permeability coefficients of plasma polymers obeyed the Arrhenius relationship fairly wall. Activation energies for permeation in the plasma films increased with the size of penetrant molecules. The activation energy of plasma polymers was much lower than that of commonly used perfluoropolymers. This difference was proved to be attributable to the much lower heat of solutions of the plasma polymers compared to perfluoropolymers. The diffusion activation energies were comparable with each other.

• Bulletin of the Korean Chemical Society
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• v.6 no.3
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• pp.128-131
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• 1985

A series of copolymer membranes of 2-hydroxyethylmethacrylate (HEMA) with selected hydrophobic monomers were prepared without crosslinking agents. The equilibrium water content, the partition coefficient, and the permeability of the solutes such as urea, methylurea, 1,3-di-methylurea, and acetamide via these membranes were measured. The partition coefficient data show that as the hydrophobicity of solutes increased, the partition of solutes were dictated by hydrophobic interaction between solute and polymer matrix. Diffusion coefficients obtained in these experiments decrease as the water content of polymer membrane decreases. This decrease is blunt as the excess heat capacities, ${\phi}C^0_p$ (excess) in aqueous solution at infinite dilution of solute increases. To investigate the relationship between water content and diffusion coefficient, the results of the diffusion experiments were examined in light of a free-volume model of diffusive transport. The remarkable increase of urea mobility in the polymer network containing relatively larger bulk water can be considered as water structure breaking effect.

• Bulletin of the Korean Chemical Society
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• v.20 no.6
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• pp.672-676
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• 1999

Gas-Permeable polymeric membranes containing carboxyl groups which are suitable for enzyme immobilization were investigated in order to use them as gas electrode membranes in biosensors. Carboxylated polyurethane (CPU) was synthesized via a reaciton between 2,2-bis(hydroxymethyl)propionic acid as a chain extender and prepolymers prepared from polycarprolactone(Mn=2,000) and 4,4'-diphenylmethane diisocynate. It was difficult to prepared membranes from the pure CPU because of its high elasticity and cohesion. However, transparent free-standing membranes were easily prepared from the blend solution of CPU and carboxylated poly(vinyl chloride)(CPVC) in tetrahydrofuran. Both elasticity and cohesion of the CPU/CPVC membranes were decreased with increasing the content of CPVC. DSC experiment suggests that CPU and CPVC may be well mixed. Permeability coefficients for O₂and CO₂(Po₂and Pco₂)in the membranes increased as the proportion of CPU increased. The addition of dioxtyl phthalate(DOP), a plasticizer, significantly enhanced the Po₂and Pco₂which were 4,4 and 30 barrer, respectively, in the CPU/CPVC(80/20 wt/wt) membranes containing 20% of DOP at 25℃ and 100psi. Thus this type of membranes may have a potential for the use as gas electrode membranes in biosensors.

• Magazine of the Korean Society of Agricultural Engineers
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• v.31 no.3
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• pp.57-69
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• 1989

The study was carried out for the strength parameter of coarse grained Soil and slope stability analysis of earth dam. The test samples were taken fifteen kinds of soil from cohesive soil to coarse gravel. The degree of compaction of test samples for shear test and permeability test was chosen 95 percentage of maximum dry density. The results of this study are as follows ; 1.The maximum dry density(Yd) of coarse grained soil increase in proportion to coarse particles(P) with the relation of Y d= 1.609+0.0043P. 2.The coefficients of permeability(k) decrease by the increase of fine particles(n) with the relation of k=0.0426e-0 185n. 3.The cohesions of soil decrease by the increase of coarse particles, but internal friction angles are more increased in same condition. 4.The internal friction angles(${\Phi}$) decrease in inverse proportion to void ratio(e) with the relation of ${\Phi}$ = 73.068 - 69.268e. 5.The strength parameters( Ct ${\Phi}$t) by triaxial compression test are clearly smaller than that (Cd, ${\Phi}$d) by direct shear test in fine grained soil, but the differences between both parameters are a little in coarse grained soil.The relations of both parameters are as follows; Ct = O.544Cd + 0.04 ${\Phi}$t= 1.282${\Phi}$d-2306 6.In cohesive soil, the strength parameters( Cl ${\Phi}$l) by large size shear test apparatus are similar to the strength parameters(Cs , ${\Phi}$s) by small size shear test appratus, but Cs and ${\Phi}$s values are larger than Cl and ${\Phi}$l values from 10 percentage to 20 percentage in coarse grained soil. 7.The fine grained soil is inappropriate to high dam more than 20 meters and it must be taken coarse grained soil with high internal friction angle for high dam.

• Journal of the Korean Society of Clothing and Textiles
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• v.25 no.2
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• pp.237-248
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• 2001

The purpose of this study was to compare the comfort sensation depending on four different kinds of denim blue jeans: cotton, cotton/tencel, tencel, cotton/pp. The objective and subjective experiments were conducted to measure the comfort of blue jeans. To investigate the objective comfort, physical properties related to thermal insulation, moisture properties and hand were measured. For subjective comfort measurement, 5 healthy female college students were taken as subjects. The outcomes of the experiments are as follows: The higher the air permeability and bulk density of the denim, the lower the thermal insulation, the thicker the denim, the higher the thermal insulation. Tencel blending denim showed the higher bulk density, the lower air contents, and consequently the lower thermal insulation than the other denims. Tencel showed the highest moisture regain, and cotton/tencel blend showed the highest water vapor permeability. Tencel denim had relatively better flexibility, shape stability and elastic recovery than the other denims. The total hand values of the denims by KES-FB system were not significantly different. Cotton and cotton/pp denims raised the subjects body temperature after excercise more than tencel or cotton/tencel denims. Average skin temperature was found to have a correlation with micro climate temperature and micro climate humidity. The correlation coefficients were 0.749 and 0.767, respectively. However, average skin temperatures were not significantly different among the materials. Pulse rate was found to be the highest when wearing cotton/pp and the lowest in case of cotton/tencel denim. The energy was consumed in order of cotton>cotton/pp>tencel>cotton/tencel. There was no significant difference in preference before excercise, but, after the excercise, the order of preference changed as the following; cotton/tencel>tencel>cotton/pp>cotton.

• Proceedings of the Korean Geotechical Society Conference
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• 2009.03a
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• pp.278-287
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• 2009

This thesis studied effect of zoning on seepage flow in concrete faced gravel-fill dam (CFGD) designed to have selected main rockfill or gravel-fill zone, Zone 3Bs with higher permeability to enhance the safety against accidental water infiltration into the dam. For this purpose, centrifuge model tests with two cases, with and without Zone 3Bs, were performed in order to investigate the necessity and the function of Zone 3Bs. Model dams were made by soil samples with modified coefficients of permeability and concrete faced slab was simulated with aluminum alloy. Water infiltration was simulated by rising water table over cracks on the facing. Behaviors of model dams were measured by LVDTs, strain gages, pore water pressures and cameras. Form the results of centrifuge tests, it was found out that the Zone 3Bs acts as a protection of main gravel-fill zone by inducing flow paths for infiltrated water into it as well as by draining off the infiltrated water out of the dam in a short time.

• Journal of the Korean Geosynthetics Society
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• v.2 no.1
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• pp.47-55
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• 2003

The effects of fiber composition factors of 14 geotextiles which are thickness, porosity, fiber length and diameter etc. on the transmissivity were examined and in-plane permeability of geotextiles under thickness change, transmissivity, confined load were analyzed by the constitutive equations. And the effects of laminar structure on the permittivity of laminar geotextile composites which were manufactured with fiber packing densities were assessed. Transmissivities were increased with thickness of geotextiles and in-plane permeability coefficients were increased with porosity and fiber diameter. The effects of porosity were decreased with normal stress and slightly increased with fiber length. Transmissivities were increased with fiber diameter and showed same tendensy for the same fiber length. Permittivities of laminar geotextile composites were influenced by the waterhead loss in the inner interface and the connection shape of these composites to water path was interpreted as bell mouth type or soft flux pipe type.

• Korean Chemical Engineering Research
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• v.49 no.4
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• pp.460-464
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• 2011

Poly(ether-block-amide)(PEBA, $PEBAX^{TM}$) resin is a thermoplastic elastomer combining linear chains of hard-rigid polyamide block interspaced soft-flexible polyether block. It was believed that the hard polyamide block provides the mechanical strength and permeation selectivity, whereas gas transport occurs primarily through the soft polyether block. The objective of this work was to investigate the gas permeation properties of carbon dioxide and methane for $PEBAX^{TM}$-1657 membrane and compare with those obtained for other grade of $PEBAX^{TM}$, $PEBAX^{TM}$-2533. And the organic/inorganic hybrid membranes were prepared using $PEBAX^{TM}$ and TEOS(tetraethoxysilane) by sol-gel process, and gas permeation properties were studied. $PEBAX^{TM}$-2533 membrane exhibited higher gas permeability coefficients than $PEBAX^{TM}$-1657 membrane. This was explained by the increase of chain mobility. The permeability coefficients for $PEBAX^{TM}$/TEOS hybrid membranes were higher than pure $PEBAX^{TM}$ membranes. This results were explained by the reduction of crystallinity of polyamide block by the introduction of TEOS. Ideal separation factor of hybrid membranes does not change much. This might be due to the increase of solubility selectivity.

• Journal of Soil and Groundwater Environment
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• v.8 no.4
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• pp.1-11
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• 2003

In order to measure aperture variation dependent on normal stress and to characterize on relationship between aperture variation and hydraulic conductivity this study measured apertures of rock fractures under a high resolution confocal laser scanning microscope (CLSM) with application of five stages of uniaxial normal stresses. From this method the response of aperture can be continuously characterized on one specimen by different loads of normal stress. The results of measurements showed a rough geometry of fracture bearing non-uniform aperture. They also revealed different values of aperture variations according to the load stages on each position along a fracture due to the fracture roughness. Laboratory permeability tests were also conducted to evaluate the changes of permeability coefficients related to the aperture variations by different loads. The results of permeability tests revealed that the hydraulic conductivity was not reduced at a fixed rate with increase of normal load. Moreover, the rates of aperture variations did not match to those of hydraulic conductivity. The hydraulic conductivity calculated in this study did not follow the cubic law, representing that the parallel plate model is not suitable to express the fracture geometry corresponding to the results of aperture measurements under the CLSM.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.13 no.1
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• pp.57-68
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• 2010

The purpose of this study is to analyze the characteristics of environment-friendliness of waterproof materials based on comprehensive experiments on waterproofness in terms of coefficients of permeability, harmfulness of waterproof materials and fish toxicity of Oryzias latipes mortality to verify eco-toxicity of each method of construction and waterproof material, which are to be applied by taking eco-toxicity into account when building ecological flows in upper areas on natural and artificial grounds. As a result, the following conclusions have been reached in this study: 1. In regard of the harmfulness analyzed, each material showed a different result of analytical value in each lab tank. Compared to input water, pH, COD, SS, T-P, and T-N values increased a little, but DO value decreased. The value of turbidity analyzed independent of the water quality standard of aquatic ecosystem set forth by the Ministry of Environment increased a little compared to the value in input water. 2. In the experiment of fish toxicity, compacted quicklime, cement fluid waterproof material, cement mortar waterproof material and bentonite powder were found to have 100% of fish mortality, respectively, and membrane waterproof material showed 83.3% of mortality, indicating strong fish toxicity. Improved asphalt sheet (63.3%) and synthetic rubber sheet (53.3%) were analyzed to have medium fish toxicity, while bentonite sheet (6.7%), Hwang-toh (6.7%) and clay (3.3%) showed relatively lower mortality and fish toxicity. 3. Regarding the analysis on waterproofness in terms of the coefficient of permeability of each waterproof material, improved asphalt sheet, synthetic rubber sheet, membrane waterproof material, cement fluid and mortar waterproof material and bentonite sheet were found impervious in case no leakage takes place in construction. Bentonite powder was found practically impervious based on the analytical results from the experiment done in compliance with weight ratios. So were the clay and Hwang-toh from the experimental results. To sum up such results as found in the experiment mentioned so far, the values of harmfulness and waterproofness analyzed were different in each lab tank, but there was absolutely little correlation with the mortality gained from the experiment on fish toxicity. In the experiment of fish toxicity, environment-friendly waterproof materials were analyzed, and it was found that clay, Hwang-toh and bentonite sheet are highly environment-friendly. In contrast, synthetic rubber and improved asphalt sheets were found to have medium-level environment-friendliness. Also, membrane water-proof materials, compacted quicklime, cement fluid and mortar waterproof material and bentonite powder were analyzed to have low environment-friendliness.