• 제목/요약/키워드: Permeability Performance

검색결과 668건 처리시간 0.028초

기체확산층의 유동투과율과 채널 형상 변화에 따른 고분자 전해질 연료전지 성능변화 수치연구 (Numerical study on PEM fuel cell performance with variation of GDL permeability and channel geometry)

  • 고수곤;손상호;남진현;김찬중
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.3114-3119
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    • 2008
  • Relatively high convective flow exists in the under-rib regions of a gas diffusion layer (GDL) when serpentine flow fields are employed in a PEMFC. This under-rib convection is believed to be favorable for the performance of PEMFCs, by enabling more effective use of catalysts in the under-rib regions. From the fact that the under-rib convection in a GDL is directly proportional to the permeability of the GDL, computational fluid dynamics (CFD) simulations were performed to discover the relationship between the GDL permeability and the PEMFC performance. Single-, triple-, and quintuple-path parallel serpentine flow fields for $9\;cm^2$ active cell area were considered while changing the GDL permeability from $1{\times}10^{-12}$ to $5{\times}10^{-11}m^2$. The results showed that higher GDL permeability generally resulted in better performance of PEMFCs, but the degree of performance enhancement became smaller as the parallel path number increased. The effects of the permeability on the local variables were also discussed.

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동제련 슬래그를 혼입한 포러스 콘크리트의 강도 및 투수성능에 관한 연구 (A Study on Strength and Permeability of Cooper Slag mixed Porous Concrete)

  • 심병주;김영수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2011년도 춘계 학술논문 발표대회 1부
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    • pp.69-72
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    • 2011
  • The purpose of this study is to identify basic property of porous concrete using cooper slag as fine aggregate. The specimens were made with cooper slag with various mixing ratio(10, 20, 30, 50%), porous concrete and porous concrete containing river fine aggregate and crushed fine aggregate, which W/B ratio fixed 0.25. Compressive strength, Flexural strength, coefficient of permeability. From the test results, various fine aggregate mixing ratio improves compressive strength and flexural strength, but cooper slag fine aggregate mixing ratio over 20%, concrete indicates trend to decrease performance of permeability. Concrete containing fine aggregate is improved the performance of permeability and strength compared to other specimen, when age 28days, and cooper slag mixing ratio less than 20% concrete indicates better performance than cooper slag mixing ratio 20% over.

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복합열화 환경을 받는 콘크리트 시설물을 위한 보수용 폴리머 시멘트 복합체의 내구성능 향상에 관한 연구 (Enhanced Durability Performance of Polymer Modified Cement Composites for Concrete Repair Under Combined Aging Conditions)

  • 원종필;박찬기
    • 한국농공학회논문집
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    • 제47권6호
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    • pp.27-34
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    • 2005
  • The purpose of this study is to improve the durability performance of polymer modified cement composites for repair of concrete under combined aging conditions. The experimental procedure was divided into three parts. First, the replacement level of mineral admixtures in polymer modified cement composites were determined in an experimental study based on a Box Behnken design. Second, the flow value, compressive strength and chloride permeability test of sixteen types of mixtures were conducted. Test results show that the polymer modified cement composites were effected on the improvement of the compressive strength and permeability performance. Third, the effects on the replacement level of silica fume mixture was evaluated by the compressive strength, chloride permeability, chemical resistance and repeated freezing and thawing cycles test. They demonstrated that the polymer modified cement composites using mixture of silica fume, fly ash, and blast furnace slag improved the durability performance.

Effect of damage on permeability and hygro-thermal behaviour of HPCs at elevated temperatures: Part 1. Experimental results

  • Gawin, D.;Alonso, C.;Andrade, C.;Majorana, C.E.;Pesavento, F.
    • Computers and Concrete
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    • 제2권3호
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    • pp.189-202
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    • 2005
  • This paper presents an analysis of some experimental results concerning micro-structural tests, permeability measurements and strain-stress tests of four types of High-Performance Concrete, exposed to elevated temperatures (up to $700^{\circ}C$). These experimental results, obtained within the "HITECO" research programme are discussed and interpreted in the context of a recently developed mathematical model of hygro-thermal behaviour and degradation of concrete at high temperature, which is briefly presented in the Part 2 paper (Gawin, et al. 2005). Correlations between concrete permeability and porosity micro-structure, as well as between damage and cracks' volume, are found. An approximate decomposition of the thermally induced material damage into two parts, a chemical one related to cement dehydration process, and a thermal one due to micro-cracks' development caused by thermal strains at micro- and meso-scale, is performed. Constitutive relationships describing influence of temperature and material damage upon its intrinsic permeability at high temperature for 4 types of HPC are deduced. In the Part II of this paper (Gawin, et al. 2005) effect of two different damage-permeability coupling formulations on the results of computer simulations concerning hygro-thermo-mechanical performance of concrete wall during standard fire, is numerically analysed.

고분자 전해질 연료전지의 전해질 막 두께가 내구성과 성능에 미치는 영향 (The Effect of Membrane Thickness on Durability and Performance of Proton Exchange Membrane Fuel Cell)

  • 황병찬;이혜리;박권필
    • Korean Chemical Engineering Research
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    • 제55권4호
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    • pp.473-477
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    • 2017
  • 고분자 전해질 연료전지(PEMFC)의 고분자 막은 PEMFC 성능과 내구성에 많은 영향을 준다. 본 연구에서는 고분자막의 두께가 성능과 내구성에 미치는 영향을 파악하기 위해 두께가 다른 Nafion 막의 수소투과도, 불소 유출 속도(FER), 수명, 성능을 측정했다. 막 두께에 따른 수소투과도, 수소투과도와 FER과의 관계, FER과 수명과의 관계로부터 막 두께와 수명의 관계를 얻었다. 막이 두꺼워지면 수소투과도와 FER이 작아지면서 수명이 증가하였다. 반면에 막이 두꺼워지면 막 저항이 증가하면서 성능은 감소하였다. 성능과 내구성을 동시에 만족시키는 막 두께 범위는 $25{\sim}28{\mu}m$였다.

원심성형 콘크리트의 투수시험을 통한 균열 자기치유 성능평가 (Evaluation of Crack Self-healing Performance in Centrifugal Molding Concrete by Permeability Test)

  • 황철성;우해식;최영철
    • 한국구조물진단유지관리공학회 논문집
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    • 제22권3호
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    • pp.84-89
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    • 2018
  • 최근 자기치유 재료에 대한 연구는 보수하기 힘들거나, 보수비용이 많이 소요되는 구조물에 대해 구조물 스스로 손상을 치유하여 사용수명을 증가시키기 위해 많이 수행되어오고 있다. 현재 널리 사용되고 있는 자기치유 평가 방법으로는 투수시험이 있다. 하지만, 자기치유 평가 방법에서 자기치유 성능은 콘크리트의 초기 균열 폭에 큰 영향을 받지만 일관된 기준을 가지고 있지 않은 실정이다. 따라서, 본 연구에서는 기존 연구에서 사용한 균열 폭과 투수량을 기반으로 균열 폭-투수량의 상관관계와 시간-투수량의 상관관계를 분석하였다. 또한, 광학현미경을 이용하여 측정한 초기 균열 폭은 신뢰성이 떨어지므로 Poiseuille flow에서 ${\alpha}$값을 도출하여 시간-균열 폭에 대한 상관관계를 분석하여 시간-투수량과 시간-균열 폭에 대한 경향을 분석하였다.

탄산화 및 비탄산화된 콘크리트의 투수계수의 해석 기법 개발 (Analytical Modeling for Microstructural Permeability Coefficient of (Non)Carbonated Concrete)

  • 윤인석
    • 콘크리트학회논문집
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    • 제21권3호
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    • pp.255-264
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    • 2009
  • 콘크리트의 투수계수는 콘크리트 구조물의 내구성능 및 미세구조의 밀실성을 판단할 수 있는 핵심적인 재료 매개변수이다. 투수계수를 산정하기 위한 많은 연구들이 있었으나, 시멘트페이스트 및 골재 각각이 콘크리트의 투수성능에 미치는 영향을 다룬 연구는 드물다. 더우기, 탄산화가 염소이온의 확산계수에 큰 영향을 미칠 수 있음에도 불구하고, 탄산화된 콘크리트에 대한 확산계수를 다룬 연구는 매우 드문 실정이다. 본 연구의 목적은 탄산화 및 비탄산화된 콘크리트의 투수계수를 추정할 수 있는 기초적 접근방법을 개발하는 것이다. 본 연구에서는 미세구조 모델 및 시멘트의 경화특성을 기초로 투수계수를 산정할 수 있는 해석적 기법이 개발되었는데, 시간단계별로 변화하는 투수계수의 해석과 탄산화된 콘크리트의 투수계수를 계산할 수 있다. 탄산화된 콘크리트에서 감소된 공극량이 계산되었으며 이는 투수계수의 산정에 이용되었다. 해석 결과는 실험적 결과를 얻어서 상호비교하여 검증하였다.

콘크리트 표층부 내구성 증진 및 성능개선을 위한 규산질계 액상형 도포 방수재의 성능 평가 연구 (A Study on the Concrete Surface of Durability Advancement and Performance Improvement for the Siliceous Liguid Type of Spread Waterproofing Material)

  • 김진성;송제영;박진상;오상근
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2005년도 춘계 학술기술논문발표대회 논문집
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    • pp.29-32
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    • 2005
  • It is recognised that a permeability waterproof agent have been extensively used for concrete, in these days. In present paper shows effective practical scheme of a permeability waterproof agent in construction market that is to develope durability of concrete structure as apply to job site through the examination physical and chemical property of a permeability waterproof agent. It is indentified that can be maintain waterproofing performance, moreover it makes satisfactory result of permeation resistance as applying siliceous waterproof agent.

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GDL Permeability에 따른 고분자 전해질 연료전지의 물질전달 및 열전달 특성에 관한 연구 (Mass Transfer and Heat Transfer Characteristics of PEM fuel cell by Permeability of GDL)

  • 한상석;이필형;박창수;이재영;황상순
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.2822-2827
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    • 2008
  • Among the main components of PEM fuel cell, the functions of GDL are to transport reactants from the channel to the catalyst and remove reaction products from the catalyst and transport heat from the catalyst to the channels in the flow filed plate. Permeability of GDL is known to make it possible to enhance the gas transport through GDL, devoting to get better performance. In this paper, three dimensional numerical simulation of the fuel cell by the permeability of GDL is presented by using a FLUENT modified to include the electrochemical behavior. Results show that as permeability is higher than $10^{-12}m^2$, gradients of temperature distribution, oxygen molar concentration and current density distribution in MEA were decreased. Although heat generation was increased as high permeability, MEA's temperature was lower than the low permeability of GDL. This seems because that convection was higher affects in mass and heat transfer process than diffusion as permeability of GDL is increases.

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외부조건의 변화에 따른 섬유보강콘크리트의 내구성능 정가에 관한 연구 (A Study on the Evaluation of Durability of Fiber Reinforced Concrete According to the Change of External Conditions)

  • 김남욱
    • 한국안전학회지
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    • 제23권5호
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    • pp.97-104
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    • 2008
  • This study was intended to evaluate the permeable performance through a change of reinforcing materials, curing condition, durability evaluation and permeability test, and to select the reinforcing material which could reduce the durability and water tightness from it, as the study for considering how the change of the outside's environment factors that the concrete structure actually contacted with impacted the concrete's durability especially the permeability by referring to such the background of the study. Accordingly, it was judged that evaluating the permeability by considering the severe environment condition where the concrete structure was placed in was more reasonable than measuring the existing permeability coefficient conducted in the sound state for the permeability evaluation of actually-used concrete structure. In this study, it also could be known that the specimen of hybrid fiber reinforced concrete which mixed the long and short steel fiber was the most effective for water tightness enhancement in severe environmental conditions.