• Title/Summary/Keyword: Permeability Performance

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Numerical study on PEM fuel cell performance with variation of GDL permeability and channel geometry (기체확산층의 유동투과율과 채널 형상 변화에 따른 고분자 전해질 연료전지 성능변화 수치연구)

  • Koh, Soo-Gon;Sohn, Sang-Ho;Nam, Jin-Hyun;Kim, Charn-Jung
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3114-3119
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    • 2008
  • Relatively high convective flow exists in the under-rib regions of a gas diffusion layer (GDL) when serpentine flow fields are employed in a PEMFC. This under-rib convection is believed to be favorable for the performance of PEMFCs, by enabling more effective use of catalysts in the under-rib regions. From the fact that the under-rib convection in a GDL is directly proportional to the permeability of the GDL, computational fluid dynamics (CFD) simulations were performed to discover the relationship between the GDL permeability and the PEMFC performance. Single-, triple-, and quintuple-path parallel serpentine flow fields for $9\;cm^2$ active cell area were considered while changing the GDL permeability from $1{\times}10^{-12}$ to $5{\times}10^{-11}m^2$. The results showed that higher GDL permeability generally resulted in better performance of PEMFCs, but the degree of performance enhancement became smaller as the parallel path number increased. The effects of the permeability on the local variables were also discussed.

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A Study on Strength and Permeability of Cooper Slag mixed Porous Concrete (동제련 슬래그를 혼입한 포러스 콘크리트의 강도 및 투수성능에 관한 연구)

  • Shim, Byung-Ju;Kim, Young-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.05a
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    • pp.69-72
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    • 2011
  • The purpose of this study is to identify basic property of porous concrete using cooper slag as fine aggregate. The specimens were made with cooper slag with various mixing ratio(10, 20, 30, 50%), porous concrete and porous concrete containing river fine aggregate and crushed fine aggregate, which W/B ratio fixed 0.25. Compressive strength, Flexural strength, coefficient of permeability. From the test results, various fine aggregate mixing ratio improves compressive strength and flexural strength, but cooper slag fine aggregate mixing ratio over 20%, concrete indicates trend to decrease performance of permeability. Concrete containing fine aggregate is improved the performance of permeability and strength compared to other specimen, when age 28days, and cooper slag mixing ratio less than 20% concrete indicates better performance than cooper slag mixing ratio 20% over.

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Enhanced Durability Performance of Polymer Modified Cement Composites for Concrete Repair Under Combined Aging Conditions (복합열화 환경을 받는 콘크리트 시설물을 위한 보수용 폴리머 시멘트 복합체의 내구성능 향상에 관한 연구)

  • Won, Jong-Pil;Park, Chan-Gi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.47 no.6
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    • pp.27-34
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    • 2005
  • The purpose of this study is to improve the durability performance of polymer modified cement composites for repair of concrete under combined aging conditions. The experimental procedure was divided into three parts. First, the replacement level of mineral admixtures in polymer modified cement composites were determined in an experimental study based on a Box Behnken design. Second, the flow value, compressive strength and chloride permeability test of sixteen types of mixtures were conducted. Test results show that the polymer modified cement composites were effected on the improvement of the compressive strength and permeability performance. Third, the effects on the replacement level of silica fume mixture was evaluated by the compressive strength, chloride permeability, chemical resistance and repeated freezing and thawing cycles test. They demonstrated that the polymer modified cement composites using mixture of silica fume, fly ash, and blast furnace slag improved the durability performance.

Effect of damage on permeability and hygro-thermal behaviour of HPCs at elevated temperatures: Part 1. Experimental results

  • Gawin, D.;Alonso, C.;Andrade, C.;Majorana, C.E.;Pesavento, F.
    • Computers and Concrete
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    • v.2 no.3
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    • pp.189-202
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    • 2005
  • This paper presents an analysis of some experimental results concerning micro-structural tests, permeability measurements and strain-stress tests of four types of High-Performance Concrete, exposed to elevated temperatures (up to $700^{\circ}C$). These experimental results, obtained within the "HITECO" research programme are discussed and interpreted in the context of a recently developed mathematical model of hygro-thermal behaviour and degradation of concrete at high temperature, which is briefly presented in the Part 2 paper (Gawin, et al. 2005). Correlations between concrete permeability and porosity micro-structure, as well as between damage and cracks' volume, are found. An approximate decomposition of the thermally induced material damage into two parts, a chemical one related to cement dehydration process, and a thermal one due to micro-cracks' development caused by thermal strains at micro- and meso-scale, is performed. Constitutive relationships describing influence of temperature and material damage upon its intrinsic permeability at high temperature for 4 types of HPC are deduced. In the Part II of this paper (Gawin, et al. 2005) effect of two different damage-permeability coupling formulations on the results of computer simulations concerning hygro-thermo-mechanical performance of concrete wall during standard fire, is numerically analysed.

The Effect of Membrane Thickness on Durability and Performance of Proton Exchange Membrane Fuel Cell (고분자 전해질 연료전지의 전해질 막 두께가 내구성과 성능에 미치는 영향)

  • Hwang, Byungchan;Lee, Hyeri;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.55 no.4
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    • pp.473-477
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    • 2017
  • The polymer membrane of proton exchange membrane fuel cell (PEMFC) has a great influence on PEMFC performance and durability. In this study, hydrogen permeability, fluorine emission rate (FER), lifetime, and performance of Nafion membranes with different thicknesses were measured to investigate the effect of thickness of polymer membrane on performance and durability. The relationship between membrane thickness and lifetime was obtained from the relationships between hydrogen permeability and membrane thickness, hydrogen permeability and FER, FER and lifetime. As the membrane became thicker, the hydrogen permeability and FER decreased and the lifetime increased. On the other hand, the performance decreased with increasing membrane resistance. The membrane thickness range satisfying both performance and durability was 25 to $28{\mu}m$.

Evaluation of Crack Self-healing Performance in Centrifugal Molding Concrete by Permeability Test (원심성형 콘크리트의 투수시험을 통한 균열 자기치유 성능평가)

  • Hwang, Chul Sung;Woo, Hae Sik;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.3
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    • pp.84-89
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    • 2018
  • Recently, study on self-healing materials have been performed to increase the life by repairing the damage of structures themselves, which are difficult to repair or require high maintenance costs. A water permeability test has been widely used for the evaluation of self-healing performance. However, in the self-healing performance test method, the initial crack width of the concrete greatly affects on the self-healing performance but it does not have a consistent standard. Therefore, in this study, the correlation between crack and permeability and that between time and permeability were analyzed based on crack width and permeability. In addition, since the initial crack width measured by optical microscope is not reliable, the value is derived from the Poiseuille flow and the tendency of time-permeability and time-crack width are analyzed.

Analytical Modeling for Microstructural Permeability Coefficient of (Non)Carbonated Concrete (탄산화 및 비탄산화된 콘크리트의 투수계수의 해석 기법 개발)

  • Yoon, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.21 no.3
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    • pp.255-264
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    • 2009
  • Permeability coefficient of concrete is a substaintial key parameter for understanding the durability performance of concrete and its microstructural densification. Many researches for the issue have been accomplished, however, it is very rare to deal with the theoretical study on permeability coefficient in connection with carbonation of concrete and the the effect of volumetric fraction of cement paste or aggregate on the permeability coefficient. The majority of these researches have not dealt with this issue combined with carbonation of concrete, although carbonation can significantly impact on the permeability coefficient of concrete. The purpose of this study is to establish a fundamental approach to compute the permeability coefficeint of (non)carbonated concrete. When simulating a microstructural characteristics as a starting point for deriving a model for the permeability coefficient by the numerical simulation program for cementitious materials, HYMOSTRUC, a more realistic formulation can be achieved. For several compositions of cement pastes, the permeability coefficient was calculated with the analytical formulation, followed by a microstructure-based model. Emphasis was on the microstructural changes and its effective change of the permeability coefficient of carbonated concrete. For carbonated concrete, reduced porosity was calculated and this was used for calculating the permeability coefficeint. The computational result was compared with experimental outcome.

A Study on the Concrete Surface of Durability Advancement and Performance Improvement for the Siliceous Liguid Type of Spread Waterproofing Material (콘크리트 표층부 내구성 증진 및 성능개선을 위한 규산질계 액상형 도포 방수재의 성능 평가 연구)

  • Kim Jin-Sung;Song Je-Young;Park Jin-Sang;Oh Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.05a
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    • pp.29-32
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    • 2005
  • It is recognised that a permeability waterproof agent have been extensively used for concrete, in these days. In present paper shows effective practical scheme of a permeability waterproof agent in construction market that is to develope durability of concrete structure as apply to job site through the examination physical and chemical property of a permeability waterproof agent. It is indentified that can be maintain waterproofing performance, moreover it makes satisfactory result of permeation resistance as applying siliceous waterproof agent.

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Mass Transfer and Heat Transfer Characteristics of PEM fuel cell by Permeability of GDL (GDL Permeability에 따른 고분자 전해질 연료전지의 물질전달 및 열전달 특성에 관한 연구)

  • Han, Sang-Seok;Lee, Pil-Hyong;Park, Chang-Soo;Lee, Jae-Young;Hwang, Sang-Soon
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2822-2827
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    • 2008
  • Among the main components of PEM fuel cell, the functions of GDL are to transport reactants from the channel to the catalyst and remove reaction products from the catalyst and transport heat from the catalyst to the channels in the flow filed plate. Permeability of GDL is known to make it possible to enhance the gas transport through GDL, devoting to get better performance. In this paper, three dimensional numerical simulation of the fuel cell by the permeability of GDL is presented by using a FLUENT modified to include the electrochemical behavior. Results show that as permeability is higher than $10^{-12}m^2$, gradients of temperature distribution, oxygen molar concentration and current density distribution in MEA were decreased. Although heat generation was increased as high permeability, MEA's temperature was lower than the low permeability of GDL. This seems because that convection was higher affects in mass and heat transfer process than diffusion as permeability of GDL is increases.

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A Study on the Evaluation of Durability of Fiber Reinforced Concrete According to the Change of External Conditions (외부조건의 변화에 따른 섬유보강콘크리트의 내구성능 정가에 관한 연구)

  • Kim, Nam-Wook
    • Journal of the Korean Society of Safety
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    • v.23 no.5
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    • pp.97-104
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    • 2008
  • This study was intended to evaluate the permeable performance through a change of reinforcing materials, curing condition, durability evaluation and permeability test, and to select the reinforcing material which could reduce the durability and water tightness from it, as the study for considering how the change of the outside's environment factors that the concrete structure actually contacted with impacted the concrete's durability especially the permeability by referring to such the background of the study. Accordingly, it was judged that evaluating the permeability by considering the severe environment condition where the concrete structure was placed in was more reasonable than measuring the existing permeability coefficient conducted in the sound state for the permeability evaluation of actually-used concrete structure. In this study, it also could be known that the specimen of hybrid fiber reinforced concrete which mixed the long and short steel fiber was the most effective for water tightness enhancement in severe environmental conditions.