• Title/Summary/Keyword: Pentane

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Thermal Wave Transfer and Combustion Response of Droplet Perturbed by Acoustic Pressure (압력파에 교란된 액적내부에서의 에너지 파동 및 반응 메커니즘)

  • Lee Cilyong;Yoon Woongsub
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • v.y2005m4
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    • pp.183-188
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    • 2005
  • This study targets to investigate thermal wave transfer in a droplet strongly coupled with acoustic pressure and its effects on combustion response. The one-dimensional vaporization model uses SRK equation of state and flash calculation method to obtain more accurate thermophysical properties and compute vapor-liquid equilibrium. Calculations of an n-pentane droplet exposed into a perturbing nitrogen gas is carried out in terms of different ambient gas pressures and wave frequencies. The thermal wave is transferred more effectively at lower frequencies, which results in the decrease in the amplitude of the response.

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Film Boiling Heat Transfer Characteristics in Liquid-Liquid System (액체,액체계의 막비등열전달 특성)

  • 김병주
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.1
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    • pp.87-94
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    • 1992
  • Film boiling heat transfer characteristics in liquid-liquid systems are studied experimentally. Liquid gallium as a heating liquid, n-pentane, freon-113, and ethanol are used as boiling liquids. In gallium-n-pentane and gallium-freon-113 systems the minimum film boiling point occurred at higher temperature than those observed in copper-boiling liquid systems. However MFB point occurred almost at the same temperature for the case of ethanol. This difference are due to the effects of contact angle and interfacial agitations in gallium-boiling liquid systems. Film boiling heat transfer rate, for the gallium-boiling liquid systems considered in this work, found to be approximately 10% higher than those in copper-boiling liquid systems, whose main cause is believed to be gallium-boiling liquid interfacial agitations affected by the density ratio between gallium and boiling liquid.

Spectroscopic characterization of N,N'-bis(salicylidene)pentane-1,3-diamine nickel(II) complex

  • Kim, Gilhoon;Won, Hoshik
    • Journal of the Korean Magnetic Resonance Society
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    • v.18 no.2
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    • pp.74-81
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    • 2014
  • The $N_2O_2$ tetradentate Schiff base ligand, N,N'-bis(salicylidene)pentane-1,3-diamine (Salpn), coupled with 1:2 concentration ratio of 1,3-diaminopentane and salicylaldehyde was used to produce a series of macrocyclic Nikel(II) complexes. In the metal complexation, it was observed that Salpn macrocyclic ligand can adopt more than a metal ion giving an unique multinuclear metal complexes including Ni(II)Salpn and $Ni(II)_3(Salpn)_2$. Characteristic IR ${\upsilon}(M-O)$ peaks for Ni(II)Salpn and $Ni(II)_3(Salpn)_2$ were observed to be $1028cm^{-1}$ and $1024cm^{-1}$, respectively. Characteristic UV-Vis absorption ${\lambda}_{max}$ peaks for $Ni(II)_3(Salpn)_2$ were observed to be 241nm and 401 nm. Structural characterization of $Ni(II)_3(Salpn)_2$ by NMR exhibits that the salicylidene ring moiety has two different resonance signals originated from the magnetically asymmetric diligand and trinuclear bis complex. Complete NMR signal assignments and characterizations elucidating structural features of $Ni(II)_3(Salpn)_2$ were described in detail.

Effect of Temperature, Pressure, and Air Flow Rate on VOCs Desorption for Gasoline Vapor Recovery (유증기 회수를 위한 VOCs 탈착에 미치는 온도, 압력 및 공기유량의 영향)

  • Lee, Song-Woo;Na, Young-Soo;Kam, Sang-Kyu;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.22 no.9
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    • pp.1131-1139
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    • 2013
  • Desorption characteristics of VOCs were investigated for the effective recovery of gasoline vapor. The adsorption capacity and desorption capacity were excellent at relatively low temperatures. The differences in the desorption capacity were not large in the condition; desorption temperature $25^{\circ}C$, desorption pressure 760 mmHg, inlet air flow rate 0.5 L/min, but were relatively great in the condition; desorption temperature $0^{\circ}C$, desorption pressure 60 mmHg, inlet air flow rate 1.0 L/min. The desorption ability of pentane was increased to about 81.4%, and the desorption ability of hexane was increased to about 102%, also the desorption ability of toluene was increased to about 156.7% by changes of temperature, pressure, inlet air flow rate in the experimental conditions. The optimum desorption condition for the effective recovery of VOCs was in the conditions; desorption temperature $0^{\circ}C$, desorption pressure 60 mmHg, inlet air flow rate 1.0 L/min.

Effect of Blowing Agents on Properties of Phenolic Foam (발포제 종류에 따른 페놀 폼의 물성 연구)

  • Jang, SaeYoon;Kim, Sangbum
    • Journal of the Korean Institute of Gas
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    • v.20 no.2
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    • pp.30-34
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    • 2016
  • In this study, we synthesized a phenol foam using a resol-type phenol resin as a research for replacing the polyurethane foam used as an insulator for cryogenic temperature, such as LNG or LPG. Foaming agents for synthesizing a phenolic foam was used HCFC-141b or n-pentane, cyclopentane, n-hexane, cyclohexane and a mixture of HFC-365mfc and HFC-227ea respectively. Cyclohexane as a blowing agent exhibited the most superior insulating performance and compressive strength. The heat resistance of polyurethane foam and phenolic foam blown by the cyclohexane, was higher than polyurethane foam.

Development of Solar Powered Water Pump - Energy conversion test and performance analysis - (태양열을 동력원으로 한 물펌프 연구개발 - 에너지변환실험과 성능해석 -)

  • 김영복;이양근;이승규;김성태;나우정;정병섭
    • Journal of Biosystems Engineering
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    • v.27 no.4
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    • pp.327-334
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    • 2002
  • In this study, energy conversion from thermal energy to mechanical power by using n-pentane was tested and exergy variation, cycle number, water quantity pumped and thermal efficiency were analyzed. The energy conversion was done and the water head could be ten meters on the experimental conditions. The operating temperature range of cycle was recommended to be around the liquid-vapour saturation temperature of the working fluid on the viewpoint of the maximum work. The cycle diagram was analyzed by the exergy analysis. For the constant water head, the cycle number was decreased and the water quantity per day was increased and thermal efficiency become higher when the water quantity per cycle become increasing. For the constant pumping water quantity per cycle, cycle number and the water quantity per day was decreased and the thermal efficiency become higher because the saturation temperature become higher when the water head become higher.

Formation of Fruit Aroma Compounds from Whey by Kluyverumyces lactis (Kluyveromyces lactis에 의한 유청으로부터 과일향 성분의 생성)

  • 김소미;이형주
    • Microbiology and Biotechnology Letters
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    • v.19 no.5
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    • pp.536-541
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    • 1991
  • To enhance the productivity of fruit flavor compounds from whey by the lactose fermenting yeast, Kluyveromyces lactzs ATCC 8585 was treated with N-methyI-N'-nitro-N-nitrosoguanidine (NTG). After the NTG treatments, a mutant showing resistance to antifungal activity of geraniol, and strong fruity but low yeasty flavor was selected and named as K. lactis 450 K. Flavor compounds from 3-day culture broth were extracted with pentane-dichloromethane (2:l) and the concentrated oleoresins were analyzed by gas chromatography. The mutant strain produced more classes and larger amount of flavor compounds than the parent stlain. Tentatively identified volatile compounds from the culture of the mutant were: terpenes such as myrcenol; alcohols such as cis-3-hexenol, n-hexanol; esters such as ethyl isovalerate, cis- 3-hexenyl n-butyrate, n-amyl-n-hexanoate, phenyl ethyl n-propioate; ketones such as methyl vinyl ketones; other compounds such as vanillin, 3-methylcoumarin.

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Copolyester Studies VIII. Crystallization Behaviours of Poly(ethylene terephthalate) Modified by the Flexible Diol Unit (Polyester의 개질에 관한 연구 (제8보). 유연한 디올 Unit로 개질된 Poly(ethylene terephthalate)의 결정화 거동)

  • Tae Oan Ahn;Jung Ho Kim;Han Mo Jeong
    • Journal of the Korean Chemical Society
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    • v.32 no.3
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    • pp.276-284
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    • 1988
  • The crystallization behaviours of poly(ethylene terephthalate) modified by 1, 3-propane diol, 1, 5-pentane diol, 1, 6-hexane diol, or poly(ethylene glycol) of molecular weight 300 as a third component were studied by isothermal and nonisothermal crystallization. When the content of the third diol was about 4 mol %, the isothermal crystallization rate at the same supercooling below the melting temperature and the nonisothermal crystallization rate at the same overheating above the glass transition temperature were increased more by the shorter flexible diol unit. On the contrary the nonisothermal crystallization rate at the same supercooling below the melting temperature was increased more by the longer flexible diol unit.

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A Study on the Risk Assessment and Mitigation Plan about Fire Explosion of n-Pentane in EPS Process (EPS공정에서 발생하는 n-Pentane의 화재폭발에 대한 위험성평가 및 위험성 완화 대책에 관한 연구)

  • Seo, Min Su;Kim, Ki Sug;Kim, Bo Min;Kang, Dong Cheon;Kang, Kil Jae;Chon, Young Woo
    • Korean Journal of Hazardous Materials
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    • v.6 no.2
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    • pp.39-46
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    • 2018
  • 최근 전자제품 생산업체에서 EPS를 직접생산하게 되면서 EPS 공정이 증가하고 있다. EPS에는 펜탄이 포함되어 있으며, 펜탄은 하이브리드 혼합물로 구분할 수 있어 높은 화재폭발의 위험성을 가지고 있다. 각 공정별 펜탄의 누출률은 발포기, 사일로실, 저장실 순이나 발포기의 경우 일반적으로 밀폐되어 있으므로 사일로 실이 가장 화재폭발 위험성이 높다고 판단하였다. 사일로실의 누출률 중 70%는 사일로 상단을 통해 누출되며, 사일로 상단을 통해 누출되는 펜탄의 거동을 분석하여 사일로실 위험성 완화대책을 수립하였다. 1. 폭발위험구역 2종으로 관리, 2. 사일로상단 50cm이내 환기설비 설치 또는 Push-Pull 구조의 환기설비설치, 3. 사일로 하단 1.4m이내에 가스감지기 설치, 4. 60%이상의 습도유지

Measurement and Estimation of VOC Composition from Gasoline Evaporation

  • Na, K.;Moon, K.-C.;Kim, Y.P.
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.E3
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    • pp.101-107
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    • 2001
  • Source profiles were developed for a total of 45 volatile organic compounds (VOC) that can be emitted from gasoline evaporation. The gasoline samples of five major brands (for each season) were blended on the basis of the market share in Seoul area and analyzed by a GC-MS/FID system. In addition, we calculated gasoline evaporative compositions using the Raoult's law from the liquid gasoline compositions. The measured and estimated gasoline vapor compositions agree well each other. As a group, alkanes are the most abundant in the gasoline vapors profiles (77.4% on average), followed by alkenes (19.1%), and aromatics (1.7%). As a specie in gasoline vapor, i-pentane is the most abundant, followed by n-butane, n-pentane, i-butane, trans-and cis-2-butenes, 2-methyl-2-butene, and trans-and cis-2-pentenes . It was also seen that aromatic content was much lower in the vapor phase compositions. From the comparison between experimental and calculated compositions, we identified the fact that once the gasoline vapor composition is reliably constructed entirely from the measured gasoline composition and the Raoult's law calculations, the need for doing separate chemical analyses of the gasoline vapor can be reduced.

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