• Journal of the Korean Ceramic Society
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• v.35 no.5
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• pp.499-504
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• 1998

ZnO varistors having a composition of 98.0 mol% ZnO 1.0 mol% $Bi_2O_3$ 0.5 mol% $MnO_2$ were prepared by the Pechini process and the sintering behavior and electrical characteristics were studied. ZnO varis-색 powder with $1.5\mu\textrm{m}$ mean diameter and narow particle size distribution was obtained using the Pechni pro-cess. Typical intermediate stage grain growth of liquid phase sintering was observed by sintering at $1100^{\circ}C$ At this temperature ZnO varistors having uniform grain size and Bi-rich liquid phase distributed uniformly along grain boundaries were prepared. The nonlinear coefficients of the ZnO varistors were in the range of 40-60 The breakdown voltages of the varistors were nearly inversely propeortional to the grain size which reflects that ZnO varistors prepared by the Pechini process have uniform distribution of Bi-rich liquid phase along grain boundaries It is believed that the microstructures of ZnO varistors can be controlled effectively by using the Pechini process which makes the control of the electrical properties of ZnO varistors possible.

• 한국전기화학회:학술대회논문집
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• 2002.07a
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• pp.117-122
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• 2002

고체산화물 연료전지의 구성요소인 양극(공기극)을 GNP와 Pechini 법을 이용하여 $(La{1-x}Sr_x)MnO_3$ 양극을 합성하여 합성한 분말의 특성과 단위전지로 사용하기 위한 조건에서의 특성을 측정하였다. GNP로 합성한 분말의 경우 직접 $(LaSr)MnO_3$ 단일 결정상을 얻을 수 있었으나, Pechini 법으로 합성한 분말의 경우는 비정질이었다. 또한 각각의 방법으로 합성한 분말의 입자형태는 구형이었고 1차상 입자크기는 GNP가 40nm, Pechini, 법으로 합성한 경우 20nm 정도의 크기를 갖고 있었다. GNP로 합성한 분말의 입자크기와 비표면적의 경우 glycine의 첨가량이 증가함에 따라 입자크기는 감소하였으나 최적 glycine 첨가량은 2.0mole 였고, 이 때 평균2차상의 입자크기는 $13.24{\mu}m$로 agglomeration 되어있었다. 최적 cathode조성은 GNP법으로 합성한 $(La_{0.9}Sr_{0.1}MnO_3$로서 가능하였고, 이 조성에서의 열팽창계수는 $9.89\times10^{-6}/^{\circ}C$이고, 전기전도도($1200^{\circ}C$에서 2시간소결)는 110 S/cm을 나타내었다.

• 한국정보디스플레이학회:학술대회논문집
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• 2008.10a
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• pp.1247-1250
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• 2008

This presentation highlights work from the authors' laboratories on the various kinds of oxide optical materials, mainly luminescence and pigment materials with different forms (powder, core-shell structures, thin film and patterning) prepared by the Pechini-type sol-gel (PSG) process. The PSG process which uses the common metal salts (nitrates, acetates, chlorides etc) as precursors and citric acid (CA) as chelating ligands of metal ions and polyhydroxy alcohol (such as ethylene glycol or poly ethylene glycol) as cross-linking agent to form a polymeric resin on molecular level, allowing the preparation of many forms of luminescent materials.

• Journal of Powder Materials
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• v.17 no.1
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• pp.59-64
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• 2010

8 mol% Y-doped $SrTiO_3$ powder was synthesized by Pechini method from titanium isopropoxide, strontium nitrate, yttrium nitrate, citric acid and ethylene glycol. A $Y_2Ti_2O_7$ pyrochlore phase-free perovskite powder was obtained by calcining a polymeric resin, which was prepared from a precursor solution, at $500^{\circ}C$ in an air atmosphere. Low temperature calcination could lead to a fine-grained microstructure. In the case of a solid-state reaction, an extended heat-treatment at high temperature in a reduced atmosphere needed to obtain a single phase perovskite $SrTiO_3$.

• Proceedings of the Korean Ceranic Society Conference
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• 2003.04a
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• pp.180.1-180
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• 2003

• Proceedings of the Korean Ceranic Society Conference
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• 2000.10a
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• pp.60.2-60
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• 2000

• Proceedings of the Materials Research Society of Korea Conference
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• 2005.05a
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• pp.178-178
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• 2005

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.9 no.5
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• pp.480-485
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• 1999

The $SrTiO_3$ with Al, Pr red phosphor for FED was synthesized by Pechini process using metallic nitrates, ethylene glycol and citric acid. The different particle growth tendency of $SrTiO_3$ phosphor powder was observed at above and below $900^{\circ}C$. Also, luminescent properties were observed under 359 nm excitation of Pr ion. The emission band was shown between 575 nm and 650 nm with 617 nm maximum spectra. Therefore, $SrTiO_3$ with Al, Pr phosphor is applicable to red phosphor of FED.

• Korean Journal of Materials Research
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• v.12 no.7
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• pp.517-521
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• 2002

Europium-activated $Ga_2$$O_3$ phosphor powders were prepared by Pechini method from the mixed aqueous solutions of gallium(III) nitrate, europium(III) nitrate, ethylene glycol and citric acid. The phase formation process and particle shape of the powders obtained were investigated by means of TG/DTA, XRD and SEM. It was found that the powders were amorphous or ${\gamma}$-$Ga_2$$O_3$-like phase up to $500^{\circ}C$ and then transformed into $\beta$- $Ga_2$$O_3$ phase above $600 ^{\circ}C$. The powders calcined below $1000^{\circ}C$ were spherical and nanometer-sized. Photoluminescence spectra measured at room temperature showed that the highest luminescence intensity was obtained for the sample synthesized under the conditions of 2 mol% Eu concentration and heat treatment at $1000^{\circ}C$.

• Journal of Powder Materials
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• v.30 no.5
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• pp.436-441
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• 2023

Molybdenum-tungsten (Mo-W) alloy sputtering targets are widely utilized in fields like electronics, nanotechnology, sensors, and as gate electrodes for TFT-LCDs, owing to their superior properties such as high-temperature stability, low thermal expansion coefficient, electrical conductivity, and corrosion resistance. To achieve optimal performance in application, these targets' purity, relative density, and grain size of these targets must becarefully controlled. We utilized nanopowders, prepared via the Pechini method, to obtain uniform and fine powders, then carried out spark plasma sintering (SPS) to densify these powders. Our studies revealed that the sintered compacts made from these nanopowders exhibited outstanding features, such as a high relative density of more than 99%, consistent grain size of 3.43 ㎛, and shape, absence of preferred orientation.