• Title/Summary/Keyword: PdPt/C

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$H_2$ sensor for detecting hydrogen in DI water using Pd membrane (수중 수소 감지를 위한 MISFET형 센서제작과 그 특성)

  • Cho, Yong-Soo;Son, Seung-Hyun;Choi, Sie-Young
    • Journal of Sensor Science and Technology
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    • v.9 no.2
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    • pp.113-119
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    • 2000
  • In this work, Pd/Pt gate MISFET sensor using Pd membrane was fabricated to detect the hydrogen in DI water. A differential pair-type was used to minimize the intrinsic voltage drift of the MISFET. To avoid hydrogen induced drift of the sensor, the silicon dioxide/silicon nitride double layer was used as the gate insulator of the FET's. In order to eliminate the blister formation on the surface of the hydrogen sensing gate metal, Pd/Pt double metal layer was deposited on the gate insulator. For this type of application sensors need to be isolated from the DI water, and a Pd membrane was used to separate the sensor from the DI water. The output voltage change due to the variation of hydrogen concentration is linear from 100ppm to 500 ppm.

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NOx Sensing Characteristics of the $WO_{3}$-Based Thin-Film Gas Sensors (박막형 $WO_{3}$계 가스센서의 NOx 감도 특성)

  • Yoo, Kwang-Soo
    • Journal of Sensor Science and Technology
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    • v.5 no.5
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    • pp.39-46
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    • 1996
  • The Pd or Pt-doped $WO_{3}$ thin-film NOx sensor was fabricated. The $WO_{3}$-based thin films as a gas-sensing layer were deposited at ambient temperature in a high-vacuum resistance heated evaporator and annealed at $500^{\circ}C$. The gas sensitivity ($R_{gas}/R_{air}$) to 5 ppm $NO_{2}$ measured at the operating temperature of $300^{\circ}C$ was 50 (highest sensitivity) for the 0.5 wt.% $Pt-WO_{3}$ sensor.

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Fabrication of Hydrogen Sensors Using Graphenes Decorated Nanoparticles and Their Characteristics (나노입자가 코팅된 그래핀 기반 수소센서의 제작과 그 특성)

  • Kim, Kang-San;Chung, Gwiy-Sang
    • Journal of Sensor Science and Technology
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    • v.21 no.6
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    • pp.425-428
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    • 2012
  • This paper presents the fabrication and characterization of graphene based hydrogen sensors. Graphene was synthesized by annealing process of Ni/3C-SiC thin films. Graphene was transferred onto oxidized Si substrates for fabrication of chemiresistive type hydrogen sensors. Au electrode on the graphene shows ohmic contact and the resistance is changed with hydrogen concentration. Nanoparticle catalysts of Pd and Pt were decorated. Response factor and response (recovery) time of hydrogen sensors based on the graphene are improved with catalysts. The response factors of pure graphene, Pt and Pd doped graphenes are 0.28, 0.6 and 1.26, respectively, at 50 ppm hydrogen concentration.

Pd/Si/Ti/Pt Ohmic Contact for Application to AlGaAs/GaAs HBT (AIGaAs/GaAs HBT 응용을 위한 Pd/Si/Ti/Pt 오믹 접촉)

  • 김일호;박성호(주)가인테크
    • Journal of the Korean Vacuum Society
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    • v.10 no.3
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    • pp.368-373
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    • 2001
  • Pd/Si/Ti/Pt ohmic contact to n-type InGaAs was investigated. As-deposited contact showed non-ohmic behavior, and high specific contact resistivity of $5\times10^{-3}\Omega\textrm{cm}^2$ was achieved by rapid thermal annealing at $375^{\circ}C$ for 10 seconds. However, the specific contact resistivity decreased remarkably to $1.7\times10^{-6}\Omega\textrm{cm}^2$ and $2\times10^{-6}\Omega\textrm{cm}^2$ at $375^{\circ}C$/60sec and $425^{\circ}C$/10sec, respectively. Superior ohmic contact and non-spiking planar interface between ohmic materials and InGaAs were maintained even at $450^{\circ}C$, therefore, this thermally stable ohmic contact system is a promising candidate for compound semiconductor devices.

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Selective Catalytic Oxidation of Ammonia over Noble Catalysts Supported on Acidic Fe-ZSM5 Supports (산성 Fe-ZSM5 담체에 담지된 귀금속 촉매를 활용한 암모니아의 선택적 산화반응)

  • Kim, Min-Sung;Lee, Dae-Won;Lee, Kwan-Young
    • Clean Technology
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    • v.18 no.1
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    • pp.89-94
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    • 2012
  • In this study, we investigated the activity of Pd and Pt supported on acidic Fe-ZSM5 supports for selective catalytic oxidation of ammonia ($NH_3$-SCO). Among the catalysts, Pt/Fe-ZSM5 catalyst exhibited superior $NH_3$-SCO activity to Pd/Fe-ZSM5 catalyst. We also tested Pt/Fe-ZSM5 catalysts with different Fe loading using ion-exchange method to prepare Fe-ZSM5 supports, which resulted in the increased catalytic performance with smaller Fe content: $NH_3$ was oxidized completely at low temperature ($250^{\circ}C$). The physicochemical properties of Fe-ZSM5 were investigated to figure out the relationship between the characteristics of the catalysts and the catalytic activity on $NH_3$-SCO by Inductively coupled plasma-atomic emissions spectrometer (ICP-AES), $N_2$ sorption, X-ray diffraction (XRD), temperature programmed desorption of $NH_3$ ($NH_3$-TPD) technique.

Characterization of Alternative Anode Catalysts for Direct Formic Acid Fuel Cell (직접 개미산 연료전지용 연료극 촉매의 특성 연구)

  • Yu, Jae Keun;Lee, Hyo Song;Kim, Ki Ho;Kim, Young Chun;Han, Jong Hee;Oh, In Hwan;Rhee, Young Woo
    • Korean Chemical Engineering Research
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    • v.44 no.3
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    • pp.314-318
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    • 2006
  • Direct formic acid fuel cells (DFAFCs) are potential alternative power sources for portable devices such as cellular phone, personal digital assistants (PDA) and laptop computers. In this study, we developed the catalysts for great performance of fuel cell, and investigated their characteristics by using EDS and SEM. Pt-Pd catalysts showed uniform size and homogeneous distribution. As the content of palladium increased, the performance of DFAFC increased. Pd black showed the greatest performance among the five catalysts tested. Also, Pt-Pd (1:1) catalyst had an excellent maximum power density of $120mW/cm^2$. As the operating temperature increased, fuel cell performance was increased due to a reaction activity increases of catalyst. But, temperature had only a slight effect on the performance of fuel cell in the best activity range of membrane.

Study on the Corrosin Properties of Au-Ag-Cu Dental Alloys (치과용 Au-Ag-Cu계 합금의 부식특성에 관한 연구)

  • Kim, Bu-Sob
    • Journal of Technologic Dentistry
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    • v.14 no.1
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    • pp.23-43
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    • 1992
  • Corrosion characteristics of four commerial gold-based dental alloys(C-1; Au75%, Ag13.9%, Pd3%, Cu & etc.,8.1%, C-2 ;Au 52.08, Ag 24%, Pd 5%, Cu & etc.,18.92, C-3 ; Au 53%, Ag 22%, Pd 5%, Pt 3% Cu & etc.,17%, C-4 ; Au 53%, Pd4, Pt1.5%, Ag & Cu & etc.,41.5%) and four experimental ternary Au-Ag-Cu alloys(E-1 ; Au 50%, Ag 30%, Cu 20%, E-2 ; Au 50%, Ag 20%, Cu 30%, E-3 ; Au 50%, Ag 10%, Cu 40%, E-4 ; Au 50%, Ag 40%, Cu 10%) were investigated by potentiodynamic polarization analysis and the structure was examined by optical microscope and SEM. All corrosion testing was conducted in 1% NaCl solution. The main results are as follows : 1. The corrosion resistence of commercial alloys was decreased in the order of C-1, C-3, C-4, C-2. C-2. 2. The E-1 and E-3 ternary alloys exhibits the higher corrosion resistence than E-2 and E-4 alloys. 3. The cast microstructure of alloys reveals dendrite morphology which shows the significant microsegregation caused by the difference in the diffusion rate between liquid and solid. 4. It is found that the surface corrosion products were mainly AgCl by X-ray diffraction results.

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A study on PZT capacitor on the glass substrate (유리 기판 위에서의 PZT 캐패시터에 관한 연구)

  • Ju, Pil-Yeon;Park, Young;Jeong, Kyu-Won;Song, Joon-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04b
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    • pp.80-83
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    • 2000
  • The post-annealing treatments on rf magnetron sputtered PZT($Pb_{1.05}(Zr_{0.52},\;Ti_{0.48})O_3$) thin films($4000{\AA}$) have been investigated for a structure of PZT/Pt/Ti/Coming glass(1737). Crystallization properties of PZT films were strongly dependent on RTA(Rapid Thermal Annealing) annealing temperature and time. We were able to obtain a perovskite structure of PZT at $650^{\circ}C$ and 10min. P-E curves of Pd/PZT/Pt capacitor demonstrate typical hysteresis loops. The measured values of $P_r$, $E_c$ were $8.1[{\mu}C/cm^2]$, 95[kV/cm] respectively. Polarization value decrease about 25% after $10^9$ cycles.

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Saponin and Ginsenoside Content in Korean Red Ginseng Products (고려홍삼 제품류의 사포닌 및 진세노사이드 함량)

  • 최강주;고성룡
    • Journal of Ginseng Research
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    • v.13 no.2
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    • pp.178-182
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    • 1989
  • Red ginseng products manufactured by the Korea Ginseng and Tobacco Corporation were analyzed to determine the crude saponin , total saponin and ginsenoside contentents by gravimetry, spertrometry and HPLC, respectively, to see if effective quality control of the components in the products can be achieved. Medicinal powders, powders, tablets and capsules which were made from ginseng powder showed similarity in saponin content, the ratio of PD to PT saponin, and the ginsenoside content and composition, while extract powder, extract, extract tea, extract pills and tea, which were made of ginseng extract, showed difference in saponin content, ratio of PD to PT saponin, and the content and composition of ginsengside. It is, accordingly, believed that ginseng products which are uniform in contents and saponin composition can be produced by carrying out strict quality control throughout the processes of making raw red ginseng into final products.

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Effects of Panax Ginseng on the Development of Morphine Induced Tolerance and Dependence(III) -Effects of Protopanaxadiol Fraction and Prtopanaxatriol Fraction in Mice- (모르핀의 내성 및 의존성 형성에 미치는 인삼의 효과(III) -인삼의 Protopanaxadiol 분획 및 Protopanaxatriol 분획의 영향-)

  • 김학성;오세관;최강주;이해빈
    • YAKHAK HOEJI
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    • v.29 no.4
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    • pp.188-192
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    • 1985
  • Protopanaxadiol (PD) fraction and protopanaxatriol (PT) fraction were separated from thebutanol fraction of panax ginseng roots. Each group of mice was injected with morphine hydrochloride (40 mg/kg s.c.) three times at 8 hr intervals for a period of 6 days. PD fraction and PT fraction were injected (25, 100 mg/kg i.p.) to mice 1 hr prior to the third morphine injection daily. Inhibition of morphine tolerance was evidenced by the increase in analgesic response to morphine hydrochloride (10mg/ kg i.p.) as estimated by the tail flick method. Inhibition of morphine tolerance by PT fraction was effective but there was no remarkable difference in inhibition of tolerance development between control group andPD fraction group.

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