• Title/Summary/Keyword: Pd complex

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Implementation of a Condition Monitoring System for Mold Transformers in DC Substations (DC 변전소 몰드변압기 온라인 상태 감시 시스템 구현)

  • Park, Young;Jung, Ho-Sung;Park, Chul-Min;Jang, Soon-Ho
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.9
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    • pp.1788-1794
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    • 2011
  • The mold transformer is a complex and critical component of DC substations in Metro system. In this paper, a cost effective and intelligent condition monitoring system for mold transformers in DC substations was developed. This paper also provides an overview of the management program using PD (partial discharge) data on mold transformers. Prior to application of the proposed system to Metro DC substations, experiments were performed at the metro line substation located in Seoul and presented case studies for the use of the intelligent condition monitoring system for mold transformer in DC substations. The experiment results indicated that the developing system can be need in helping mange the risk of unexpected failure of mold type transformers.

Well-Defined series and parallel D-spectra for preparation for linear time-varying systems (선형 시변 시스템에 대한 잘 정의된 (well-defined) 직렬 및 병렬 D-스펙트럼)

  • Zhu, j.jim;Lee, Ho-Cheol;Choe, Jae-Won
    • Journal of Institute of Control, Robotics and Systems
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    • v.5 no.5
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    • pp.521-528
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    • 1999
  • The nth-order, scalar, linear time-varying (LTV) systems can be dealt with operators on a differential ring. Using this differential algebraic structure and a classical result on differential operator factorizaitons developed by Floquet, a novel eigenstructure(eigenvalues, eigenvectors) concepts for linear time0varying systems are proposed. In this paper, Necessary and sufficient conditions for the existence of well-defined(free of finite-time singularities) SD- and PD- spectra for SPDOs with complex- and real-valued coefficients are also presented. Three numerical examples are presented to illustrate the proposed concepts.

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The distance and polarization characteristics of electromagnetic wave radiated at needle-to-plane electrodes in Air and complex dielectric (공기 및 복합유전체 갭에서의 방사전자파의 거리 및 편파특성)

  • 김충년;이현동;박광서;박원주;이광식;이동인;이동헌
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2000.11a
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    • pp.241-245
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    • 2000
  • In this paper, VHF(30~230[MHz]) electromagnetic waves radiated from partial discharge(PD) at two-type electrodes in air are measured and the peculiar patterns of their spectra are reported. Also, the polarization and distance characteristics of electromagnetic wave rediated by PD, were investigated. In case of epoxy insulator in inserted, the noise level of radiated electromagnetic waves is 0.6~6.2[dB] higher than the case in air at below 90[MHz]. The frequency spectrum distribution of radiated electromagnetic waves appears different in the whole frequency range according to the arrangement of antenna.

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A Study on a Neuro-Fuzzy Controller Design (뉴로-퍼지 제어기 설계 연구)

  • Im, Jeong-Heum;Chung, Tae-Jin
    • Proceedings of the KIEE Conference
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    • 2002.07d
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    • pp.2120-2122
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    • 2002
  • There are several types of control systems that use fuzzy logic controller as a essential system component. The majority of research work on fuzzy PID controller focuses on the conventional two-input PI or PD type controller. However, fuzzy PID controller design is a complex task due to the involvement of a large number of parameters in defining the fuzzy rule base. In this paper we combined conventional PI type and PD type fuzzy controller and set the initial parameters of this controller from the conventional PID controller gains obtained by Ziegler-Nichols tuning or other coarse tuning methods. After that, by replacing some of these parameters with sing1e neurons and making them to be adjusted by back-propagation learning algorithm we designed a neuro-fuzzy controller which showed good performance characteristics in both computer simulation and actual application.

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Improvements of the Public Pedestrian Passage in the Apartment Complex from Crime Prevention Through Environmental Design Aspect (범죄예방 환경설계 관점에서 공동주택 단지 내 공공보행통로의 개선방안 연구)

  • Lee, Seung-Ji
    • Journal of the Architectural Institute of Korea Planning & Design
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    • v.34 no.6
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    • pp.135-142
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    • 2018
  • A public pedestrian passage induces traffic into the apartment complex, and therefore, it requires the application of Crime Prevention Through Environmental Design(CPTED). This paper aims to analyze the conditions and to suggest the improvements of public pedestrian passages in apartment complexes, applying a 3-D approach from CPTED aspect. The first aspect is "Designation": 1)The linkage between the public pedestrian passages is weak, and their designated purpose becomes unclear. 2)When the designated purpose is not considered for each complex, the closure rate is high. 3)The closure rate of the "Through type" is high. It suggests that the pedestrian network should be built and vitalized at the local urban level. The second aspect is "Definition." The public pedestrian passage lacks a social, cultural, and legal definition and only has a passive physical definition. It suggests that a legal definition and specialized guildline be prepared. The third aspect is "Design": 1)Insufficient territoriality exists between the public pedestrian passage and the inside of the complex. Territoriality should be reinforced between the public pedestrian passage and the rest of the internal territory. 2)The landscaping adjacent to the public pedestrian passage lacks deliberation. Since this is where safety and privacy collide, detailed design and maintenance of the landscaping is required. 3)It lacks systematical crime prevention facilities and should compensate accordingly.

A Consideration of the Present Status of Support for Community Revitalization in the Japanese UR Rental Housing Complex (일본 UR임대주택단지의 커뮤니티활성화 지원실태에 관한 고찰)

  • Lee, Su-Jin
    • Journal of the Architectural Institute of Korea Planning & Design
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    • v.36 no.3
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    • pp.103-111
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    • 2020
  • This study aims to analyze community support methods and specific attainments of UR rental housing complex S in Japan and examine the present state of community formation.. UR rental housing S is part of the community revitalization support project launched by UR Urban Agency for creating exchanges among residents in the rental housing complex and in this study, the community support project from February to November 2013 was considered. As community revitalization support tasks, five types of events and exchange meetings were held. While the events and exchange meetings continued, even the residents who did not join the residents' association began to make an exchange with each other and their identity as residents enhanced, which means there was a change in the sense of community. Moreover, it is thought that a good solution to maintaining the chance for the events and exchange meetings after the support project is that residents of the younger generation actively cooperate in management as the residents' association members. 5 years after the support project, the present condition of activities of complex residents was examined, but the Residents' Association was disbanded due to the aging of residents, a growth in residents and low participation rates of the younger generation. Besides, there is a complete absence of community activities in the complex now.

Protocol of a Nationwide Observational Study among Patients with Nontuberculous Mycobacterium Pulmonary Disease in South Korea (NTM-KOREA)

  • Kwak, Nakwon;Choi, Hongjo;Jeon, Doosoo;Jhun, Byung Woo;Jo, Kyung-Wook;Kang, Young Ae;Kwon, Yong-Soo;Lee, Myungsun;Mok, Jeongha;Shim, Tae-Sun;Shin, Hong-Joon;Whang, Jake;Yim, Jae-Joon
    • Tuberculosis and Respiratory Diseases
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    • v.83 no.2
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    • pp.141-146
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    • 2020
  • Background: The burden of nontuberculous mycobacterial (NTM) pulmonary disease (PD) is increasing globally. To understand the treatment outcomes and prognosis of NTM-PD, a unified registry is needed. In this project, we aim to construct a multicenter prospective observational cohort with NTM-PD in South Korea (NTM-KOREA). Methods: The primary objective of this study is to analyze treatment outcomes according to the species. In addition, recurrence rate, adverse events, the impact of each drug on treatment outcomes as well as the impact of characteristics of mycobacteriology will be analyzed. The inclusion criteria for the study are as follows: fulfilling the criteria for NTM-PD having one of the following etiologic organisms: Mycobacterium avium complex, M. abscessus subspecies abscessus, M. abscessus subspecies massiliense, or M. kansasii; receiving the first treatment for NTM-PD after enrollment; age >20 years; and consenting to participate in the study. Seven institutions will participate in patient enrollment and about 500 patients are expected to be enrolled. Participants will be recruited from 1 March 2020 until 19 March 2024 and will be observed through 19 March 2029. During the follow-up period, participants' clinical course will be tracked and their clinical data as well as NTM isolates will be collected. Conclusion: NTM-KOREA will be the first nationwide observational cohort for NTM-PD in South Korea. It will provide the information to optimize treatment modalities and will contribute to deeper understanding of the treatment outcomes and long-term prognosis of patients with NTM-PD in South Korea.

Effect of Pyridine on Toluene Diisocyanate (TDI) Synthesis Using Direct Carbonylation over Pd/SiO2 (Toluene diisocyanate(TDI) 합성을 위한 Pd/SiO2 촉매상 직접 카보닐화반응에서의 피리딘 첨가효과)

  • Seo, Myung-Gi;Kim, Seongmin;Lee, Dae-Won;Lee, Kwan-Young
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.417-420
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    • 2012
  • This study is about reduction reaction making 2, 4-dinitrotoluene (2, 4-DNT) to 2, 4-toluene diisocyanate (2,4-TDI) with Pd/$SiO_2$. Catalytic systems based on Pd/$SiO_2$ at about $200^{\circ}C$ and under 100 bars of carbon monoxide. We studied the effect of pyridine on the yield of the TDI. TDI was not created without pyridine, but created with pyridine, at the reaction result. According to research, homogeneous synthesis of TDI with direct carbonylation, palladium and pyridine complexion is known to catalyze. When adding pyridine the reason of TDI synthesis is palladium leaching, ICP-AES was performed to confirm it. As a result, the proportion of Pd loaded in $SiO_2$ was decreased 52% than before, after the reaction by adding 20 vol% pyridine. Generating TDI by adding pyridine might be the effect of the complex ion, which is composed of leached palladium and pyridine.

Analysis of Cadmium in Urine using Flame and Flameless Atomic Absorption Spectrophotometry (불꽃 및 비불꽃원자흡수분광법을 이용한 뇨중 카드뮴 분석)

  • Ham, Yong-Gyu;Lee, Seok-Ki;Jeon, Jae-Hong;Joung, Chang-Ung;Son, Bu-Soon
    • Analytical Science and Technology
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    • v.12 no.5
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    • pp.355-359
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    • 1999
  • Trace cadmium was determined in urine by flame and nameless AAS. Inflame method, cadmium was extracted into MIBK from Cd-DDTC complex. In flameless method, samples were pretreated with 1%, Triton X-100. 1% $HNO_3$ and matrix modifier $Pd(NO_3)_2$. Analysis of cadmium was, performed at $450-750^{\circ}C$ ashing temperature by use of pyrocoated tubes. Results of analysis, flameless method superior in sample treatment and reproducibility to flame method and highest absorbance was obtained at $550^{\circ}C$ ashing temperature. 100 mg/L $Pd(NO_3)_2$ concentration. Proposed method were applied to the determination of cadmium in standard urine Lononorm-Metalle 3.

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Synthesis and Characterization of Square Planar Mixed-Ligand Complexes (II) : Electrophilic and Nucleophilic Reaction of M(S-S)(N-N) Type Complexes with Ni(II), Pd(II), and Pt(II) (평면사각형 혼합 리간드 착물의 합성과 그 특성 (제 2 보) : Ni(II), Pd(II) 및 Pt(II)의 M(S-S)(N-N)형 착물의 친전자성 및 친핵성 반응)

  • OH Sang Oh;Chung Duck Young
    • Journal of the Korean Chemical Society
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    • v.36 no.1
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    • pp.81-86
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    • 1992
  • The electrophilic and nucleophilic reactions of M(S-S,ph)(N-N,H) (M = Ni(II), Pd(II), Pt(II); (S-S,ph) = 1,2-diphenylethylenedithiolate; (N-N,H)=1,10-phenanthroline) complexes have been investigated. Reaction with norbornadiene depended upon the back donating ability of the central metal ion and produced 2,5-dithia-3,4-diphenyl-tricyclo[4,4,1,0]-undeca-3,8-diene. In the reaction with methyl iodide, the effect of cleavage of (N-N,H) ligand affected the yield of methylated $M(S-S,ph)_2$ product. The structure of the thermolysis product, ${\alpha},{\alpha}{\prime}$-bismethylthiostibene $(CH_3S-SCH_3,ph)$ of methylated complexes indicates that the main product of the nucleophilic reaction is $M(CH_3S-SCH_3,ph)(S-S,ph)$. We have synthesized a new mixed-ligand complex M(S-S,CN)(N-N,H)((S-S,CN) = 1,2-dicyanoethylenedithiolate) through the nucleophilic reaction of ligand.

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