• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.92.2-92.2
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• 2011

차세대 에너지로 연료전지가 각광을 받고 있는 현재, 세계 각국에서는 연료전지의 상용화를 위해 노력하고 있다. 그러나 촉매분야에서 백금계 촉매의 사용량의 문제에 따른 매장량 한계점과 귀금속이라는 문제점이 존재하기 때문에 이에 대하여 대책강구가 필요한 시점이다. 이에 백금 촉매의 활성을 증대하고자 나노 크기의 제어 연구가 진행되고 있다. 또한, 촉매의 구조적인 면에 따라 촉매의 활성이 달라지는 점을 착안하여 백금계의 나노 형상 조절 연구와 백금계 촉매를 대체할 비백금계의 촉매 개발 연구가 활발히 진행되어지고 있다. 이에 본 연구는 백금계 촉매 중 Pd을 polyol process에 의한 나노 형상 조절을 통하여 단위 질량당(or 단위 부피당)촉매의 활성을 높이고자 하였다. 여기서 새로이 도입된 환원제는 Glycerol을 이용하였으며, {111}면이 많이 드러난 Pd 나노입자를 형성하였다. 이에 따라 나노 형상 조절이 된 Pd촉매를 이용하여 상용화된 촉매(Pd/C(XC-72R))에 비하여 전기화학적인 특성의 차이와 Pd 촉매의 촉매적 특성의 효과를 보고자 한다.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.262-262
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• 2012

Modifications of graphenes have been studied for catalytic applications due to their advantages such as high surface area, conductivity and thermal stability. In this research, individual graphene oxide (GO) sheets were exfoliated from graphite using Hummers and Offeman method. Pd nano-particles were deposited on the GO surface using Pd2+ ion exchange where hydroxyl groups on the GO act as nucleation sites of Pd nanoparticles and their dispersions. The thermal treatments of the Pd-GO in H2 flow produced Pd-Graphene nanocomposites. Their catalytic performances in Sonogashira reaction were investigated. Morphological and chemical structures of the GO, Pd-GO, and Pd-Graphene were investigated using FT-IR, XRD, TEM, STEM, and XPS. The catalytic performances have been investigated using microwave reactor.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.52 no.10
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• pp.431-435
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• 2003

It is very difficult and dangerous to measure PD(Partial Discharges) from high voltage equipments in outdoor situation. But that is very important thing for preventing them from more serious accident by defects made by insulating degradation. This paper provides useful method to detect PD signals easily without any dangerous situation. Electric field sensor by the principle of capacitor can detect PD signals without direct connection between sensor and high voltage equipment and has very wide frequency range suitable for noise rejection. Electric field sensor and related circuit for processing PD signal show good performance as a PD sensor when it is applied to simulated high power equipment generating PD pulses.

• Proceedings of the KSR Conference
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• 2009.05a
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• pp.1977-1983
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• 2009

This paper described partial discharge(PD) patterns depending on types of insulation defects in CNCO-W cable(Concentric Neutral Closs-linked Polyethylene Insulated Polyolefin-Water Proof Sheathed Power Cable). The PD measurement system consists of a coupling network, a detection impedance, and a low noise amplifier. A 16 bit, 250 MS/s data acquisition system was used to analyze PD patterns. To simulate insulation defects in a power cable, a needle with the curvature radius of $10{\mu}m$ was inserted into the insulation part. We measured phase ($\Phi$), magnitude (q), and counts (n) of PD pulse for the defects, and classified PD patterns using the PRPD (phase Resolved Partial Discharge) method. From the analysis of acquired PD signals, we could find that a unique PD pattern is formed according to the types of defect.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.15 no.9
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• pp.818-821
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• 2002

We investigated the evolution of magnetic property with varying palladium (Pd) contents and elevating substrate temperatures up to 200 $^{\circ}C$ during dc-sputtering. We observed that saturation magnetization (Ms), remanence and anisotropic magnetoresistance (AMR) ratio decrease with Pd contents in the case of keeping the substrate temperature at 3$0^{\circ}C$. However they increase by adding 2 %Pd, then decrease above 3 %Pd when we keep the substrate temperature at 20$0^{\circ}C$. Coercivity does not change with Pd contents. Our results imply that we may tune the Ms and AMR with Pd contents and substrate temperature in permalloy films.

• Proceedings of the KIEE Conference
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• 2005.07c
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• pp.2175-2178
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• 2005

During normal machine operation, partial discharge(PD) measurements were performed with turbine generator analyzer(TGA) in five high voltage motors(rated 6.6kV). These high voltage motors were installed with 80pF capacitive couplers at the terminal box. The PD patterns were displayed two dimensional and three dimensional. TGA summarizes each plot with two quantities such as the normalized quantity number(NQN) and the peak PD magnitude(Qm). Off-line PD measurements were conducted on five motors. These motors were energized to 3.81kV. The PD levels in pC were measured with a conventional digital PD detector. The comparison of positive to negative PD indicates whether the defect elements of PD are within the insulation or on the insulation surface. Internal discharges were generated in phase A, B and C of COP-B and pulv.-B, in phase B of Pulv. C and in phase C of Pulv.-D motor. Discharge at conductor surface was discovered in phase A of Pulv. D motor. Slot discharges occurred in three phases of Pulv. E motor.

• Proceedings of the KIEE Conference
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• 2004.05b
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• pp.136-139
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• 2004

It is widely known that the ultra high frequency (UHF) method that detects the electromagnetic wave of the PD pulses in the gas insulated space is one of the most competitive methods for its high sensitivity. From the above point of view, this paper describes the propagation characteristics of GIS PD signals measured with ultra wide band (UWB) GIS PD detecting system in which PD signals are detected into the dual UHF band. The UWB PD detection system consists of the UWB UHF coupler, the UWB low noise amplifier (LNA) and the oscilloscope. The dual bands for PD signals are 0.5-2GHz(full band) and 1-2GHz(high band). As results, propagation characteristics of GIS PD signals were measured in the mock-up GIS bus and it was found that the propagation characteristics of the high band showed a better result in accordance with the infernal configuration of the GIS bus than those of the full band.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.221-222
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• 2005

In this paper, application of NN (Neural Network) as a method of pattern discrimination of PD(partial discharge) which occurs at the stator coil of traction motor was studied. For PD data acquisition, three defective models are manufactured such as internal discharge model, slot discharge model and surface discharge model. PD data for recognition were acquired from PD detector and DAQ board which is able to analysis the PD signal and perform the pattern discrimination. Statistical distributions and parameters are calculated to discriminate PD sources. And also these statistical distribution parameters are applied to classify PD sources by BP and has good recognition rate on the discharge sources.

• Korean Journal of Chemical Engineering
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• v.35 no.12
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• pp.2379-2383
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• 2018

We report a facile one-pot aqueous-phase synthesis of PdAu bimetallic nanoparticles with different Pd/Au ratio. The synthesis was conducted by co-reduction of Pd and Au precursor using ascorbic acid as a reducing agent and in the presence of polyallylamine hydrochloride (PAH). By high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM) and energy-dispersive X-ray spectrometry (EDS) analyses, we found that the synthesized nanoparticles had an onion-like core/shell/shell/shell structure with Au-rich core, Pd-rich shell, Au-rich shell, and Pd shell, respectively. We also investigated the catalytic performance of the synthesized PdAu nanoparticles toward hydrogen peroxide generation reaction.

• KSBB Journal
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• v.23 no.5
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• pp.413-418
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• 2008

The production of 1,3.propanediol (1,3-PD) was investigated with Klebsiella pneumoniae DSM2026 and K. pneumoniae DSM4799 using crude glycerol obtained from biodiesel industry. Crude glycerol was used without prior purification to investigate effects of impurities in crude glycerol on 1,3-PD production. In the batch cultures, 1,3-PD production with crude glycerol was $1.1{\sim}2.5$ times higher than that with pure glycerol, indicating that crude glycerol is even a better substrate than pure glycerol for 1,3-PD fermentation. When glucose was added, 1,3-PD production and yield decreased in spite of enhanced cell growth. Furthermore, the addition of glucose was found to increase 2,3-butanediol, a by-product, significantly because of the change in metabolism in the presence of glucose. In semi-batch cultures without glucose addition, 26 g/L 1,3-PD was produced with crude glycerol, which was $2{\sim}3$ times higher than that with pure glycerol. Based on our results, it was clearly shown that crude glycerol is an effective substrate for biological 1,3-PD production, making it more feasible to produce 1,3-PD at a lower price.