• Title/Summary/Keyword: PbU

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SHRIMP U-Pb Zircon Geochronology of the Guryong Group in Odesan Area, East Gyeonggi Massif, Korea: A new identification of Late Paleozoic Strata and Its Tectonic Implication (경기육괴 동부 오대산 지역의 구룡층군에 대한 SHRIMP U-Pb 저어콘 연대측정: 새로운 후기 고생대층의 인지와 지체구조적 의의)

  • Cho, Deung-Lyong
    • The Journal of the Petrological Society of Korea
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    • v.23 no.3
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    • pp.197-208
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    • 2014
  • Zircon separated from a biotite schist of the Guryong Group in Odesan area, eastern part of the Gyeonggi Massif in Korea were analysed for SHRIMP U-Pb ages. CL images display composite core-rim structures of the zircon, indicating an in-situ overgrowth of zircon through a high-grade metamorphism. The metamorphic zircon rims give a weighted mean age of $247{\pm}6Ma$. While the detrital zircon cores have zoning patterns and Th/U ratios indicative of a magmatic origin. Among 53 analyses from the cores, 46 data yield near concordant ages which are concentrated at $378{\pm}10Ma$ (n=9), $420{\pm}4Ma$ (n=6) and $1845{\pm}9Ma$ (n=18) with sporadic Neoproterozoic ($687{\pm}9Ma$) to late Archean ($2519{\pm}20Ma$) ages. The age data constraint sedimentation age of protolith of the Guryong Group, so far unknown, as late Paleozoic. The Guryong Group of this study is the first late Paleozoic strata reported from eastern Gyeonggi Massif, and its maximum depositional age (ca 378 Ma) is identical with those of the late Paleozoic strata in the southwestern Ogcheon Belt. The Triassic metamorphic age and abundant middle Paleozoic provenance (361~425 Ma) of the Guryong Group are similar with those reported from the Triassic collisional belt in central China. Thus this study indicates that the Odesan area would be an possible eastward extension of the Triassic collisional belt in central China.

Impedance Spectroscopy of (Pb0.92La0.08)(Zr0.95Ti0.05)O3 Ceramics above Room Temperatures

  • Jong-Ho Park
    • Korean Journal of Materials Research
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    • v.34 no.5
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    • pp.242-246
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    • 2024
  • La modified lead zirconate titanate ceramics (Pb0.92La0.08)(Zr0.95Ti0.05)O3 = PLZT-8/95/5 were prepared using the conventional solid state reaction method in order to investigate the complex impedance characteristics of the PLZT-8/95/5 ceramic according to temperature. The complex impedance in the PLZT-8/95/5 ceramic was measured over a temperature range of 30~550 ℃ at several frequencies. The complex dielectric constant anomaly of the phase transition was observed near TU1 = 179 ℃ and TU2 = 230 ℃. A remarkable diffuse dielectric constant anomalous behaviour of the complex dielectric constant was found between 100 ℃ and 550 ℃. The complex impedance spectra below and above TU1 and TU2 were fitted by the superposition of two Cole-Cole types of impedance relaxations. The fast component in the higher frequency region may be due to ion migration in the bulk, and the slow component in the lower frequency region is interpreted to be the formation and migration of ions at the grain boundary or electrode/crystal interfacial polarization.

A Study on the Microwave Dielectric Properties of Low-Temperature Sintered (Pb, Ca )$ZrO_3$ ceramics with $V_2O_{5}$ Additives ($V_2O_{5}$가 첨가되어 저온 소결된 (Pb,Ca)$ZrO_3$세라믹의 마이크로파 유전특성에 대한 연구)

  • Jeong, Young;Park, Jung-Hum;Yoon, kwang-Hee;Yoon, Hyun-Sang;Lee, Doo-Hee;Kim, Kyu-Soo;Park, Chang-Yub
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.1-4
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    • 1994
  • In this study. the microwave dielectric properties, such at dielectric constant(${\varepsilon}_{\gamma}$), unloaded quality factor multiplied with resonant frequency($Q_{u}$.f), and temperature coefficient of resonant frequency(${\tau}_{f}$), were investigated for the low-temperature sintered (Pb, Ca)$ZrO_3$ with $V_2O_{5}$ additives as well as structural properties. As a result, (Pb,Ca)ZrO$_3$ with 0.2 wt% $V_2O_{5}$ additive, sintered at $1200^{\circ}C$, showed good properties like ${\varepsilon}_{\gamma}$ 109, $Q_{u}$.f 2736 GHz, and ${\tau}_{f}$ -2.94 ppm/$^{\circ}C$. Especially ${\tau}_{f}$ was much better than ($Pb_{0.63}Ca_{0.37}$)$ZrO_3$ of which ${\tau}_{f}$ was known to be + 13.4 ppm/$^{\circ}C$, so it seems to be applicated in micorowave device components.

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$Bi_2Te_3-PbTe$계 열전소재의 자연나노구조체 형성 및 특성

  • Im, Ju-Hyeok;Jeong, Gyu-Ho;Kim, Gwang-Cheon;Yu, Hyeon-U;Kim, Jin-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.263-263
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    • 2009
  • The microtstructures and properties of alloys in the pseudo-binary $Bi_2Te_3-PbTe$ system were investigated as a first step towards the design of nanostructured materials with enhanced thermoelectric properties. The liquid alloys were cooled by water quenching method. Dendritic and lamellar structures were observed clearly by using environmental scanning electron microscope(eSEM) and electron probe micro analyzer(EPMA) take into account composition ratio between $Bi_2Te_3$ and PbTe. The compound $Pb_2Bi_6Te_{11}$ precipitated as a metastable phase under all conditions. The structure of those samples changed from dendritic to lamellar by increasing $Bi_2Te_3$ ratio of composition.

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