• Title/Summary/Keyword: PbS

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Development of Highly Sensitive SWIR Photodetectors based on MAPI-capped PbS QDs (MAPI 리간드 치환형 PbS 양자점 기반의 고감도 단파장 적외선 광 검출기 개발)

  • Suji Choi;JinBeom Kwon;Yuntae Ha;Daewoong Jung
    • Journal of Sensor Science and Technology
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    • v.33 no.2
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    • pp.93-97
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    • 2024
  • With the development of promising future mobility and urban air mobility (UAM) technologies, the demand for LIDAR sensors has increased. The SWIR photodetector is a sensor that detects lasers for the 3D mapping of lidar sensor and is the most important technology of LIDAR sensor. An SWIR photodetector based on QDs in an eye-safe wavelength band of over 1400 nm has been reported. QDs-based SWIR photodetectors can be synthesized and processed through a solution process and have the advantages of low cost and simple processing. However, the organic ligands of QDs have insulating properties that limit their ability to improve the sensitivity and stability of photodetectors. Therefore, the technology to replace organic ligands with inorganic ligands must be developed. In this study, the organic ligand of the synthesized PbS QDs was replaced with a MAPI inorganic ligand, and an SWIR photodetector was fabricated. The analysis of the characteristics of the manufactured photodetector confirmed that the photodetector based on MAPI-capped PbS QDs exhibited up to 26.5% higher responsivity than that based on organic ligand PbS QDs.

A Reliability Test for Pb-Free Plating Solution and its Deposit (Pb-Free 도금용액 및 피막의 신뢰성평가)

  • Hur, Jin-Young;Koo, Suck bone;Lee, Hong-Kee
    • Clean Technology
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    • v.11 no.3
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    • pp.153-164
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    • 2005
  • This study found a reliable evaluation for four kinds of pb-Free plating solutions and it's layers, through pure Sn, SnAg, SnBi and SnCu. These four kind of solutions are widely used to pb-Free plating. Hull-cell, Harring-blum, coverage, throwing power, current efficiency, stability, life-time, composition, hardness, roughness, abrasion, scratch, solderability, corrosion, contact angle, morphology, SIR(Surface insulation resistance) and Whisker test were experimented. Also, Using ICP, XRF, FE-SEM, EDS, temperature/humidity chamber, solderability tester, hardness tester, roughness tester, abrasion tester, salt spray tester, contact angle tester, SIR tester, and microscope. In this paper could be shown the systematic and various analysis for reliability about four kinds of pb-Free plating solutions, processes and it's deposit surface.

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Analysis of Consumer Purchase Factors through Online Marketing of Convenience Store PB Products (편의점 PB상품의 온라인 마케팅을 통한 소비자 구매 요인 분석)

  • Park, Jung-Hoon;Kim, Seung-In
    • Journal of Digital Convergence
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    • v.18 no.5
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    • pp.399-404
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    • 2020
  • The purpose of this study is to find out the consumer's purchasing behavior and its factors when a convenience store brand is marketing new PB products online. For this study, we surveyed 2030 millennials about the purchase behavior of convenience store PB products and the paths to encounter PB products. As a result, consumers who purchase convenience store PB products were exposed to the product through SNS or YouTube, and they tended to join the trend by posting on SNS after purchase. In this study, we want to examine the consumption trends of millennials that have this type of consumption and the concept of online marketing that affects them. It is hoped that future consumer purchases will continue to be valuable consumption rather than relying on trends.

Performance Evaluation of Radiation Protection Apron's (방사선방어 앞치마 성능 평가)

  • Kang, Jong-gu;Kang, Byung-Sam
    • Journal of radiological science and technology
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    • v.42 no.5
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    • pp.373-377
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    • 2019
  • Radiation exposure is on the rise as the working hours of radiation workers increase. Accordingly, the importance of protection products for decreasing the dose of exposure has risen, and excellent X-ray shielding ability and light weight are required. The purpose of this study is to compare the Pb which use currently and other elements in order to reduce the exposure of workers to the most effective protection products. For experiment, we used the general X-ray equipment and angiography equipment, and obtained the Pb and apron's shielding rate. When the shielding rate of Pb and apron was compared in general X-ray equipment, the shielding rate was 95.1% for Pb 0.5 mm, 96.1% for apron 0.5 mmPb and 95.6% for Bi+W 0.5 mmPb. When compared the shielding rate of each aprons in angiography equipment, 0.5 mmPb apron was the highest as 96.4% and Bi+W 0.25 mmPb apron was the lowest as 90.2% at the 50 cm distance. The shielding rate of 0.5 mmPb apron was the highest as 95.7% and Bi+W 0.25 mmPb apron was the lowest as 85.9% at the 100 cm distance. As a result of evaluating the apron efficiency through this study, 0.5 mmPb apron showed the best shielding rate, but it was the heaviest apron. 0.35 mmPb apron and Bi+W 0.25 mmPb apron weighed light but had low shielding rate. Through the results of this experiment, it is recommended that radiation workers reduce radiation exposure by using more efficient protection products.

The Effect of Consumer's Perceptual Characteristics for PB Products on Relational Continuance Intention: Mediated by Brand Trust and Brand Equity (PB상품에 대한 소비자의 지각특성이 관계지속의도에 미치는 영향: 브랜드신뢰 및 브랜드자산을 매개로 한 정책적 접근)

  • Lim, Chaekwan
    • Journal of Distribution Research
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    • v.17 no.5
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    • pp.85-111
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    • 2012
  • Introduction : The purpose of this study was to examine the relationship between perceptual characteristics of consumers and intent of relational continuance for PB(Private Brand) products in discount stores. This study was conducted as an empirical study based on survey. For the empirical study, factors of PB products as characteristics perceived by consumers such as perceived quality, store image, brand image and perceived value were deduced from preceding studies. The effect of such factors on intent of relational continuance mediated by brand trust and brand equity of PB products was structurally examined. Research Model : Based on theory analysis and hypotheses, constructed a Structural Equation Model(SEM). The research model is shown in Figure 1. Research Method : This paper is based on s qualitative study of selected literature and empirical data. The survey for empirical study was carried out on consumers in Gyeonggi and Busan between January 2012 and May 2012. 300 surveys were distributed and 253 (84.3%) of them were returned. After excluding omissions and insincere responses, 245 surveys (81.6%) were used for final analysis as effective samples. Result : First of all, the Reliability was carried out for instrument used. The lower limit of 0.7 for Cronbach's Alpha as suggested by Hair et al. (1998). And Construct validity was established by carrying out exploratory factor analysis by Varimax rotation for all. Four factor result for the consumer's perceptual characteristics of PB Products, two mediating factors and one dependent factor. All constructs included in research framework have acceptable validity and reliability. Table 1 shows the factor loading, eigen value, explained variance and Cronbach's alpha for each factor. In order to assure validity of constructs, I implemented Confirmatory Factor Analysis (CFA), using AMOS 20.0. In confirmatory factor analysis, researcher can take control over the specification of indicators for each factor by hypothesizing that a specific factor is loaded with the relevant indicators. Moreover, CFA is particularly useful in the validation of scale for the measurement of specific construct. CFA result summarized Table 2 shows that the fit measures of all constructs fulfill the recommended level and loadings are significant. To test causal relationship between constructs in the research model, used AMOS 20.0 that provides a graphic module as method for analysing Structural Equation Modeling. The result of hypothesis test is shown in Table 3. As a result of empirical study, perceived quality, brand image and perceived value as selected attributes for PB products showed significantly positive (+) effect on brand trust and brand equity. Furthermore, brand trust and brand equity showed significantly positive (+) effect on intent of relational continuance. However, store image of discount stores selling the PB products was analyzed to have positive (+) effect on brand trust and no significant effect on brand equity. Discussion : Based on the results of this study, the relationship between overall quality, store image, brand image and value perceived by consumers about PB products and intent of relational continuance was structurally verified as being mediated by brand trust and brand equity. Looking at the results, a strategic approach that maximizes brand trust and equity value for PB products by large discount stores is required on top of basic efforts to improve quality, brand image and value of PB products in order to maximize consumer's intent of relational continuance and to continuously attract repeated purchase of products.

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Correlations between the Polarization and Strain Induced by Electric field in $\textrm{0.9Pb}\textrm({Mg}_{1/3}\textrm{Nb}_{2/3})\textrm{O}_3$-$\textrm{0.1PbTiO}_3$ Relaxor Ferroelectrics ($\textrm{0.9Pb}\textrm({Mg}_{1/3}\textrm{Nb}_{2/3})\textrm{O}_3$-$\textrm{0.1PbTiO}_3$계 강유전체에서 전계인가에 따른 분극 및 변위의 상관관계)

  • Park, Jae-Hwan;Park, Jae-Gwan;Park, Sun-Ja
    • Korean Journal of Materials Research
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    • v.9 no.1
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    • pp.81-85
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    • 1999
  • Polarization and strain induced by unipolar electric field (P\ulcorner, S\ulcorner), those induced by bipolar electric field (P, S) and remanent polarization (P\ulcorner) were investigated in 0.9Pb(Mg\ulcornerNb\ulcorner)O$_3$-$0.1PbTiO_3$relaxor ferroelectric ceramics in the temperature range of $-50^{\circ}C$~$90^{\circ}C$. From the temperature dependence of polarization and strain, the transition from predominantly paraelectric (electrostrictive) to partially ferroelectric (piezoelectric) is visualized. Under the given temperature, the P\ulcorner/P\ulcorner is always larger than the S\ulcorner/S\ulcorner and the difference between them becomes larger ass the temperature decrease. The S\ulcorner/P\ulcorner increases as the temperature decreased below phase transition temperature. It was suggested that these experimental results might be explained with a simple rigid ion model concentrating on BO\ulcorner octahedron.

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Stress Corrosion Cracking Behavior of Alloy 690 in Crevice Environment (Pb + S + Cl) in a Steam Generator Tube (증기발생기 전열관 틈새복합환경(Pb+S+Cl)에서 Alloy 690의 응력부식균열거동)

  • Shin, Jung-Ho;Lim, Sang-Yeop;Kim, Dong-Jin
    • Corrosion Science and Technology
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    • v.17 no.3
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    • pp.116-122
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    • 2018
  • The secondary coolant of a nuclear power plant has small amounts of various impurities (S, Pb, and Cl, etc.) introduced during the initial construction, maintenance, and normal operation. While the concentration of impurities in the feed water is very low, the flow of the cooling water is restricted, so impurities can accumulate on the Top of Tubesheet (TTS). This environment is chemically very complicated and has a very wide range of pH from acidic to alkaline. In this study, the characteristics of the oxide and the mechanism of stress corrosion cracking (SCC) are investigated for Alloy 690 TT in alkaline solution containing Pb, Cl, and S. Reverse U-bend (RUB) specimens were used to evaluate the SCC resistance. The test solution comprises 3m NaCl + 500ppm Pb + 0.31m $Na_2SO_4$ + 0.45m NaOH. Experimental results show that Alloy 690 TT of the crevice environment containing Pb, S, and Cl has significant cracks, indicating that Alloy 690 is vulnerable to stress corrosion cracking under this environment.

Rapid and Precise Determination of Pb Isotope Ratios Using Mu1ti-Collector ICP/MS (다검출기 유도결합 플라즈마 질량분석기를 이용한 신속하고 정밀한 Pb 동위원소 분석)

  • 최만식;정창식;신형선;임태선
    • The Journal of the Petrological Society of Korea
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    • v.10 no.3
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    • pp.157-171
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    • 2001
  • This study investigated the effects of Pb/Tl ratio, Pb concentration and concomitant matrix elements on the measurement of Pb isotope ratios using multi-collector ICP/MS (AXIOM MC model). Accuracy and reproducibility of Pb isotope ratios in NBS 981 solution were estimated for 42 data measured from March to August 2001. Pb isotopes measured in rocks, bronzes and sediments were compared to data measured by TIMS. Reproducibilities for $^{206}Pb/^{204}Pb,\; ^{207}Pb/^{204}Pb,\;and\;^{208}Pb/^{204}Pb$ ratio were about 500 ppm (2sd) and for $^{207}Pb/^{206}Pb$\;and\;^{208}Pb/^{206}Pb$ were 100~200 ppm for 200 ng of Pb in NBS 981 solution. The optimum conditions for the analysis of Pb isotope ratios with AXIOM MC for best accuracy and reproducibility were defined as follows; 1) Pb/Tl ratio is about 10 2) Pb concentration is about 100 ng/ml 3) correction for mass discrimination is performed by exponential law using 2.3887 of $^{205}Tl/^{203}Tl$ and Pb mass fractionation factor empirically obtained from $ln(^{208}Pb/^{206}Pb)-ln(^{205}Tl/^{203}Tl)$ relationship. The sample data measured with MC/ICP/MS for acid-digested and chemically separated rock samples, and acid-digested bronze samples and sediment samples coincide with those of TIMS within analytical errors. Therefore, MC/ICP/MS is a rapid analytical technique for Pb isotope ratios with the similar precision compared with TIMS.

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Biosorption and Development of Biosorbent by using Seaweed, Sugassum thunbergii (해조류, Sargassum thunbergii를 이용한 중금속의 바이오 흡착제의 개발)

  • SUH Kuen-Hack;LEE Hak-Sung;SUH Jung-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.33 no.1
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    • pp.60-65
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    • 2000
  • Biosorptions of Cr and Pb were evaluated for 23 species of marine algae collected from a Korean coast. Among a variety of species for biosorbent potential, Sargassum species showed higher uptake capacity for Cr and Pb. An adsorption equilibrium was reached in about 1 hr for Cr and 30 min for Pb. The maximum uptake capacity was136.0 mg Cr/g biomass and 232.5 mg Pb/g biomass, respectively. In Pb biosorption in the column packed with Sargassum tbunbertii, 300 and 200 bed Tolumes at the concentration of 50 mg/L in feed solution were processed at the column residence time of 5 and 10 min before the column breakthrough point occurred. The elutions with 0.1 M HCl solution were more than $95{\%}$. The high efficiency of continous biesorntion and elution (3 cycles) indicated that Sargassum thunbergii was an effective biosorbent for Pb recovery.

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A Study on Chromium Electroplating of Piston Ring Groove's Surface (엔진피스톤링 홈의 크롬도금에 관한 연구)

  • 문경만
    • Journal of Advanced Marine Engineering and Technology
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    • v.19 no.2
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    • pp.47-55
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    • 1995
  • When the low heavy oil is using as fuel oil to the diesel engine, some problems such as corrosion resistance, wear resistance and heat resistance are happened in diesel engine's internal material, especially the adhesive wear of piston ring groove was occurred as a important problem. Therefore to prevent adhesive wear of its groove, the surface of its groove used to be electroplated with Chrominum and for its Chromium electroplating, Fe anode is being used until nowadays because of its Special shape. However in case of using Fe anode, there were some problems such as deterioation of solution, property of Chromium film, and condition of coation. In this paper Pb anode electroplated withPb to the steel plate was investigated for its Chromium electroplating for Pb's high corrosion resistance in acid solution, and Pb anode is not dissolved compared with Fe anode and deterioration degree of solution in case of Pb anode is smaller than that of Fe anode and also property of Chromium film was better than that of Fe anode. Moreover it was known that the optimum cathodic current density for Pb electroplating to steel plate as insoluable anode for Chromium coating of piston ring groove is 30mA/$cm^2$ by experimental results obtained.

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