• Title/Summary/Keyword: Pb addition

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A Study on the Effect of Heavy Metals on Embryos Formation of Sea Urchins (중금속이 성게의 배아형성에 미치는 영향에 관한 연구)

  • 유춘만
    • Journal of Environmental Health Sciences
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    • v.24 no.3
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    • pp.6-10
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    • 1998
  • This study was attempted to carry out the effects of heavy metals when sea urchins (Hemicentrotus pulcherrimus, Anthocidaris crassispina, Scahhechinus brevis) formed early embryos. Results of the experiment for the effects of heavy metals on the development of sea urchins, in most sea urchins, the ranking of heavy metals according to decreasing effects upon fertilization and development of urchin eggs was follows: Hg, Cu, Zn, CA, Ni, Cr, Pb, As,and Fe. In addition, in most heavy metals, the ranking of experimental animals according to decreasing effects upon fertilization and development of urchin eggs in the same concentration of heaw metals was follows: H. pulcherrimus, A. crassispina, and S. brevis.

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인산염을 이용한 납오염 토양 고정화 반응의 가속화

  • 이의상;이상봉;이인원
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.201-204
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    • 2004
  • Immobilization is seen as a promising technology for lead remediation. In a laboratory experiment, immobilization of lead with soluble P was tested as a function of reaction time and P concentration. The P treated with an acidic solution to enhance heavy metal immobilization was worked into the soil, and within 7 days, lead was stabilized. Different molar ratios of soluble phosphates (super-phosphate and KH$_2$PO$_4$) would be considerably effective to accelerate the formation of highly insoluble minerals due to the lack of leachable Pb in the contaminated soil. Although it was demonstrated that the addition of soluble phosphates with an acidic solution significantly reduced available lead in soil up to over 95%, remaining phosphorus in soil matrix might cause a possible groundwater eutrophication in the near future.

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A Study on Manufacturing and Characteristics of solid Lubricant Oilless Bearin (고체윤활 베어링의 제조방법 및 특성연구)

  • Kim, Chang-Uk;Ryu, Su-Hyeon
    • Korean Journal of Materials Research
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    • v.11 no.11
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    • pp.991-996
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    • 2001
  • This study is the manufacture of solid lubricant oilless bearing using sintered parts. PTFE was as organic solid lubricant and $MoS_2$ as inorganic solid lubricant, and its characteristics were studied. Thickness of lubricant was suited 25~$100\mu\textrm{m}$ for lubricant characteristics. Curring temperature of MoS_2$ film was 12$0^{\circ}C$, 2 hours and that of PTFE film was $260^{\circ}C$, 20 minutes. The solid weight and solid volume of $MoS_2$ film was 51.7% and 27.4%, and that of PTFE was 44.9% and 24.3%. Chemical resistant of PTFE solid lubricant oilless bearing was excellent as salt test was 520hours, and usable temperature range was $-200~+280 ^{\circ}C$. Conduction of electricity can be increase by addition of graphite or $$\alpha$- PbO_2$. The electric conductivity was 100~180$\Omega$.

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Geochemical Characteristics of Mine Wastes in Abandoned Mines in Korea (휴/폐광 광산폐기물의 지구화학적 특성)

  • 정명채;정영욱;민정식
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1998.11a
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    • pp.71-75
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    • 1998
  • The objective of this study is to investigate geochemical characteristics of mine wastes including tailings in various abandoned mines in Korea. Tailings and wastes were sampled in and around 39 metalliferous mines, and analysed heavy metal concentrations including Cd, Cu, Pb and Zn extracted by 0.1N HCl and aqua regia by Atomic Absorption Spectrometry. Measurements of paste pH and lime requirement were carried out to examine a general geochemical characteristics of the materials. Lots of mine wastes were characterized by very low pH values of 2 to 4 and high lime requirement to control neutralization of the wastes. In addition, elevated levels of heavy metals were found in various mine wastes extracted by both 0.lN HCl and aqua regia. Because the mine wastes can be dispersed into the downstream by clastic movement and wind-blow, it is necessary to control the materials with a proper method for their reclamation.

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A Study on the Calculation Method about Emissions of Greenhouse Gases of Nonferrous-metal Industry Part in Domestic Nonferrous-metal Industry (국내 비철금속 산업부문 온실가스 발생량 산정 방법에 관연 연구)

  • Chung, Jin-Do;Han, Jong-Min;Kim, Jang-Woo
    • Journal of Environmental Science International
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    • v.18 no.2
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    • pp.197-203
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    • 2009
  • The aim of this study is to calculate process emission of GHGs(greenhouse gases) in nonferrous-metal industry, such as Zn, Pb, Cu and Ni. In addition, variation and emission of GHGs generated from these company were defined. And then, GHGs algorithm and calculation formular which were considered as production process in each part of nonferrous-metal industry were developed to develop calculation program of GHGs emission. These algorithm and calculation formular would present fundamental direction about other nonferrous-metal industry in the future.

Effect of $Al_{2}O_{3}$ filler addition on sintering behavior of low-firing $BaO-B_{2}O_{3}-ZnO$ glass ceramic system

  • Kim, Young-Nam;Kim, Byung-Sook;Lee, Joon-Hyung;Kim, Jeong-Joo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.814-817
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    • 2003
  • The sintering behavior of $BaO-B_{2}O_{3}-ZnO$, which is Pb-free glass-ceramic system, was examined as functions of the composition and the amount and particle size of $Al_{2}O_{3}$ filler. Different kinds of modifiers were added and $Al_{2}O_{3}$ fillers with different particle sizes ($1.5{\mu}m$ and $4.5{\mu}m$) were added. The glass frit-filler composites were sintered in the temperature range $520{\sim}580^{\circ}C$. X-ray diffraction results revealed that some of the composites crystallized during sintering. Dielectric constant and thermal expansion coefficient the glass-ceramics were analyzed.

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A Poling Study on a Piezoceramic/Polymer 0-3 Composites for Hydrophone Applications (Hydrophone 응용을 위한 Piezoceramic/Polymer 0-3 Composite의 분극 개선)

  • Lee, S.H.;Cho, H.C.;SaGong, G.;Seul, S.D.;Koo, H.B.
    • Proceedings of the KIEE Conference
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    • 1989.07a
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    • pp.349-352
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    • 1989
  • Poling piezoelectric ceramic-polymer composites with 0-3connectivity is difficult because of the high dielectric constant of most of the ferroelectric filler materials, and the high resistivity of the polymer matrix. To aid in poling this type of composite, conductivity of the polymer phase can be controlled by adding small amount of a semiconductor phase such as germanium, carbon or silicon. In this study, flexible piezoelectric composites of $PbTiO_3$ powder and Eccogel polymer were developed using small amounts of a semiconducting phase. These composites were poled rapidly at low voltages, resulting in properties superior to composites prepared without a conductive phase. The effect of addition of various conductive phase with different volume percentage on the dielectric and piezoelectric properties of the composite are discussed here.

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Preparation and Properties of Sol-Gel Processed Lead Lanthanum Titanate Thin

  • Kim, Hyun-Hoo;Lee, Jung-Geun
    • Transactions on Electrical and Electronic Materials
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    • v.1 no.1
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    • pp.17-21
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    • 2000
  • In order to investigate the dependence of a content in lead lanthanum titanate (PLT) films and heat treatment, sol-gel process has been used. Four types of PLT thin films with the chemical formula, Pb$\_$1-x/ La$\_$x/Ti$\_$1-x/4/O$_3$(X=18, 21, 24 and 28 mole %) have been fabricated on Pt/Ti/SiO$_2$/Si multi-layers and ITO/glass substrates, The post-annealing temperature in the range of 400~700 $\^{C}$ is applied for the formation of perovskite structure in PLT films. The structureal, electrical and optical properties of PLT film with the addition of La content are estimated. The films orientation and surface structure of films are studied by XRD (X-ray diffraction) and SEM(scanning electron microscopy). The P-E hysteresis loop become narrower with increasing La content. The average transmittance of the films is about 80%.

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A study on heavy metal migration in fly ash/bentonite using a reactive transport model

  • Jung, Yoo-Jin;Cho, Hee-Chan
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.629-636
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    • 2003
  • The retardation of heavy metals in a mixture of fly ash and bentonite was studied as a potential barrier material for a landfill. Column tests were conducted using synthetic leachate having 100 mg/L and 50 mg/L of lead (Pb) and cadmium (Cd), respectively. Results indicated that the mixture had obvious retardation ability for heavy metals. To investigate the retardation factor caused by adsorption, batch adsorption tests were conducted at various concentrations. Test results were correlated with both Langmuir and Freundlich isotherms. The adsorption of the lead ion was applicable to the Langmuir isotherm and the adsorption of the cadmium ion was applicable to the Freundlich isotherm. In addition, based on experimental results, the migration characteristics of heavy metals through the bed of fly ash and bentonite mixture were investigated using the PHREEQC, a reactive transport model, under the real conditions of the landfill liner.

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Benzothiazole-Based Semisquaraine as Colorimetric Chemosensor for $Hg^{2+}$

  • Heo, Eun-Yeong;Go, Yeong-Il;Bae, Jin-Seok;Kim, Seong-Hun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.10a
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    • pp.83-84
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    • 2008
  • A highly selective colorimetric chemosensor for $Hg^{2+}$ based on the semisquaraine(BSQ) containing benzothiazole moiety was investigated. BSQ showed color change only with $Hg^{2+}$ but it showed no significant changes upon addition of other metal ions such as $Ca^{2+},\;Pb^{2+},\;Al^{3+},\;Ce^{2+},\;Ba^{2+},\;Ni^{2+},\;Cd^{2+},\;Zn^{2+},\;and\;Mg^{2+}$. $Hg^{2+}$ ions coordinated to the BSQ forming 1:1 complex. The experimental data and conclusions are rationalized by $DMol^3$ calculation results.

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