• Title/Summary/Keyword: Pb addition

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A Empirical Study on Preference Property for the Private Brand(PB) of Large Discount Stores in Gyeonggi-Do (경기지역의 대형할인점 유통업체브랜드(PB) 선호특성에 대한 실증연구)

  • Kim, Jeong-in;Lee, Jae-hak;Han, Kyu-baek
    • Journal of Distribution Science
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    • v.5 no.2
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    • pp.101-117
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    • 2007
  • Recently, in the process of distribution industry's growth, distribution environment is changing rapidly by appearance of new business condition and strategy of multiple store. According to the intensification of competition, recently large discount stores are developing private brand(PB) products for the purpose of product differentiation and profitability. But after the economic crisis in 1997, young housewives and salaried man's that have rational and practical buying pattern become the core consumer's in the large discount stores. Hence low price strategy is not new things for the consumer's anymore. In addition to, acquiring new consumer, many discount stores are establishing new stores at the rural area. But they undergo hardships of establishing new stores at the rural area because of disparity consumer's behavior, income level and consumption's pattern among regions. So, when they try to establish new stores, they need to know consumer's behavior at the region. Therefore the purpose of this study is to analyze preference property for the private brand(PB) of large discount stores in Gyeonggi-Do.

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Environmentally Adaptive Stabilization of the Hazardous Heavy Metal Waste by Cementious Materials(I) (산업폐기물 중의 유해중금속의 환경친화적 안정화 처리(I))

  • 원종한;안태호;최광휘;최상흘;손진군;심광보
    • Journal of the Korean Ceramic Society
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    • v.39 no.7
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    • pp.680-686
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    • 2002
  • The solidification/stabilization mechanism of each cementious material was investigated. It was found that when $C_3$S was hydrated , the Pb element could be transferred to the insoluble Ca[Pb(OH)$_3$.$H_2O$]$_2$and the Cr element to the CaCr $O_4$$H_2O$. The addition of heavy metal tends to delay the hydration until initial 7 days. The Pb element as also delayed the hydration and the Cr element was substituted for the ettringite. On the occasion of the hydration of $C_4$ $A_3$ $S^{S}$, the Pb and Cr ions were solidified/stabilized by the substitution into the ettringite and/or monosulfate. Leaching of the Pb, Cr and Zn elements in the solidified material was extremely little, indicating that heavy metals were effectively solidified/stabilized in the hydrated cementious materials. Solidification/stabilization of heavy metal ions in the industrial wastes such as the STS, BF and COREX sludge was investigated. In case of the mixing ratio of cement and slag was 3 : 7, leaching of hazardous heavy metal ions was very little, indications that the solidification and stabilization was very successful.l.

A Comparative Study on the Whole Rock Magnetic Susceptibility and SHRIMP Zircon U-Pb Geochronology of the Domestic Dimension Stone and Chinese similar Dimension Stone (전암대자율 특성과 SHRIMP 저어콘 U-Pb 연대 측정을 통한 국내 석재와 중국 유사 석재의 비교 연구)

  • Kim, Kun-Ki;Jwa, Yong-Joo;Hong, Sei-Sun;Lee, Ki-Wook
    • The Journal of the Petrological Society of Korea
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    • v.24 no.3
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    • pp.273-289
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    • 2015
  • This study used the petrological features and the whole rock susceptibility characteristics suggest ways to determine the domestic dimension stones and Chinese similar dimension stones. In addition, this study compare the intrusive period by measuring the zircon U-Pb age of these stones. Result of comparing the petrological feature, with the exception of Macheon stone and Boryeong stone to show the differences in mineral composition and texture under a microscope, the domestic dimension stones and Chinese similar dimension stones exhibit substantially the same petrological feature. According to the measurement results for the whole rock magnetic susceptibility, Goheong, Iksan, Pocheon stones are the similar as Chinese dimension stones, and other stones are easily distinguished. The zircon U-Pb age results for Geochang, Iksan, and Pocheon stones are equivalent to the Jurassic Daebo granites and G603, G633, G655 are the Cretaceous granites. Therefore, the domestic dimension stones and Chinese similar dimension stones can be clearly determined by the zircon U-Pb age results.

Evaluation of usability of the shielding effect for thyroid shield for peripheral dose during whole brain radiation therapy (전뇌 방사선 치료 시 갑상선 차폐체의 주변선량 차폐효과에 대한 유용성 평가)

  • Yang, Myung Sic;Cha, Seok Yong;Park, Ju Kyeong;Lee, Seung Hun;Kim, Yang Su;Lee, Sun Young
    • The Journal of Korean Society for Radiation Therapy
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    • v.26 no.2
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    • pp.265-272
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    • 2014
  • Purpose : To reduce the radiation dose to the thyroid that is affected to scattered radiation, the shield was used. And we evaluated the shielding effect for the thyroid during whole brain radiation therapy. Materials and Methods : To measure the dose of the thyroid, 300cGy were delivered to the phantom using a linear accelerator(Clinac iX VARIAN, USA.)in the way of the 6MV X-ray in bilateral. To measure the entrance surface dose of the thyroid, five glass dosimeters were placed in the 10th slice's surface of the phantom with a 1.5 cm interval. The average values were calculated by measured values in five times each, using bismuth shield, 0.5 mmPb shield, self-made 1.0 mmPb shield and unshield. In the same location, to measure the depth dose of the thyroid, five glass dosimeters were placed in the 10th slice by 2.5 cm depth of the phantom with a 1.5 cm interval. The average values were calculated by measured values in five times each, using bismuth shield, 0.5 mmPb shield, self-made 1.0 mmPb shield and unshield. Results : Entrance surface dose of the thyroid were respectively 44.89 mGy at the unshield, 36.03 mGy at the bismuth shield, 31.03 mGy at the 0.5 mmPb shield and 23.21 mGy at a self-made 1.0 mmPb shield. In addition, the depth dose of the thyroid were respectively 36.10 mGy at the unshield, 34.52 mGy at the bismuth shield, 32.28 mGy at the 0.5 mmPb shield and 25.50 mGy at a self-made 1.0 mmPb shield. Conclusion : The thyroid was affected by the secondary scattering dose and leakage dose outside of the radiation field during whole brain radiation therapy. When using a shield in the thyroid, the depth dose of thyroid showed 11~30% reduction effect and the surface dose of thyroid showed 20~48% reduction effect. Therefore, by using the thyroid shield, it is considered to effectively protect the thyroid and can perform the treatment.

Heavy Metal Adsorption of Untreated Barks by Treatment Conditions of Aqueous Solution (용액의 처리조건에 따른 미처리 수피에 의한 중금속 흡착)

  • Paik, Ki-Hyon;Kim, Dong-Ho;Kim, Seung-Ho
    • Journal of the Korean Wood Science and Technology
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    • v.28 no.2
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    • pp.49-56
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    • 2000
  • This study was designed to investigate the adsorption of heavy metal ions by untreated bark according to the treatment conditions of aqueous solution. The effect of temperature and pH of aqueous solution, particle size of bark, addition of light metal ions on the adsorption was examined, and the competition in adsorption among heavy metal ions was also evaluated. te The adsorption ratio of $Cu^{2+}$ and $Zn^{2+}$ increased with increasing themperature of solution from $-5^{\circ}C$ to $10^{\circ}C$ however, it was relatively constant at temperatures between $10^{\circ}C$ and $55^{\circ}C$. The adsorption ratio of $Cr^{6+}$ increased continuously with increasing the temperature of solution. The maximum adsorption ratio of $Cu^{2+}$, $Zn^{2+}$, and $Pb^{2+}$ was noted at pHs ranged 6 to 7; however, the adsorption ratio declined sharply on either sides of the optimum. The adsorption ratio of $Cr^{6+}$ decreased continuously with increasing the pH of solution. The adsorption ratio increased as decreasing the particle size of bark, and there was little differences in adsorption tendency between pine and oak bark. By the addition of $Ca^{2+}$ or $Mg^{2+}$(10~25 ppm), the adsorption ratio of $Cu^{2+}$ and $Zn^{2+}$ increased. An increase of the adsorption ratio was higher in oak bark than in pine bark. However, the adsorption ratio of $Pb^{2+}$ and $Cr^{6+}$ was not affected by the addition of light metal ions. As the mixed solution of 2 or 3 kinds of heavy metal ions($Cu^{2+}$, $Zn^{2+}$, $Pb^{2+}$) was treated with the untreated bark, the adsorption of $Zn^{2+}$ decreased considerably because of the competitive adsorption among heavy metal ions. Also the adsorption of $Cu^{2+}$ was more and less reduced. However the adsorption of $Pb^{2+}$ was not affected by the presence of other heavy metal ions.

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$(Na,Li)NbO_3-BaTiO_3$세라믹스의 유전 및 압전 특성

  • Seong, Geum-Hyeon;Lee, Yu-Hyeong;Ryu, Ju-Hyeon;Jeong, Yeong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.77-77
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    • 2009
  • $Pb(Zr,Ti_O_3$계 세라믹스는 우수한 압전 특성으로 인하여 압전변압기 및 액츄에이터, 센서 등 많은 분야에 응용이 되어져 왔다. 그러나, 최근 들어 $1000^{\circ}C$에서 급속도로 많은 휘발을 하는 PbO는 환경 및 인체에 나쁜 영향을 미칠 뿐 아니라 사용 후의 처리도 어려워 선진국에서는 사용을 제한하거나 줄이고 있는 추세에 있다. 따라서, PbO를 포함하지 않은 무연 (Lead-free)계 압전 세라믹스에 대한 연구가 많은 관심을 끌고 있으며 앞으로는E 장래성 있는 하나의 이슈 분야가 될 것이다. 이러한 Pb-based System 세라믹스를 대체 할 재료로서 $(Bi_{1/2}Na_{1/2})TiO_3$나 Tungsten-Bronze type, $(K_{1/2}Na_{1/2})NbO_3$ 등이 주로 연구가 되고 있다. 특히, alkali niobate를 기초로 한 $(K_{1/2}Na_{1/2})NbO_3(NKN)$은 무연 압전 물질로서 많은 주목을 받고 있다. 그러나, NKN의 주요 성분인 K 의 높은 조해성 때문에 일반적인 고상방법으로는 고 밀도의 세라믹을 얻기 힘들뿐더러 낮은 상전이 온도 때문에 많은 응용에는 제약이 되고 있다. 이러한 세라믹의 단점을 보완하고자 Hot forging, RTGG, SPS 등 과 같이 특수한 소결방법을 사용하여 고밀도의 세라믹을 제작하지만 이 방법들은 제품 대량 생산에 있어 경제적으로나 복잡한 제조과정을 고려할 때 매우 비효율적이라고 판단된다. 그러므로 $BaTiO_3$, $LiTaO_3$, Mg, Ca등을 첨가 시켜 소결을 향상시키고 고밀도를 얻기 위해 많은 연구가 진행 중이다. 따라서 본 연구에서는 Pb-based계의 세라믹스를 대체할 우수한 특성의 세라믹스를 제작하고자 기존의 $(K_{1/2}Na_{1/2})NbO_3(NKN)$세라믹스에서 낮은 용융온도 때문에 소결하기 어려운 $KNbO_3$를 제거한 $NaNbO_3$$LiNbO_3$$BaTiO_3$를 추가한 $NaLiNbO_3-BaTiO_3$세라믹스에 $K_4CuNb_8O_{23}$(KCN)을 첨가함으로서 이에 따른 압전 및 유전 특성을 조사하였다.

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Value of Ultrasonography in the Diagnosis of Carpal Tunnel Syndrome : Correlation with Electrophysiological Abnormalities and Clinical Severity

  • Kim, Min-Kyu;Jeon, Hong-Jun;Park, Se-Hyuck;Park, Dong-Sik;Nam, Hee-Seung
    • Journal of Korean Neurosurgical Society
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    • v.55 no.2
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    • pp.78-82
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    • 2014
  • Objective : To investigate a diagnostic value of ultrasonography in carpal tunnel syndrome (CTS) patients and to evaluate a correlation of sonographic measurements with the degree of electrodiagnostic abnormalities and clinical severity. Methods : Two-hundred-forty-six symptomatic hands in 135 patients and 30 asymptomatic hands in 19 healthy individuals as control group were included. In ultrasonographic study, we measured the cross-sectional area (CSA) and flattening ratio (FR) of the median nerve at the pisiform as well as palmar bowing (PB) of the flexor retinaculum. Sensitivity and specificity of ultrasonographic measurements were evaluated and ultrasonographic data from the symptomatic and control hands were compared to the grade of electrodiagnostic and clinical severity. Results : The mean CSA was $13.7{\pm}4.2mm^2$ in symptomatic hands and $7.9{\pm}1.3mm^2$ in asymptomatic hands. The mean FR was $4.2{\pm}1.0$ in symptomatic hands and $3.4{\pm}0.4$ in asymptomatic hands. The mean PB was $3.5{\pm}0.5$ mm in symptomatic hands and $2.6{\pm}0.3$ mm in asymptomatic hands. Statistical analysis showed differences of the mean CSA, FR and PB between groups were significant. A cut-off value of $10mm^2$ for the mean CSA was found to be the upper limit for normal value. Both the mean CSA and PB are correlated with the grade of electrophysiological abnormalities and clinical severity, respectively. Conclusion : Ultrasographic measurement of the CSA and PB is helpful to diagnose CTS as a non-invasive and an alternative modality for the evaluation of CTS. In addition, ultrasonography also provides a reliable correlation with the grade of electrodiagnostic abnormalities and clinical severity.

Piezoelectric property variation with respect to the frit addition for lower temperature sintering in PNW-PMN-PZT ceramic system (PNW-PMN-PZT 압전 세라믹의 저온소결을 위한 프리트 첨가 압전 특성평가)

  • Ryu, Sung-Lim;Kwon, Soon-Yong;Woo, Duck-Hyun;An, Sang-Gi;Jeong, Ji-Hyun;Um, Ju-Chul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.191-191
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    • 2008
  • 강유전성 세라믹스 재료로써는 PZT계열의 세라믹재료가 널리 쓰이고 있다. 이는 우수한 유전 및 압전특성을 가지고 있으나, PbO을 다량 함유하고 있어 $1000^{\circ}C$이상에서 PbO가 급격하게 휘발되는 성질 때문에 조성의 변동이 생겨 재현성이 어려우며 이를 방지하기 위하여 PbO를 과잉 첨가시키기 때문에 PbO휘발로 인한 강한 독성이 인체에 유해하고, 비환경 친화적인 물질로 최근에는 환경문제가 대두됨에 따라 대체 또는 보완 할 수 있는 방안에 검토되고 있다. 본 연구는 그 해결책의 한 방안으로 압전특성이 우수한 $(Pb_{0.94}Sr_{0.06})[(Ni_{1/2}W_{1/2})_{0.02}(Mn_{1/3}Nb_{2/3})_{0.07}(Zr_{0.51}Ti_{0.49})_{0.91}]O_3$계 조성을 설계하고 Glass frit(0~1.1 wt%)를 소량 첨가하여 액상 소결 특성을 부여하고 $1000^{\circ}C$ 이하의 저온에서 소결하여 유전 및 압전 특성을 평가하였다. 실험방법은 일반적인 세라믹스 제조공정으로 24시간 ball milling하고 $850^{\circ}C$에서 2시간 하소 후 Glass frit를 소결조제로 소랑 첨가하여 $1000^{\circ}C$ 이하 온도에서 소결을 진행하여 각 소결온도에 따른 유전 및 압전 특성을 평가하였다. 최종 소결된 시편의 밀도와 수축율을 분석하여 최적의 소결온도를 확립하였으며 XRD분석을 통해 perovskite구조를 확인하고 미세구조확인을 위해 SEM으로 관찰하였다. 압전 특성을 평가하였다.

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Application of Soil Washing Technology to the Soil Contaminated by Heavy Metals (중금속에 의해 오염된 토양에 대한 토양세척기법의 적용성 연구)

  • 정동철;이지희;최상일
    • Journal of Korea Soil Environment Society
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    • v.2 no.2
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    • pp.53-60
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    • 1997
  • A series of batch and lab-scale pilot tests were conducted to optimize the design parameters for the application of soil washing techniques to the soil contaminated by heavy metals. Cu, Pb, and Zn were selected as target heavy metals. The concentrations of Cu, Pb, and Zn were 500mg/kg dry soil, 1, 000mg/kg dry soil, and 500mg/kg dry soil, respectively. Citric acid and oxalic acid were used for the extractants. In the batch tests, the extraction efficiencies for Cu, Pb, and Zn were 79%, 72%, 72%, respectively. The proper extractant concentration and dilution ratio(weight/volume) for Cu and Pb were turned to be citric acid 50mM and 1:5, respectively. The extraction efficiencies were enhanced with the addition of 1~2% OA-5 or SDS. From pilot scale tests for Pb, first stage and second stage of soil washing resulted in the extraction efficiency of 59% and 78%, respectively.

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Recovery of Yttrium from the Sludge Generated in Recycling Process of the Obsolete CRT (폐CRT의 재활용 공정에서 발생한 슬러지로부터 Y의 회수)

  • 전준미;이재천;정진기;김남철
    • Resources Recycling
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    • v.10 no.6
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    • pp.22-28
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    • 2001
  • A study on the recovery of yttrium was conducted using the phosphor sludges generated in the recycling process of obsolete CRTs. Yttrium was leached by HCl and $HNO _3$. The leaching efficiency of yttrium was extensively investigated in terms of acid concentration, leaching temperature and time, and pulp density. Yttrium and lead was recovered from leaching solutions also by precipitation method. The leaching behavior of yttrium was similar in both acids. The leaching efficiency of yttrium for both acids increased with time at the conditions of 3.0M, $90^{\circ}C$, and 280 g/L of pulp density. After 40 minutes, it was saturated to 93% and 90% for HCl and HNO$_3$respectively. Yttrium was recovered from leaching acid solution by the addition of $H_2$$C_2$$O_4$while lead was removed as $PbSO_4$by $Na_2$ $SO_4$.

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