• 제목/요약/키워드: Paste Electrode

검색결과 255건 처리시간 0.027초

Bi 계열 Glass Frit 조성이 계면저항에 미치는 영향 (The Effects of Composition on the Interface Resistance in Bi-System Glass Frit)

  • 김인애;신효순;여동훈;정대용
    • 한국전기전자재료학회논문지
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    • 제26권12호
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    • pp.858-862
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    • 2013
  • The front electrode should be used to make solar cell panel so as to collect electron. The front electrode is used by paste type, printed on the Si-solar cell wafer and sintered at about $800^{\circ}C$. The paste is composed Ag powder and glass frit which make the ohmic contact between Ag electrode and n-type semiconductor layer. From the previous study, the Ag electrodes which used two commercial glass frit of Bi-system were so different on the interface resistance. The main composition of them was Bi-Zn-B-Si-O and few additives added in one of them. In this study, glass frit was made with the ratio of $Bi_2O_3$ and ZnO on the main composition, and then paste using glass frit was prepared respectively. And, also, the paste using the glass frit added oxide additives were prepared. The change of interface resistance was not large with the ratio of $Bi_2O_3$ and ZnO. In the case of G6 glass frit, 78 wt% $Bi_2O_3$ addition, the interface resistance was $190{\Omega}$ and most low. In the glass frit added oxide, the case of Ca increased over 10 times than it of G6 glass frit on the interface resistance. It was thaught that after sintering, Ca added glass frit was not flowed to the interface between Ag electrode and wafer but was in the Ag electrode.

Determination of Ag(Ⅰ) Ion at a Modified Carbon Paste Electrode Containing N,N'-Diphenyl Oxamide

  • Won, Mi-Sook;Yeom, Jeong-Sik;Yoon, Jang-Hee;Jeong, Euh-Duck;Shim, Yoon-Bo
    • Bulletin of the Korean Chemical Society
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    • 제24권7호
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    • pp.948-952
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    • 2003
  • New approach for the determination of Ag(I) ion was performed by using a carbon paste electrode (CPE) containing N,N'-Diphenyl oxamide (DPO) with anodic stripping voltammetry. The CMEs have been prepared by making carbon paste mixtures containing an appropriate amount of DPO salt coated onto graphite particles to analyze trace metal ions via complexation followed by stripping voltammetry. Various experimental parameters affecting the response, such as pH, deposition time, temperature, and electrode composition, were carefully optimized. Using differential pulse anodic stripping voltammetry, the logarithmic linear response range for the Ag(I) ion was 1.0 × $10^{-7}$ - 5.0 × $10^{-9}$ M at the deposition time of 10 min, with the detection limit was 7.0 × $10^{-10}$ M. The detection limit adopted from anodic stripping differential pulse voltammetry was 7.0 × $10^{-10}$ M for silver and the relative standard deviation was ± 3.2% at a 5.0 × $10^{-8}$ M of Ag(I) ion (n = 7). The proposed electrode shows a very good selectivity for Ag(I) in a standard solution containing several metals at optimized conditions.

Effect of Frit Content in Ag Paste on the Discoloration of Transparent Dielectric in PDP

  • Jeon, Jae-Sam;Kim, Hyung-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
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    • pp.1248-1251
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    • 2005
  • In PDP, a transparent dielectric is formed on a front glass substrate so as to cover bus electrodes (Ag). During the fabrication process, sometimes, a transparent dielectric reacts with bus (Ag) electrode in the range of $560-600^{\circ}C$, and the reaction gives the dielectric its yellow coloration, what is called "yellowing phenomena". In this paper, we investigated the reaction between bus electrode and transparent dielectric covered with different frit content in Ag paste.

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전기화학적 방법에 의한 HRP의 최적 pH 도출 (Electrochemical Determination of the Optimum pH of HRP)

  • 윤길중
    • 분석과학
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    • 제16권6호
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    • pp.504-508
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    • 2003
  • A carbon paste electrode was constructed with peroxidase extracted from Horseradish and the variation of the response of the sensor with pH was investigated. Current profiles showed two highest sensitivities at two pH values respectively. In addition, two bands were observed in the electrophoretic expansion. A coincidence of the two experimental results added support to the possibility that the biosensor has two different isozymes. Assuming that current profiles are the sum of two gaussians, we deconvoluted them and determined the optimum pH of peroxidase isozymes.

Electrochemical Detection of Pesticide in Living Plant and Fish Brain Cell

  • Lee, Chang-Hyun;Ly, Suw-Young
    • 한국환경과학회지
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    • 제19권8호
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    • pp.941-949
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    • 2010
  • The three electrode system was used to detect the pesticide fenitrothion ($C_9H_{12}NO_5PS$. MW=277.24) using cyclic voltammetry (CV) and square wave anodic stripping voltammetry (SWASV). The working electrode was mercury immobilized on a carbon nanotube paste electrode (Hg-CNTPE). At the optimized condition, the limit of detection (LoD) was 0.6 ppt ($2.16{\times}10^{-12}\;M$), and the relative standard deviation was 0.035% (n=15). And there is more sensitive in detecting fenitrothion than common type carbon nanotube paste electrode. When it was implanted into the brain of live fish (carp), the existence of fenitrothion was measured without any destruction or damage of tissue.

Formation of Black Matrix and Ag Electrode Patterns by Photolithographic Process for High Resolution PDP

  • So, Jae-Yong;Kwon, Hyeok-Yong;Kim, Suk-Kyung;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.369-372
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    • 2008
  • Black matrix and Ag electrode with uniform line pitches were successfully fabricated through the photolithographic process by using the photosensitive black pastes and Ag pastes with optimized photosensitive properties for high resolution PDPs. The photosensitivity of the black and Ag pastes in the photolithographic process was investigated with the variation of photosensitive BM and Ag pastes and the photolithography process conditions. The important components and formulation of the photosensitive BM and Ag paste we discussed.

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Electrochemical Investigation of Animal Tissue Embedded Biosensor Bound with Ethylene-Propylene Rubber

  • Yoon, Kil-Joong
    • Bulletin of the Korean Chemical Society
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    • 제31권10호
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    • pp.2913-2917
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    • 2010
  • When rubber dissolved in toluene was used as a binding material of graphite powder, the mechanical robustness of the carbon paste was guaranteed by the fast volatility of the solvent immediately after electrode construction. This characteristic of the rubber solution met qualifications for practical use of carbon paste electrodes and enabled the design of a new enzyme electrode bound with EPDM. In order to confirm whether the electrode shows quantitative electrochemical behaviors or not, its kinetic parameters, e. g. the symmetry factor (0.2), the exchange current density ($3.66\;{\mu}A/cm^2$), the capacity of the double layer ($2.0{\times}10^{-5}\;F$), the Michaelis constant ($4.39{\times}10^{-3}\;M$), the diffusion coefficient of substrate ($2.58{\times}10^{-12}\;cm^2/sec$), the time constant (0.018 sec) and other factors were investigated.

LTCC 기판의 Particle Size 에 따른 Ag-Pd 전극의 Soldering 특성 변화 (Soldering characteristics of Ag-Pd electrodes in relationship to differing particle size of LTCC substrate)

  • 조현민;유명재;박종철
    • 한국마이크로전자및패키징학회:학술대회논문집
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    • 한국마이크로전자및패키징학회 2002년도 춘계 기술심포지움 논문집
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    • pp.130-133
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    • 2002
  • Solder leaching resistance of the metal electrode is an important factor with regard to adhesion properties of ceramic substrate. In the Low Temperature Co-fired Ceramics (LTCC), Ag-Pd or Ag-Pt pastes are used instead of pure Ag paste to prevent leaching. Solder leaching behavior of the Ag-Pd paste in relation to LTCC raw material powder size was investigated. First fabrication of LTCC green tape with different particle size was done. LTCC substrates with Ag-Pd electrode were prepared using conventional multilayer ceramic process. Dipping test was performed to test solder leaching behavior of the electrode. Ag-Pd electrode on LTCC substrate with smaller particle size achieved higher solder leaching resistance.

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백금 도금된 탄소반죽 전극을 이용한 일회용 글루코오스 센서 (Disposable Glucose Sensor Based on Platinised Carbon Paste Electrode)

  • 이동주;유재현;최강;최문희;김문환;류준오;한상현;차근식;남학현
    • 전기화학회지
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    • 제2권4호
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    • pp.227-231
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    • 1999
  • Carbon paste전극을 백금도금 한 후 이 전극을 사용한 일회용 전류법 glucose센서를 제작하였다. 전극에 시료용액을 가한 후, voltammetry을 이용하여 본 센서의 감응성을 연구하였다. screen printing된 carbon paste전극 표면 위에 전기도금 방법으로 도입된 백금은 센서의 분석성능과 mediator의 전기 화학적 가역성을 크게 향상시켜 준다. 제작된 센서가 $[Fe(CN)_6]^{4-/3-}$에 대한 heterogeneous rate constant는 $1.45\times10^{-2}cm{\cdot}s^{-1}$이며, 이 센서는 적용전위 0.3V vs. Ag/AgCl에서 glucose에 대한 좋은 감응성을 보여주었다. 이 때 glucose에 대한 Michaelis-Menten상수는 24.5mM이다. 일회용 glucose 스트립 센서의 분석성능을 평가하기 위하여 NOVA S.P. Ultra M analyzer와 비교실험을 수행하였다. 이 때 시료용액으로서 $80\~297 mg/dL$ 범위의 glucose를 함유하고 있는 30여 종류의 혈청을 사용하였고, 상관계수는 0.983으로서 정밀도와 정확도가 비교적 우수함을 보여주었다.