• Title/Summary/Keyword: Particulate Matters

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A Study on Selective Catalytic Reduction on Diesel Particulate Filter Catalyst and Coating Technology the Removal of Particulate Matters and NOx for Old Special Cargo Vehicles (노후 특수·화물 차량 PM/NOx 저감을 위한 SDPF 촉매 및 코팅 기술 연구)

  • Jeong, Kwanhyoung;Seo, Philwon;Oh, Hungsuk;Kim, Jongkook;Kang, Soyeon;Kang, Jeongho;Kim, Hyunjun;Shin, Byeongseon
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.695-699
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    • 2021
  • In this study, Selective Catalytic Reduction on Diesel Particulate Filter (SDPF) after-treatment system was introduced to simultaneously remove NOx and Particulate Matters (PM) emitted from trucks and special cargo vehicles using old engine. First, in order to select an Selective Catalytic Reduction (SCR) catalyst for SDPF, the de-NOx performance of V/TiO2 and Cu-Zeolite catalysts were compared, and the SCR catalyst characteristics were analyzed through Brunauer Emmett Teller (BET), X-ray Diffraction (XRD) and NH3-TPD (Temperature Programmed Desorption). From the activity test results, the Cu-zeolite catalyst showed the best thermal stability. For optimal coating of SDPF, slurry was prepared according to the target particle size. From the coating stability and back pressure test results of SDPF according to the amount of SCR coating, As a result of comparing coating stability, back pressure, and de-NOx performance by producing A, B, and C samples for each loading amount of the SDPF catalyst, the best results were found in the B sample. The engine dynamometer test was conducted for the optimal SDPF after-treatment system, and the test results satisfied Eu-5 regulations.

Measurements of Polycyclic Aromatic Hydrocarbons(PAHs) Concentration in Air of the Seoul Underground Shopping Stores (서울시 지하상가 공기중 다환방향족 탄화수소의 농도조사에 관한 연구)

  • 전준민;김윤신
    • Journal of Korean Society for Atmospheric Environment
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    • v.9 no.1
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    • pp.81-92
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    • 1993
  • A purpose of this study was carried out to investigate the concentrations of four elements of PAHs(Polycyclic Aromatic Hydrocarbons) in suspended particulate matters of underground shopping stores in Seoul city. The particulate matters were collected at five underground shopping stores(Yongdungpo, Myongdong, Ulchiro, Express Terminal, Chamshil) in the Seoul area during February-October, 1992. Samples were collected using cascade impactor of low volumn air sampler and were analysed using High Performance Liquid Chromatography(HPLC) with fluorescence detector. Calibration on HPLC analyse is nearly accord with retention time between the standard solution and the samples. Analysed results obtained favorable analysing recovery rate of 97.3% and coefficient of variation of 1.60%. Mean concentrations of suspended particulate matters in five underground shopping stores wre 216.3 g/$m^3$ and observed higher at fine particles(117.2 g/$m^3$) which is respirable particulates than coarse particles(99.2 g/$m^3$). Concentrations of four species PAH were determined with anthracene of 16.8ng/$m^3$, fluoranthene of 72.3ng/$m^3$, benzo(a)pyrene of 0.54ng/$m^3$, and benzo(k)fluoranthene of 0.29ng/$m^3$, respectively. Fluoranthene levels were significantly higher than those levels in other components. PAHs concen-tration at shopping areas showed 21.3ng/$m^3$ in Yongdungpo, 35.1ng/$m^3$ in Myongdong, 23.4ng/$m^3$ in Ulchiro, 11.1ng/$m^3$ in Express Terminal, and 21.4ng/$m^3$ in Chamshil, respectively. Particularly, benzo(a)pyrene and benzo(k)-fluoranthene were detected over 83 percentage in fine particles, while fluoranthene wre highly detected in coarse particles. Also, higher concentrations of benzo(a)pyrene, benzo(k)fluoranthene were found in winter while levels of anthracene and fluoranthene were found higher in summer than other seasons.

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Characteristics of Ionic Components in Size-resolved Particulate Matters in Suwon Area (수원지역 분진의 입경별 이온성분 분포특성에 관한 연구)

  • Oh, Mi-Seok;Lee, Tae-Jung;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.1
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    • pp.46-56
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    • 2009
  • The main purpose of this study was to investigate air quality trends of ambient aerosol with obtaining size-fractionated information. The suspended particulate matters were continuously collected on membrane filters and glass fiber filters by an 8-stage cascade impactor for 2 years (Sep. 2005 $\sim$ Sep. 2007) in Kyung Hee University-Global Campus. 8 ionic species ($Na^+$, ${NH_4}^+$, $K^+$, $Mg^{2+}$, $Ca^{2+}$, $Cl^-$, ${NO_3}^-$, and ${SO_4}^{2-}$) were analyzed by an IC after performing proper pretreatments of each sample filter. The average concentration levels of each ion were $9.24{\mu}g/m^3$ of ${SO_4}^{2-}$, $7.35{\mu}g/m^3$ of ${NO_3}^-$, $2.81{\mu}g/m^3$ of ${NH_4}^+$, $2.11{\mu}g/m^3$ of $Ca^{2+}$, $1.65{\mu}g/m^3$ of $Cl^-$, $1.87{\mu}g/m^3$ of $Na^+$, $0.80{\mu}g/m^3$ of $Mg^{2+}$, and $0.54{\mu}g/m^3$ of $K^+$, respectively. The distribution pattern of $Na^+$, $Mg^{2+}$, $Ca^{2+}$, $Cl^-$, and ${NO_3}^-$ was bi-modal and two peaks appeared in the range of $0.4{\sim}0.7{\mu}m$ and $3.3{\sim}4.7{\mu}m$, respectively. On the other hand, ${SO_4}^{2-}$, ${NH_4}^+$, and $K^+$ showed patterns of uni-modal distribution, mostly abounded in the fine mode group.

Collection Characteristics of Particulate Matters from Biomass Burning by Control Devices: Mainly Commercial Meat Cooking (생물성연소에서 발생하는 미세먼지의 장치별 집진 특성: 고기구이를 중심으로)

  • Park, Seong-Kyu;Choi, Sang-Jin;Park, Geon-Jin;Kim, Jin-Yun;Bong, Choon-Keun;Park, Seong-Jin;Kim, Jong-Ho;Hwang, Ui-Hyun
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.6
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    • pp.641-649
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    • 2011
  • The aim of this study is to understand the characteristics of exhausting particulate matters (PM) and to control emitted PM from meat cooking restaurants. We found that $PM_{2.5}$, $PM_{5.0}$ occupy 69.2% and 98.6% of total PM from pork cooking, respectively. Therefore, we can see that it is not easy to remove PM generated from a pork cooking process. The collection efficiencies of various control devices, which are a condensing scrubber, a cyclone, an impactor, an oil filter and an electrostatic precipitator (ESP), were measured and compared. ESP had the highest collection efficiency (88.6%) and condensing scrubber had the lowest one (68.0%). However, the system recovering property should be considered to choose a control device because PM from meat cooking process are extremely stickiness. Therefore, we can recommend that ESP following an impactor or a cyclone is the best combination to remove PM generated from meat cooking restaurants.

Optimization of an Ozone-based Advanced Oxidation Process for the Simultaneous Removal of Particulate Matters and Nitrogen Oxides in a Semiconductor Fabrication Process (반도체 제조공정 미세먼지-질소산화물 동시 저감을 위한 오존 고속산화공정 최적화 연구)

  • Uhm, Sunghyun;Lee, Seung Jun;Ko, Eun Ha;Hong, Gi Hoon;Hwang, Sangyeon
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.659-663
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    • 2021
  • 10 m3/min (CMM) multi-pollutants abatement system was successfully developed by effectively integrating ozone oxidation, wet scrubbing, and wet electrostatic precipitation for the simultaneous removal of particulate matters (PMs) and NOx in a semiconductor fabrication process. The sophisticated control and optimization of operating parameters were conducted to maximize the destruction and removal efficiency of NOx. In particular, the stability test of a wet electrostatic precipitator was carried out in parallel for 30 days to validate the reliability of core parts including a power supply. An O3/NO ratio, which is the most important operating parameter, was optimized to be about 1.5 and the optimization of wet scrubbing with a reducing agent made it possible to analyze the contribution of neutralization reaction.

A Study on the Enhancement of Inventories for Precursors (NOx, SOx) Released from Open Burning of Agricultural Waste Vinyl Causing the Secondary Generation of Particulate Matters

  • Kim, Tae-Han;Choi, Boo-Hun
    • Journal of People, Plants, and Environment
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    • v.24 no.2
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    • pp.195-207
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    • 2021
  • Background and objective: While response measures to particulate matters in rural areas are limited due to poor inventory record keeping in the agricultural sector, it is necessary to control agricultural waste vinyl and the emission of precursors released from open burning and the secondary generation of particulate matters. Currently, the open burning emission calculation method uses the definition prescribed in CAPSS by the National Institute of Environmental Research. Methods: This study presented an open burning emission calculation formula for agricultural waste vinyl, which is included as agricultural waste. As for activity data, the open burning ratio of agricultural waste vinyl, and the annual incineration volume provided in the Status Survey by the Ministry of Agriculture, Food, and Rural Affairs were applied. The emission factor was generated through incineration tests on three agricultural plastic film samples collected by the Korea Environment Corporation. Results: Among precursors, SOx and NOx were selected and their emission features were monitored with incineration experiment infrastructure based on the EPA 5G method. The highest emission concentration by agricultural waste type was concentrated in the first and second quarters. As for emission factor of SO2, it was calculated at 98.25 g/kg for mulching-use LDPE, 52.31 g/kg for greenhouse-use LDPE, and 14.40 g/kg for HDPE. As for NOx, it was calculated at 18.21 g/kg for mulching-use LDPE, 16.49 g/kg for greenhouse-use LDPE, and 10.67 g/kg for HDPE. Conclusion: This test confirmed the incineration features of PE-based plastics, ascertained the SOx emission factor that had not been included in open burning in the past, and established that low NOx emission concentration is interfered by soil mixed with livestock excretions. The findings from this study are expected to contribute to improving the system for controlling air pollutants in rural environments.