• 제목/요약/키워드: Particle-free

검색결과 612건 처리시간 0.024초

Preparation and Characterizations of C60/Polystyrene Composite Particle Containing Pristine C60 Clusters

  • Kim, Jung-Woon;Kim, Kun-Ji;Park, Soo-Yeon;Jeong, Kwang-Un;Lee, Myong-Hoon
    • Bulletin of the Korean Chemical Society
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    • 제33권9호
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    • pp.2966-2970
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    • 2012
  • Fullerene/polystyrene ($C_{60}$/PS) nano particle was prepared by using emulsion polymerization. Styrene and fullerene were emulsified in aqueous media in the presence of poly(N-vinyl pyridine) as an emulsion stabilizer, and polymerization was initiated by water soluble radical initiator, potassium persulfate. The obtained nano particles have an average diameter in the range of 400-500 nm. The fullerene contents in the nano particle can be controlled up to 15 wt % by varying the feed ratio, which was confirmed by themogravimetric analysis (TGA) and elemental analysis (EA). The structure and morphologies of the $C_{60}$/PS nano particles were examined by various analytical techniques such as dynamic light scattering (DLS), scanning electron microscope (SEM), transmission electron microscope (TEM), electron diffraction (ED) pattern, X-ray powder diffraction (XRD), and UV spectroscopy. Unlike conventional $C_{60}$/PS particles initiated by organic free radical initiators, in which the fullerene is copolymerized forming a covalent bond with styrene monomer, the prepared $C_{60}$/PS nano particles contain pristine fullerene as secondary particles homogeneously distributed in the polystyrene matrix.

인조스웨드의 견뢰도 향상에 관한 연구 (3) (Enhancement of Dyeing Fastness of Artificial Suede (3))

  • 김경필;김혜인
    • 한국염색가공학회지
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    • 제28권4호
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    • pp.280-289
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    • 2016
  • Silica microgel was prepared by sol-gel process and then functional groups, epoxy group and ethoxy group, were introduced on the particle by coupling treatment with 3-glysidoxypropyltrimethoxysilane. The functional silica microgel(functional SiGel) formation was identified using FT-IR spectrometry. Phase stability for DMF solution of functional SiGel, PU resin and pigment was evaluated by Turbiscan Lab. And physical properties of artificial suede including hand values, morphology and dyeing fastness were investigated. The mean particle size and the specific surface area of the functional SiGel were $0.77{\mu}m$ and $380m^2/g$. Mixture containing the functional SiGel, PU resin and pigment was more stable than the functional SiGel-free mixed solution. Artificial suede prepared by the functional SiGel had appearance and feeling close to natural suede. The migration fastness, the solvent wicking fastness and rubbing fastness of the artificial suede were enhanced to 4~5 grades, 4~5 grades and 3~4 grades, respectively.

물의 양성자완화에 의한 기생 강자성 ${\alpha}-Fe_{2}O_{3}$의 자기능률 결정 (Determination of the Magnetic Moment of ${\alpha}-Fe_{2}O_{3}$ of the Parasitic Ferromagnetism by the Proton Relaxation in Water)

  • Yong-Jin Kim;Jung-Gi Kim
    • 한국자기학회지
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    • 제4권3호
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    • pp.282-284
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    • 1994
  • 물의 양성자완화에 의하여 기생 강자성 ${\alpha}-Fe_{2}O_{3}$의 유효 자기능률 결정을 위한 이론식을 유도하였다. 그 이론식을 유도함에 있어서 그 결정입자의 대응전자스핀과 물분자의 양성자 스핀사이의 거리가 상대적 거리보다 오히려 동경벡터로 고려되어야 한다는 사실을 제외하고서 자유 상자성 이론들을 함유함고 있는 수용액에 적용된 수학적 과정과 정확히 동일하다는 것을 알았다. 또한 유도된 이론식에 의하여 계산된 결정입자의 유효자기능률이 Hiral에 의하여 결정된 실험치 잘 일치함을 알았다.

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A study on Nickel Hydroxide Crystallization for Plating waste Treatment

  • Lee, Chang-Hwan;Lee, Choul-Ho
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.292-295
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    • 2001
  • A Study on the precipitation characteristics of nickel hydroxide as well as carbonate and sulfide is carried out to determine the proper treatment condition of the wastewater induced from nickel-plating industry. The nickel concentrations in the effluent could be kept lower than 5ppm when the value of pH was maintained higher than 10. The precipitation of nickel salts by alkaline addition to the nickel containing model wastewater was conducted by using proper amount of sodium hydroxide, sodium carbonate, sodium bicarbonate and sodium sulfide. In case of the sulfide treatment, the residual nickel concentration in the clear water after precipitates removed showed the lowest value. The influences of the precipitation condition upon the particle size of the crystals precipitated were also investigated. In spite of the various precipitation conditions were adopted, the particle size of the precipitated crystals showed no great differences. The sedimentation rates of the precipitated particle bed were observed and the free sedimentation period was terminated within 20 minutes. Although the hindered sedimentation as well as bed compaction progressed subsequently, the bed heights were maintained almost the same level after two hours of sedimentation.

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Nondestructive Bending Strength Evaluation of Ceramics Made from Miscanthus sinensis var. purpurascens Particle Boards - Effect of Resin Impregnation Ratio -

  • Byeon, Hee-Seop;Won, Kyung-Rok;Oh, Seung-Won
    • Journal of the Korean Wood Science and Technology
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    • 제42권2호
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    • pp.130-137
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    • 2014
  • Nondestructive evaluation (NDE) method by using a resonance frequency mode was carried out for ceramics made from particle boards with different phenol resin impregnation ratios (30, 40, 50, 60%) at carbonizing temperature of $800^{\circ}C$. The material for ceramics was Miscanthus sinensis var. purpurascens board. Dynamic modulus of elasticity increased with increasing impregnation ratio. There was a close relationship of dynamic modulus of elasticity and static bending modulus of elasticity to modulus of rupture (MOR). However, the result indicated that correlation coefficient is higher in dynamic modulus of elasticity to MOR than that in static modulus of elasticity to MOR. Therefore, the dynamic modulus of elasticity using resonance frequency by free vibration mode is more useful as a nondestructive evaluation method for predicting the MOR of ceramics made from Miscanthus sinensis var. purpurascens particle boards by different phenol resin impregnation ratios.

Prepartion and Characterization of the Pt doped $TiO_2$ Membranes

  • Bae, Dong-Sik;Han, Kyong-Sop;Choi, Sang-Hael
    • The Korean Journal of Ceramics
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    • 제3권1호
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    • pp.52-56
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    • 1997
  • The Pt doped $TiO_2$ composite membranes were prepared by the sol-gel process. The Pt doped titania sol was peptized with hydrochloric acid in the pH range of 1.23 to 1.32 at 5$0^{\circ}C$. The average particle size of the Pt doped titania sol was shown to be below 15nm and well dispersed in the solution. XPS show the Pt elements continuous and homogeneous dispersed in the $TiO_2$ membrane. The mean particle size of the Pt doped $TiO_2$ composite membrane has smaller than that of the undoped $TiO_2$ composite membrane. The average pore size of the Pt doped $TiO_2$ composite membrane was increased from 58 to 193 $\AA$ with firing temperature changed from 550 to 85$0^{\circ}C$. It was observed that the Pt doped $TiO_2$ composite membranes showed crack-free and homogeneous microstructue as well as narrow particle size distribution up to above 75$0^{\circ}C$.

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SPH 기법의 계산인자 민감도에 대한 연구 (Study on the Effects of Computational Parameters in SPH Method)

  • 김유일;남보우;김용환
    • 대한조선학회논문집
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    • 제44권4호
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    • pp.398-407
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    • 2007
  • A smoothed particle hydrodynamics (SPH) method is applied for simulating two-dimensional free-surface problems. The SPH method based on the Lagrangian formulation provides realistic flow motions with violent surface deformation, fragmentation and reunification. In this study, the effect of computational parameters in SPH simulation is explored through two-dimensional dam-breaking and sloshing problem. The parameters to be considered are the speed of sound, the frequency of density re-initialization, the number of particle and smoothing length. Through a series of numerical test. detailed information was obtained about how SPH solution can be more stabilized and improved by adjusting computational parameters. Finally, some numerical simulations for various fluid flow problem were carried out based on the parameters chosen through the sensitivity study.

바닥 조파장치가 설치된 수로에서 규칙파의 유속장에 관한 해석해 개발 (Development of Analytical Solutions on Velocities of Regular Waves Generated by Bottom Wave Makers in a Flume)

  • 정재상;이창훈
    • 한국해안·해양공학회논문집
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    • 제34권3호
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    • pp.58-71
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    • 2022
  • 본 연구에서는 바닥 조파장치가 설치된 수로에서 재현된 규칙파의 2차원 유속장에 대한 해석해를 유도하였다. 바닥 조파장치로 삼각형 및 사각형 형상이 적용되었다. 선형파 이론과 움직이는 바닥에 대한 경계조건, 동역학적 및 운동학적 자유수면 경계조건을 이용하여 속도포텐셜을 유도하였으며, 이로부터 각 방향 성분의 유속에 대한 해석해를 구하였다. 적분식 형태로 유도된 속도포텐셜 및 유속에 대한 해석해를 수치해석으로 계산하였다. 유도된 해석해는 바닥 조파장치가 설치된 조파수로에서 규칙파의 유속 특성에 대해 물리적으로 타당한 결과를 보였다.

하전입자의 응집성장에 대한 수치적 연구 (Numerical Simulation for the Aggregation of Charged Particles)

  • 박형호;김상수;장혁상
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집D
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    • pp.605-611
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    • 2001
  • A numerical technique for simulating the aggregation of charged particles was presented with a Brownian dynamic simulation in the free molecular regime. The Langevin equation was used for tracking each particle making up an aggregate. A periodic boundary condition was used for calculation of the aggregation process in each cell with 500 primary particles of 16 nm in diameter. We considered the thermal force and the electrostatic force for the calculation of the particle motion. The morphological shape of aggregates was described in terms of the fractal dimension. The fractal dimension for the uncharged aggregate was $D_{f}=1.761$. The fractal dimension changed slightly for the various amounts of bipolar charge. However, in case of unipolar charge, the fractal dimension decreased from 1.641 to 1.537 with the increase of the average number of charges on the particles from 0.2 to 0.3 in initial states.

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THE SMOOTHED PARTICLE HYDRODYNAMICS AND THE BINARY TREE COMBINED INTO BTSPH: PERFORMANCE TESTS

  • KIM W. -T.;HONG S. S.;YUN H. S.
    • 천문학회지
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    • 제27권1호
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    • pp.13-29
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    • 1994
  • We have constructed a 3-dim hydrodynamics code called BTSPH. The fluid dynamics part of the code is based on the smoothed particle hydrodynamics (SPH), and for its Poisson solver the binary tree (BT) scheme is employed. We let the smoothing length in the SPH algorithm vary with space and time, so that resolution of the calculation is considerably enhanced over the version of SPH with fixed smoothing length. The binary tree scheme calculates the gravitational force at a point by collecting the monopole forces from neighboring particles and the multipole forces from aggregates of distant particles. The BTSPH is free from geometric constraints, does not rely on grids, and needs arrays of moderate size. With the code we have run the following set of test calculations: one-dim shock tube, adiabatic collapse of an isothermal cloud, small oscillation of an equilibrium polytrope of index 3/2, and tidal encounter of the polytrope and a point mass perturber. Results of the tests confirmed the code performance.

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