• Journal of Environmental Science International
• /
• v.14 no.2
• /
• pp.221-230
• /
• 2005

Catalytic wet oxidation of trichloroethylene (TCE) in water has been conducted using $TiO_2-supported$ cobalt oxides at $36^{\circ}C$ with a weight hourly space velocity of $7,500\;h^{-1}.\;5\%\;CoO_x/TiO_2$, prepared by using an incipient wetness technique, might be the most promising catalyst for the wet oxidation although it exhibited a transient behavior in time on-stream activity. Not only could the bare support be inactive for the wet decomposition reaction, but no TCE removal also occurred by the process of adsorption on $TiO_2$ surface. The catalytic activity was independent of all particle sizes used, thereby representing no mass transfer limitation in intraparticle diffusion. XPS spectra of both fresh and used Co surfaces gave different surface spectral features for each $CoO_x,\;Co\;2P_{3/2}$ binding energy for Co species in the fresh catalyst appeared at 781.3 eV, which is very similar to the chemical states of $CoTiO_x$ such as $CO_2TiO_4\;and\;CoTiO_3$. The used catalyst exhibited a 780.3-eV main peak with a satellite structure at 795.8 eV. Based on XPS spectra of reference Co compound, the TCE-exposed Co surfaces could be assigned to be in the form of mainly $Co_3O_4$. XRD patterns for $5\%\;CoO_x/TiO_2$ catalyst indicated that the phase structure of Co species in the catalyst even before reaction is quite comparable to the diffraction lines of external $Co_3O_4$ standard. A model structure of $CoO_x$ present predominantly on titania surfaces would be $Co_3O_4$, encapsulated in thin-film $CoTiO_x$ species consisting of $Co_2TiO_4$ and $CoTiO_3$, which may be active for the decomposition of TCE in a flow of water.

• Journal of Environmental Science International
• /
• v.19 no.11
• /
• pp.1423-1436
• /
• 2010

The effects of meteorological and reclaiming conditions on the reduction of suspended particles are investigated using a computational fluid dynamics (CFD) model with the k-$\varepsilon$ turbulence closure scheme based on the renormalization group (RNG) theory. Twelve numerical experiments with different meteorological and reclaiming conditions are performed. For identifying the meteorological characteristics of the target area and providing the inflow conditions of the CFD model, the observed data from the automatic weather station (AWS) near the target area is analyzed. Complicated flow patterns such as flow distortion, horse-shoe vortex, recirculation zone, and channeling flow appeared due to the topography and buildings in the domain. Specially, the flow characteristics around the reclamation area are affected by the reclaiming height, reclaiming size and windbreak height. Reclaiming height affected the wind speed above the reclaiming area. Windbreak induces more complicated flow patterns around the reclaiming area as well as within the reclaiming area. In front of the windbreak, flow is distorted as it impinges on the windbreak. As a result, upward flow is generated there. Behind the windbreak, a secondary circulation, so called, a recirculation zone is generated and flow is reattached at the end of the recirculation zone (reattachment point). At the lower part of the recirculation zone, there is a reverse flow toward the windbreak. Flow passing to the reattachment point starts to be recovered. Total amounts of suspended particles are calculated using the frictional and threshold frictional velocities, erosion potential function, and the number of surface disturbance. In the case of a 10 m-reclaiming and northerly wind, the amount of suspended particles is largest. In the presence of 5 m windbreak, the friction velocity above the reclaiming area is largely reduced. As a result, the total amount of the suspended particles largely decreases, compared to the case with the same reclaiming and meteorological conditions except for the windbreak The calculated suspended particle amounts are used as the emission rate of the dispersion model simulations and the dispersion characteristics of the suspended particles are analyzed.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.31 no.3B
• /
• pp.205-209
• /
• 2011

The low carrying capacity caused by the deposition in a sewer line is one of the main reason of the urban flood. Therefore, an efficient maintenance and management of the storm water drainage system is very important to prevent urban flood. In this research, the sediment transport characteristics through a pressure pipeline were examined with laboratory experiments. Bed-forms in a pipeline, sediment rates, roughness due to sediments were examined. Experimental system consists of flow circulation system with a pump and a sediment feeder at the upstream of the pipeline. Sediments were supplied into a 60 mm-diameter and 8 m-long pipe. Maximum flow rate is $30m^3/hr$, and the sediment feeding rate range is 5 g/s~19 g/s. Governing parameters and estimation equation for sediment transport rate were developed. The mean velocity (U), coefficient of viscosity (${\mu}$), unit width bed load ($q_b$), mean diameter of particle ($d_{50}$), unit weight of sediment in water (${\gamma}^{\prime}_s$) were adopted as the most influencing factors of sediment transport patterns. The prediction equation for sediment transport rate were developed with two dimensionless terms. These two dimensionless terms showed a linear relationship with high correlation coefficient.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.21 no.10
• /
• pp.144-149
• /
• 2020

Bubble reduction devices are intended to solve problems related to the quantitative supply of oil. Therefore, in this study, numerical analysis was conducted to verify the flow characteristics of bubble particles during the operation of a bubble reduction device. As a result of the basic analysis, the area where the rise and fall of bubbles were most active was found, and numerical calculations were performed focusing on the points. Before the numerical calculations, a non-dimensional derivation was performed to secure homogeneity among the variables. Based on the data obtained from non-dimension derivation, 25 variable conditions for each particle size and fluid velocity were set. Through separate calculations, the equation for bubble rise and fall was derived. By calculating the ratio of drag and buoyancy for each variable, if the drag force acting on the bubble was greater than buoyancy, the bubble falls, and bubbles are not reduced. If the buoyancy is larger than drag, the bubble rises, and the bubble is reduced. Through the analysis, the rise and fall of the bubble were confirmed, and the results were consistent with the separate numerical calculations.

• Journal of Korean Society of Forest Science
• /
• v.77 no.2
• /
• pp.178-185
• /
• 1988

This study is carried out for analyzing the factors causing several disasters occurring around beach area in order to set a plan for an afforestation which will fulfill its function as facilities for prevention of disasters and for relaxation around beach resort at Tong-ri, Pokil-my$\bar{o}$n, Wando-gun. The results are as follows : 1. The main wind direction was summer was SE. 2. The first class in the rate of frequency of the hourly average wind speed and the instantaneous wind speed in summer were 2.1-3.0m/sec (29.2%) and 1.1-2.0m/sec (30.6%) respectively. 3. The particle sizes of the dune sands was a little small (82.5% in 0.125 to 0.25mm, $D_{50}=0.178mm$). 4. The mineral composition and the chemical components were as follows : The main mineral : Quartz The accessary minerals : Calcite, Feldspars(Orthoclase), Sericite. The chemical components : $SiO_2$ ; 75.6%. $Al_2O_3$ ; 8.1%, CaO ; 7.76%, Ign. loss ; 6.8%, MgO ; 0.23%, $K_2O$ ; 0.72%, $Na_2O$ ; 0.41%, $Fe_2O_3$ ; 0.32%. 5. The threshold friction velocity equation for the diameter class of the dune sands was $y=4.191x^{0.221}$. 6. The amount of floating salt was maximum at the point of 65m away from beach line, dropped abruptly at 135m and remained almost same on its way to the inland. The equation of the amount of floating salt was $y=28.181{\times}(-0.369^x)$. 7. The amount of extracted salt(33%) in seawater in summer was the same as the one of the nearest seawater of Korea.

• Journal of Energy Engineering
• /
• v.6 no.1
• /
• pp.58-67
• /
• 1997

In this study numerical computations were performed to predict reacting flow fields of gasification processes of pulverized subbituminous coal in a cylindrical coal gasifier. To check the size effects of particles on flow fields in the gasifier, simulations were performed for five cases with four sizes of particles such as 40 $\mu\textrm{m}$, 60 $\mu\textrm{m}$, 80 $\mu\textrm{m}$ and 100 $\mu\textrm{m}$. Each case has a unique size of particles with one more case that has evenly mixed four sizes of particles. Predictions showed that the gasification which uses coals of the mixed sizes reveals more preferable gas velocity and temperature distributions than that uses coals of a unique size. Predicted gas temperature at the exit of the gasifier ranged 1,400 to 1580$^{\circ}C$, 1,480 to 1,700$^{\circ}C$, 1,600 to 1740$^{\circ}C$, 1630 to 1790$^{\circ}C$ and 1500 to 1680$^{\circ}C$ for particle sizes of 40 $\mu\textrm{m}$, 60 $\mu\textrm{m}$, 80 $\mu\textrm{m}$, 100 $\mu\textrm{m}$ and the evenly mixed four sizes, respectively.

• Analytical Science and Technology
• /
• v.15 no.3
• /
• pp.263-269
• /
• 2002

After porous filters were manufactured using cordierite powder whose mean particle size was 200 ${\mu}m$, they were loaded with catalysts such as Pt, Pd, Cu, Co, La, $V_2O_5$ by vacuum impregnation method. And we investigated the activity of catalysts used for catalytic oxidation of VOC by passing toluene through catalyst-loaded filters. The porous filters had the apparent porosity of 62%, the compressive strength of about 10 MPa and the pressure drop of 15 mmHg at the face velocity of 5 cm/sec. The loading of catalyst decreased the porosity of the filters and increased the pressure drop and the compressive strength of them. Among the catalysts, Pt had the highest activity for catalytic oxidation and could remove more than 90% of toluene at 250 $^{\circ}C$. Below 250 $^{\circ}C$, the content of Pt catalyst had an influence on the conversion of toluene but didn't show any influence above 250 $^{\circ}C$.

• Analytical Science and Technology
• /
• v.13 no.5
• /
• pp.584-591
• /
• 2000

The separation of Nd from the simulated $U_3Si/Al$ spent fuel solution with sequential two-step anion exchange separation has been studied. To prepare the simulated $U_3Si/Al$ spent nuclear fuel, unirradiated $U_3Si/Al$ whose composition consists of small $U_3Si$ particle dispersed in an Al matrix with Al cladding was dissolved with a mixture of 4 M HCl and 10 M $HNO_3$ and 8 or 15 fission product elements were added to the dissolved solution. The trace amount of silica in the solutions was removed by evaporating to dryness with HF and the U was adsorbed on the first anion exchange resin. Neodymium can be purely isolated from the fission product elements with a methanol-nitric acid eluent using the second anion exchange resin. A large excess of Al didn't influence on the elution velocity of Nd, but reduced the eluted contents of Nd, Al, Eu, Gd, Sm and Sr, A large amount of Al was removed first from the column with 3 mL of loading solution (0.8 M $HNO_3$/99.8% MeOH) before Nd elution by the eluent [0.04 M $HNO_3$-99.8% MeOH(1:9)]. The recovery of Nd was more than 94%, regardless of Al contents. Taking the 9 to 13 mL fraction of eluate was effective to purely isolate Nd.

• Journal of Environmental Impact Assessment
• /
• v.23 no.4
• /
• pp.271-284
• /
• 2014

The objectives of this research were to analyse the microhabitat of Cobitis choii which is designated as an endangered fish species (I) and national monument species in Korea (No. 454), and provide valuable information of suitable replacement habitat in the future for a conservation of the population with rapid decreases by environmental pollution. Sampling and microhabitat analysis in three streams such as Baekgok, Yugu and Gap Stream, known as one of the least habitats in Korea showed that the mean number of Cobitis choii observed was 2.6. This result indicated that the richness was too low, so the species conservation was very urgent. Optimal physical microhabitat of the population was determined as environmental conditions with > 60% sand with 1 mm particle size, optimal water depth of 20 - 60 cm in the habitats, and the optimal current velocity of < 0.4 m/s. Under the circumstances of the microhabitat, optimal water volume (discharge) was 0 - 2 m3/s in the each sectional analysis and this reach was mainly composed of the stream section with intermittant slow runs and pools. These microhabitats were largely disturbed by physical modifications of habitat and chemical pollutions due to direct influences of nutrient-rich water inputs from the urban area and intensive agricultural pollutants. For these reasons, optimal habitat replacement are required in the future for the conservation of the species.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.24 no.5
• /
• pp.611-618
• /
• 2018

In this study, numerical analysis of solid-liquid two-phase flow was conducted as a preliminary step to analyze the flow characteristics of drilling fluid using the commercial CFD code, ANSYS CFX 14.5. The homogeneous model and separated flow model were used to simulate solid-liquid two-phase flow phenomena. In the separated flow model, Gidaspow's drag force model was applied with the kinetic theory model was applied for solid particles. The validity of the numerical model used in this study was verified based on the published experimental results. Numerical analysis was carried out for volume fractions of 0.1 to 0.5 and velocities of 1 to 5 m/s in a horizontal tube with a diameter of 54.9 mm and a length of 3 m. The Pressure drop and volume fraction distribution of solid particles were confirmed. The pressure drop was predicted using the homogeneous model and separated flow model within the MAE of 17.04 % and 8.98 %, respectively. A high volume fraction was observed in the lower part of the tube, and the volume fraction decreased toward the upper part. As velocity increased, variations in volume fraction distribution at varying heights were decreased, and the numerical results predicted these flow characteristics well.