• Title/Summary/Keyword: Particle diameter distribution

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Formation of TiO(OH)$_2$ Ultrafine Particles by Reverse Micelle (역마이셀에 의한 TiO(OH)$_2$ 미세분말 제조)

  • 장화익;강석원;이광래
    • Journal of the Korean Ceramic Society
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    • v.35 no.6
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    • pp.594-602
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    • 1998
  • Titanium hydroxide (TiO({{{{ {OH }_{2 } }})) fine particles were produced by the reverse micelle technique. For the formation of titanium hydroxide (TiO({{{{ {OH }_{2 } }})) particles with the technique reversed micellar solution was prepared by solubilizing water into organic solvent (isooctane) with a surfactant and titanium alkoxide (tetraisopropyl orthotitanate) diluted with isopropyl alcohol was added to the reversed micellar solution. The hdrolyzed species (TiO({{{{ {OH }_{2 } }})) was formed by the hydrolysis of titanium alkoxide and titanium dioxide is then formed by the condensation of the hydrolyzed species. There are several process variables such as surfactants concentration of surface cosurfactant hydrolysis temperature and pH. In this work the ef-fects of process variables on paticle shapes particle size distribution and paticle agglomeration were bi-nodal for an anionic surfactant(AOT) in the whole range of temperature pH and surfactant concentration of this experiment. The addition of ethanol as a cosurfactant resulted in narrow particle size distribution of the experiment. The additiono of ethanol as a cosurfactant resulted in narrow particle size distribution and 0.12${\mu}{\textrm}{m}$ of smaller average particle diameter. FT-IR spectrum of particles shows the absorption peak of Ti-OH bonding and Ti-O bonding. An exothermic peak around 41$0^{\circ}C$ in TGA-DTA curve shows that crys- tallized anatase phase appears and completely transits to anatase around 45$0^{\circ}C$.

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Preparation of the Narrow-dispersed Microcapsules containing Electronic Ink : Influence of Surfactant and Stirring Rate

  • Park, Youn-Jung;Kim, Chul-Am;Suh, Kyung-Soo;Kang, Seung-Youl;Park, Soo-Min
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.914-916
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    • 2009
  • Using gelatin and acacia as wall and electronic ink as core substance, microcapsules were prepared by complex coacervation to fabricate a flexible electronic paper display. In order to obtain the microcapsules in a narrow dispersed distribution, we focus on the interfacial tension between the hydrophobic electrophoretic ink and an aqueous polyelectrolyte solution, through controlling sodium dodecyl sulphate (SDS) concentration and stirring rate. The existence of anionic surfactant of SDS not only decreases the droplet diameters, but also reduces the diameter size distribution. And, as the stirring rate is increased, the average size of microcapsule is also decreased.

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Treatment of Heavy Metal Wastewater Bed Electrode Reactor by a Fluidized 1. Distribution of Local Mass Transfer Coefficients on the Current Feeder (유동층 전극반응기를 이용한 중금속폐수의 처리에 관한 연구 1. 전류공급원에서의 국부물질전달계수의 분포)

  • 황영기;정은혁
    • Journal of Environmental Science International
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    • v.6 no.1
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    • pp.1-8
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    • 1997
  • Varing the flow velocity of solution and particle diameter, the mass transfer coefficient of the local electrode on current feeder has been measured in an empty flow reactor, an inert fluidized bed electrode reactor, and an active fluidized bed electrode reactor. It had its maximium value when the bed porosity was 0.6 to 0.65 and decreased with in- creasing the height of local electrode. The mass transfer coefficient was found to be high especially when higher particle was fluidized. Electrochemical deposition of copper dissolved in the synthesized wastewater has been performed in the active fluidized bed electrode reactor. The deduction rate was higher than 90% and the residual concentration of copper decreased to less than 5ppm.

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VALIDATION OF NUMERICAL APPROACH FOR THE SEDIMENT OF MULTI-SIZE PARTICLES IN A FLUID CONTAINER (다양한 크기를 갖는 입자들의 유체 용기 내부에서의 침전에 대한 수치적 접근방법의 검증)

  • Ji, Youngmoo;Choi, Sangmin
    • Journal of computational fluids engineering
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    • v.18 no.2
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    • pp.93-98
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    • 2013
  • In this paper, we reported the verification of numerical simulation approach for sedimentation of the multi-size particles in a container. The comparison between experimentally measured values and numerically evaluated values on settle down process of fully mixed mixture is carried out. In an attempt to represent the natural particle size distribution, various diameters of single particles are simulated and the results are compared with the outcome of the multi-size computation. When the empirical formula for mean particle size estimation is adopted to define the sediment diameter, computation and comparison are conducted.

Shear-induced Migration of Brownian Suspension in a Pressure-driven Microchannel Flow

  • Kim Y.W.;Jin S.W.;Kim S.W.;Yoo J.Y.
    • 한국가시화정보학회:학술대회논문집
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    • 2004.11a
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    • pp.84-85
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    • 2004
  • Experimental study was conducted to characterize shear-induced lateral migration of $1.0-{\mu}m-diameter$ Brownian particles flowing through a rectangular microchannel which can be used to deliver small amount of liquids, drugs, biological agents and particles in microfluidic devices. Measurements were obtained by using a mercury lamp with a light of 532-nm wavelength, an inverted epi-fluorescence microscope, and a cooled CCD camera to record particle images. Peclet number was used as a parameter to assess the lateral distribution of the particles at a fixed volume fraction of $0.1\%$. It was shown that as Pe increased, particles were moved toward the centerline of the channel, which is in good agreement with previous studies.

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The Effect of the Air Temperature and Air-assisted Pressure on the Fuel Droplet Atomization (분무 공간의 공기온도와 보조공기의 공급압력이 연료입자의 미립화에 미치는 영향)

  • Kim, Y.S.;Lee, J.S.;Yoon, S.H.;Chung, S.S.;Ha, J.Y.
    • Journal of ILASS-Korea
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    • v.3 no.4
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    • pp.16-24
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    • 1998
  • The fuel injection type, in the gasoline engines of atomization of fuel droplet and its distribution hae influenced directly on the decision of engine performance and harmful emission. In this paper, atomization characteristics of fuel spray is investigated with microscopic visualization system. Particle motion analysis system is used to measure the SMD from fuel spray of air-assisted injector by initial factors such as temperature of ambient air and air-assisted pressure. As air-assist pressure and ambientair temperature increase, the SMD is decreased, and its variation is more stable.

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A Facile Preparation of Silver Nanocolloids by Hydrogen Reduction of a Silver Alkylcarbamate Complex

  • Hong, Hyun-Ki;Gong, Myoung-Seon;Park, Chan-Kyo
    • Bulletin of the Korean Chemical Society
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    • v.30 no.11
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    • pp.2669-2674
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    • 2009
  • Controlled reduction of silver alkylcarbamate complexes with hydrogen gas was investigated as a facile synthetic method for high concentrations of silver nanocolloids in organic solvent. Polyvinylpyrrolidone (PVP) was used to stabilize the silver colloids obtained from the chemical reduction. To determine optimum conditions for preparation of the stable and controlled silver colloids with the narrowest particle size and distribution, a large number of experiments were carried out involving variations in the concentrations of the silver 2-ethylhexylcarbamate (Ag-EHCB) complex, PVP, and 2-propanol. The initial colloid had a mean particle diameter between 5$\sim$50 nm, as measured by transmission electron microscopy, and exhibited a sharp absorption band in the UV region with a maximum size near 420 nm. After treatment with a reducing agent, the colloids were characterized by ultraviolet-visible spectroscopy, X-ray diffraction, and high-resolution transmission electron microscopy.

Preparation of Nanocapsules Containing Phase Change Materials by Miniemulsion Polymerization

  • Oh, Keun Jin;Kim, Dae-Su;Lee, Jae Heung;Choi, Kil-Yeong;Lee, Changjin
    • Journal of Adhesion and Interface
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    • v.4 no.1
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    • pp.35-42
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    • 2003
  • Polystyrene nanocapsules containing octadecane as a core material were prepared by miniemulsion polymerization. The morphology and size of the nanocapsules were measured with varying the surfactant concentration, content of initiator, core/shell ratio and content of comonomer. The morphologies of the prepared nanoparticles were examined by a scanning electron microscope, a transmission electron microscope and the core material was confirmed by a differential scanning calorimeter. The particles below 70 nm in diameter were formed at a high surfactant concentration. The size of the nanoparticles was not significantly affected by the initiator content. With increasing the core/shell ratio and polar comonomer content, the particle size and its distribution were increased.

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A Characteristic Study of the Aerosol Size Distribution in Pohang Province (포항 지역 대기에서 측정된 에어로졸 입자분포 특성 연구)

  • Seo, Moon Hyeok;Chang, Hyuk Sang
    • Particle and aerosol research
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    • v.8 no.4
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    • pp.151-160
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    • 2012
  • Health effects caused by the ultrafine particles in ambient air are great concern to the public health, and the strict measuring and monitoring of the ambient aerosol are required. In this work, the characteristics of the aerosol size distribution in Pohang province are studied. Optical particle counters (Grimm APS 1108 and 1109) were used to measure the aerosol size distribution in the area. Locations near the national monitoring site located in the industrial and the residence area were selected for the measuring sites of this study, and the locations in border area between the industry and the residence were selected for the reference of the comparison. In the industry site, it is found that the concentration of aerosol particles near the size of 5 ${\mu}m$ appear characteristically and the fluctuations in concentration with respect to time are minimal. The mass concentration of the aerosol above 10 ${\mu}m$ in diameter in the industry area was found to fluctuate significantly. The mass portion of $PM_{10}$ and PM2.5 to TSP in the residence area were 83% and 51% respectively. In the industrial regional, it was found that the mass portion of PM10 and $PM_{2.5}$ to TSP were 76% and 35% respectively. In the boundary area the mass portion of $PM_{10}$ and $PM_{2.5}$ to TSP were 78% and 54% respectively.

A Study on the Characterization of Size Distributions and Atmospheric Dry Deposition of Heavy Metals (대기중 중금속 입자의 입경분포 및 건식침적 특성에 관한 연구)

  • Yi, Seung-Muk;Lee, Eun-Young;Cheong, Jang-Pyo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.3
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    • pp.575-585
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    • 2000
  • Mass and elemental dry deposition fluxes and ambient particle size distributions were measured using dry deposition plates, a cascade impactor. and a CPS(Coarse Particle Sampler), from July to November 1998 in Seoul. Korea. Primarily anthropogenic elemental fluxes (Cu, Mn, Ni, Pb, Zn) were on average one to two orders of magnitude lower than primarily crustal elements (Al, Ca). Complete total and elemental particle size distributions showed trimodal size distributions due to the peak in particles larger than $10{\mu}m$ in diameter. A multi-step model and the Sehmel-Hodgson model were used to calculate total and cumulative deposition fluxes. The result indicated that dry deposition fluxes were extremely sensitive to the mass of particles larger than $10{\mu}m$ in diameter due to their high dry deposition velocities. The result showed that particles larger than $10{\mu}m$ in diameter dominated atmospheric dry deposition. The modeled fluxes calculated using the measured atmospheric particle size distributions and modeled deposition velocities were compared to measured ones. In general, the measured mass and elemental fluxes agreed well with the modeled ones.

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