• Title/Summary/Keyword: Particle assembly

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Study on the Floating and Sinking of Insects Living on Water (물 위에 사는 곤충의 부양과 가라앉음에 관한 연구)

  • Lee Duck-Gyu;Kim Ho-Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.10 s.253
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    • pp.982-986
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    • 2006
  • It is well known that the surface tension forces can make a particle denser than water float when the size of the particle is of the order of 1 mm. This is deeply related to the basic mechanism enabling small insects to wander around on the pond surface and also to a newly emerging technology of self-assembly using capillary forces. For the quantitative understanding of this effect, we experimentally study the maximum density of a cylinder that can float on water and how fast the cylinder sinks when the density exceeds the maximum value. We compare our experimental results with the theoretical prediction and find good agreement between them.

Magnetic Behaviors of Isolated Fe-Co-Ni Nanoparticles in a Random Arrangement

  • Yang, Choong Jin;Kim, Kyung Soo;Wu, Jianmin
    • Journal of Magnetics
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    • v.6 no.3
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    • pp.94-100
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    • 2001
  • Fe-Co-Ni particles with an average size of 45 and 135 nm are characterized in terms of magnetic phase transformation and magnetic properties at room temperature. BCC structure of Fe-Co-Ni spherical particles can be synthesized from Fe-Co-Ni-Al-Cu precursor films by heating at 600-80$0^{\circ}C$ for the phase separation of Fe-Co rich Fe-Co-Ni particles, followed by a post heating at $600^{\circ}C$ for 5 hours. The average size of nanoparticles was directly determined by the thickness of precursor films. Exchange interactive hysteresis was observed for the nano-composite (Fe-Co-Ni)+(Fe-Ni-Al) films resulting from the short exchange interface between ferromagnetic Fe-Co-Ni particles surrounded by almost papramagnetic Ni-Al-Fe matrix. Arraying the isolated Fe-Co-Ni nano-particles in a random arrangement on $Al_2O_3$substrate the particle assembly showed a behavior of dipole interactive ferromagnetic clusters depending on their volume and inter-particle distance.

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Influence of the Syndiotacticity of Poly(vinyl alcohol) block on the formation of micelles for Poly(vinyl alcohol-b-styrene) (Poly(vinyl alcohol) block의 신디오탁틱이 Poly(vinyl alcohol-b-styrene)의 micelle형성에 미치는 영향)

  • 이광화;조창기
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.291-292
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    • 2003
  • Amphiphilic block copolymer는 self-assembly특성을 가지고 있기 때문에 선택된 용매 속에서 nanoscale-domain 즉 micelle을 형성할 수 있다. 이러한 특성은 기타 불용성 물질을 가용화하고 colloidal particle을 안정화시키거나 micro-emulsion을 형성할 수 있어 pharmaceutics, drug delivery system등 영역, 그리고 emulsion stabilizer, thickener, dispersion agent등으로 사용될 수 있다. (중략)

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Preparation of graphene-$TiO_2$ composite by aerosol process and it's characterization for dye-sensitized solar cell (에어로졸 공정에 의한 Graphene-$TiO_2$ 복합체 제조 및 염료감응 태양전지 특성평가)

  • Jo, Eun Hee;Kim, Sun Kyung;Jang, Hee Dong;Chang, Hankwon;Roh, Ki-Min;Kim, Tae-Oh
    • Particle and aerosol research
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    • v.9 no.2
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    • pp.51-57
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    • 2013
  • A graphene(GR)-$TiO_2$ composite was synthesized from colloidal mixture of graphene oxide(GO) nanosheets and $TiO_2$ nanoparticles by an aerosol assisted self-assembly. The morphology, specific surface area and pore size of asprepared GR-$TiO_2$ composite were characterized by FE-SEM, BET, and BJH respectively. The shape of GR-$TiO_2$ composite was spherical. The average particle size was 0.5-1 ${\mu}m$ in diameter and the pore diameter ranged 20-50 nm. Photovoltaic characteristics of a mixture of the GR-$TiO_2$ and $TiO_2$ nanoparticles were measured by a solar simulator under simulated solar light. The highest photoelectric conversion efficiency of the mixture photoanode was 5.1%, which was higher than that of $TiO_2$ photoanode.

On the Particle Swarm Optimization of cask shielding design for a prototype Sodium-cooled Fast Reactor

  • Lim, Dong-Won;Lee, Cheol-Woo;Lim, Jae-Yong;Hartanto, Donny
    • Nuclear Engineering and Technology
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    • v.51 no.1
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    • pp.284-292
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    • 2019
  • For the continuous operation of a nuclear reactor, burnt fuel needs to be replaced with fresh fuel, where appropriate (ex-vessel) fuel handling is required. Particularly for the Sodium-cooled Fast Reactor (SFR) refueling, its process has unique challenges due to liquid sodium coolant. The ex-vessel spent fuel transportation should concern several design features such as the radiation shielding, decay-heat removal, and inert space separated from air. This paper proposes a new design optimization methodology of cask shielding to transport the spent fuel assembly in a prototype SFR for the first time. The Particle Swarm Optimization (PSO) algorithm had been applied to design trade-offs between shielding and cask weight. The cask is designed as a double-cylinder structure to block an inert sodium region from the air-cooling space. The PSO process yielded the optimum shielding thickness of 26 cm, considering the weight as well. To confirm the shielding performance, the radiation dose of spent fuel removed at its peak burnup and after 1-year cooling was calculated. Two different fuel positions located during transportation were also investigated to consider a functional disorder in a cask drive system. This study concludes the current cask design in normal operations is satisfactory in accordance with regulatory rules.

Blast Modeling of Concrete Column Using PFC (PFC를 이용한 콘크리트기둥의 발파모델링)

  • Choi Byung-Hee;Yang Hyung-Sik;Ryu Chang-Ha
    • Explosives and Blasting
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    • v.23 no.1
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    • pp.47-54
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    • 2005
  • An explosion modeling technique was developed by using the spherical discrete element code, $PFC^{3D}$, which can be used to model the dynamic stress wave propagation phenomenon. The modeling technique is simply based on an idea that the explosion pressure should be applied to a $PFC^{3D}$ particle assembly not in the form of an external force (body force), but in the form of a contact force (surface force). A test blast was conducted for a RC column, whose dimension was $600\times300\times1800$ in millimeters. The initial velocities of the surface movements were measured to be in the range of $14\~18\;m/s$ with the initiation times of $1.5\~2.0m$. Then the blasting procedure was simulated by using the modeling technique. The particle assembly representing the concrete was made of cement mortar and coarse aggregates, whose mirco-properties were obtained from the calibration processes. As a result, the modeling technique developed in this study made it possible for the burden to move with the velocity of $17\~24\;m/s$, which are slightly higher values compared to those of the test blast.

Dispersion and Shape Control on Nanoparticles of Gd2O3:Eu3+ Red Phosphor Prepared by Template Method (주형법으로 제조된 Gd2O3:Eu3+ 적색 형광체의 나노입자 분산 및 형상제어)

  • Park, Jeong Min;Ban, Se Min;Jung, Kyeong-Youl;Choi, Byung-Ki;Kang, Kwang-Jung;Kim, Dae-Sung
    • Korean Journal of Materials Research
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    • v.27 no.10
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    • pp.534-543
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    • 2017
  • $Gd_2O_3:Eu^{3+}$ red phosphors were prepared by template method from crystalline cellulose impregnated by metal salt. The crystallite size and photoluminescence(PL) property of $Gd_2O_3:Eu^{3+}$ red phosphors were controlled by varying the calcination temperature and $Eu^{3+}$ mol ratio. The nano dispersion of $Gd_2O_3:Eu^{3+}$ was also conducted with a bead mill wet process. Dependent on the time of bead milling, $Gd_2O_3:Eu^{3+}$ nanosol of around 100 nm (median particle size : $D_{50}$) was produced. As the bead milling process proceeded, the luminescent efficiency decreased due to the low crystallinity of the $Gd_2O_3:Eu^{3+}$ nanoparticles. In spite of the low PL property of $Gd_2O_3:Eu^{3+}$ nanosol, it was observed that the photoluminescent property was recovered after re-calcination. In addition, in the dispersed nanosol treated at $85^{\circ}C$, a self assembly phenomenon between particles appeared, and the particles changed from spherical to rod-shaped. These results indicate that particle growth occurs due to mutual assembly of $Gd(OH)_3$ particles, which is the hydration of $Gd_2O_3$ particles, in aqueous solvent at $85^{\circ}C$.

Effect of MEA fabrication on the performance degradation of DMFC (MEA 제조 방법에 따른 직접 메탄올 연료전지의 성능저하 현상 평가)

  • Cho, Yoon-Hwan;Cho, Yong-Hun;Park, Hyun-Seo;Won, Ho-Youn;Sung, Yung-Eun
    • New & Renewable Energy
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    • v.3 no.1 s.9
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    • pp.60-67
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    • 2007
  • Catalyst coated membrane [CCM] type and catalyst coated substrate [CCS] type of membrane electrode assembly [MEA] were manufactured and evaluated their performance. Degradation test were conducted to find the difference of long term stability in two types of MEA and the factor for performance degradation problem occurred. Performance degradation test of single cell in two different types of MEA were carried out when current density was $200mA/cm^{2}$. The degradation test had proceeded for 230 hours and performance degradation was checked by I-V curve and impedance measurement at regular intervals. Also, MEA before/after operation and changes of catalyst layer were characterized by SEM, TEM, and XRD. Maximum power density of CCM type was higher than that of CCS type. Meanwhile, an increase of particle size of catalyst and an increase of impedance resistance after long term operation were observed. In the case of using CCM type MEA, the performance was deteriorated 38% of initial performance. In the case of using CCS type MEA, the performance was deteriorated 43% of initial performance. In consideration of difference of initial performance, performance of CCM type is higher than that of CCS type but both types had similar problems during degradation test.

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Improving the Neutronic Characteristics of a Boiling Water Reactor by Using Uranium Zirconium Hydride Fuel Instead of Uranium Dioxide Fuel

  • Galahom, Ahmed Abdelghafar
    • Nuclear Engineering and Technology
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    • v.48 no.3
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    • pp.751-757
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    • 2016
  • The present work discusses two different models of boiling water reactor (BWR) bundle to compare the neutronic characteristics of uranium dioxide ($UO_2$) and uranium zirconium hydride ($UZrH_{1.6}$) fuel. Each bundle consists of four assemblies. The BWR assembly fueled with $UO_2$ contains $8{\times}8$ fuel rods while that fueled with $UZrH_{1.6}$ contains $9{\times}9$ fuel rods. The Monte Carlo N-Particle Transport code, based on the Mont Carlo method, is used to design three dimensional models for BWR fuel bundles at typical operating temperatures and pressure conditions. These models are used to determine the multiplication factor, pin-by-pin power distribution, axial power distribution, thermal neutron flux distribution, and axial thermal neutron flux. The moderator and coolant (water) are permitted to boil within the BWR core forming steam bubbles, so it is important to calculate the reactivity effect of voiding at different values. It is found that the hydride fuel bundle design can be simplified by eliminating water rods and replacing the control blade with control rods. $UZrH_{1.6}$ fuel improves the performance of the BWR in different ways such as increasing the energy extracted per fuel assembly, reducing the uranium ore, and reducing the plutonium accumulated in the BWR through burnup.