• 산업기술연구
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• 제21권B호
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• pp.149-153
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• 2001

A study on the particle growth in $TEOS/O_2$ plasma was performed, and particle size and its distribution was measured by the electrical aerosol analyzer (EAA), light scattering particle size analyzer and the particle size was also determined by SEM. The effects of process variables such as total gas flow rate, reactor pressure, supplied power and initial reactant concentration on the particle growth were investigated. From the EAA results, the particle size distribution is divided into three groups of the cluster size and the small and large size particles. The particle size distribution measured by the light scattering particle size analyzer becomes bimodal, because the cluster size particles smaller than 20 nm in diameter cannot be detected by the light scattering particle size analyzer. The size of particles measured by the light scattering particle size analyzer is in good agreements with those by the SEM. Also we could understand that the particle formation is very sensitive to the changes of reactor pressure and reactant concentration. As the total gas flow rate increases, the particle size decreases because of the shorter residence time. As the reactor pressure, or the reactant concentration increases, the particle concentration increases and the particles grow more quickly by the faster coagulation between particles.

• 산업기술연구
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• 제6권
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• pp.19-31
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• 1986

The residence time distribution of liquid flow in a 4.0cm diameter column packed with porous $Al_2O_3$ spheres of 0.37cm diameter were measured with pulse injections of a tracer under cocurrent trickling flow conditions. The mean residence time of liquid flow and liquid hold-up calculated by the transient curve of tracer were unaffected by gas flow rates under experimental ranges of liquid flow rates from 2.4 to $4.5(kg/m^2\;sec)$ and gas flow rates from 0 to $0.13(kg/m^2\;sec)$. The axial dispersion coefficient of liquid stream and apparent diffusivity of tracer in a micropore of solid particle were estimated from the response curve of tracer. The calculated Peclet No. were increased in ranges of 68-to 82 with a increasing of liquid mass velocity, and the external effective contacting efficiency between liquid and solid which can be expressed. by $(D_i)_{app}/D_i$ varied in ranges of 0.54 to 0.68 depending on the liquid flow rates. The gas to liquid(water) volumetric mass transfer coefficient were determined from desorption experiments with oxygen at $25^{\circ}C$ and 1 atm. The measured mass transfer coefficients were increased with liquid flow rates and the effect of gas flow rates on the mass transfer coefficient was insignificant.

• Korean Chemical Engineering Research
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• 제47권5호
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• pp.572-579
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• 2009

본 연구에서는 분진폭발에 있어서 기초적 현상을 규명하고 분진의 화염구조와 메커니즘에 대하여 실험적으로 조사하였다. 실험장치는 길이 1.8 m, 단면이 0.15 m의 정방형인 수직연소관을 사용하였으며, 덕트 내를 전파하는 상방 분진층류화염과 화염면에 대하여 고속카메라를 사용하여 가시화하였다. 또한 슐리렌, 이온프로브, 열전대 등을 사용하여 예열대 및 반응대의 두께를 측정하였다. 석송자 분진화염의 예열대 두께는 4~13 mm로 탄화수소가스의 예혼합기 화염보다도 수배 크다. 입자화상유속법(PIV)에 의한 해석 결과, 예열대에서의 미연소 입자의 체류 시간은 입자의 열분해가스 생성에 필요하며, 체류시간은 화염전파속도, 입자속도 및 예열대 두께에 의존하는 것을 알았다.

• 한국입자에어로졸학회지
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• 제8권4호
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• pp.151-160
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• 2012

Health effects caused by the ultrafine particles in ambient air are great concern to the public health, and the strict measuring and monitoring of the ambient aerosol are required. In this work, the characteristics of the aerosol size distribution in Pohang province are studied. Optical particle counters (Grimm APS 1108 and 1109) were used to measure the aerosol size distribution in the area. Locations near the national monitoring site located in the industrial and the residence area were selected for the measuring sites of this study, and the locations in border area between the industry and the residence were selected for the reference of the comparison. In the industry site, it is found that the concentration of aerosol particles near the size of 5 ${\mu}m$ appear characteristically and the fluctuations in concentration with respect to time are minimal. The mass concentration of the aerosol above 10 ${\mu}m$ in diameter in the industry area was found to fluctuate significantly. The mass portion of $PM_{10}$ and PM2.5 to TSP in the residence area were 83% and 51% respectively. In the industrial regional, it was found that the mass portion of PM10 and $PM_{2.5}$ to TSP were 76% and 35% respectively. In the boundary area the mass portion of $PM_{10}$ and $PM_{2.5}$ to TSP were 78% and 54% respectively.

• 대한기계학회논문집
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• 제19권9호
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• pp.2342-2352
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• 1995

Deposition of flame-synthesized silica particles onto a target is utilized in optical fiber preform fabrication processes. The particles are convected and deposited onto the target. Falkner-Skan wedge flow was chosen as the particle laden flow. Typically the particles are polydisperse in size and follow a lognormal size distribution. Brownian diffusion, thermophoresis, and coagulation of the particles were considered and effects of these phenomena on particle deposition were studied. A moment model was developed in order to predict the particle number density and the particle size distribution simultaneously. Particle deposition with various wedge configurations was examined for conditions selected for a typical VAD process. When coagulation was considered, mean particle size and its standard deviation increased and particle number density decreased, compared to the case without coagulation. These results proved the fact that coagulation effect expands particle size distribution. The results were discussed with characteristics of thermal and diffusion boundary layers. As the boundary layers grow in thickness, overall temperature and concentration gradients decrease, resulting in decrease of deposition rate and increase of particle residence time in the flow and thus coagulation effect.

• 한국재료학회지
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• 제13권5호
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• pp.328-332
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• 2003

Characteristics of $TiO_2$nanoparticles controlled by precursor flow rate and reaction temperature in chemical vapor condensation process were interpreted in the view of decisive reaction factors, i.e. supersaturation ratio, concentration of vapor molecule, collision frequency and rate, and residence time, which directly affect the particle size and size distribution in CVC reactor. As results, the increases of precursor flow rate and reaction temperature induced the increase in the average sizes of $TiO_2$ nanoparticles in CVC reactor by acceleration of coagulation growth due to the increase of collision between $TiO_2$vapor molecules and particles. The effects of reaction factors on the characteristics of$TiO_2$nanoparticles were discussed with considering particle formation process in CVC reactor under given process parameters.

• Bulletin of the Korean Chemical Society
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• 제30권7호
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• pp.1505-1515
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• 2009

A new method to semicontinuously determine $PM_{2.5}$ ionic species with a short time resolution is described in detail. In this system, a particle collection section (mixing part, particle collection chamber, and air/liquid separator) was developed. A Y-type connector was used to mix steam and an air sample. The particle collection chamber was constructed in the form of a helix coil and was cooled by a water circulation system. Particle size growth occurred due to the high relative humidity and water absorbed particles were efficiently collected in it. Liquid samples were drained out with a short residence time (0.08-0.1 s). The air/liquid separator was also newly designed to operate efficiently when the flow rate of the air sample was 16.7 L $min^{-1}$. For better performance, the system was optimized for particle collection efficiency with various types of test aerosols such as ($NH_4)_2SO_4,\;NaCl,\;NH_4HSO_4,\;and\;NH_4NO_3$. The particle collection efficiencies were almost 100% at different concentration levels in the range over 500 nm in diameter but 50-90% in the range of 50-500 nm under the following experimental conditions: 15 coil turns, a water flow rate for steam generation of 0.65 mL $min^{-1}$, and an air sample flow rate of 16.7 L $min^{-1}$. Finally, for atmospheric applications, chemical compositions of $PM_{2.5}$ were determined with a time resolution of 20 min on January 11-24, 2006 in Seoul, Korea, and the chemical characteristics of $PM_{2.5}$ ions were investigated.

• 한국입자에어로졸학회지
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• 제11권2호
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• pp.29-36
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• 2015

The purpose of this research is to find out the collection property of nanoparticle in diffusion filter to know particle size dispersion of nanomaterial using inertial force and principle of Brownian diffusion motion. We used inertial filters which are two different type and diffusion filters made by various kinds of Wiremesh and the different pieces of filter to compare with particle size distribution using NaCl particles. Finally, We made a conclusion as follows : (1) the bigger available charging volume is and the larger specific surface area of inertial filter is, the better collection efficiency is. (2) The higher wire-mesh number of filter is, the more collection efficiency of small particle is increasing because the wire of the higher Wiremesh number filter is thinner and denser. (3) The more pieces of wire-mesh filter, the more collection efficiency is increasing because it makes the residence time longer.

• 공업화학
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• 제8권6호
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• pp.901-906
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• 1997

유기금속화합물인 Tetraethylorthosilicate(TEOS)를 출발원료로 기상열분해법을 이용하여 초미립 실리카분말을 제조하였다. 반응온도, 가스유량, 반응물질의 농도, 및 반응물질의 예비가열온도가 초미립 실리카분말의 입자크기 특성에 미치는 영향을 조사하였다. 반응온도가 증가할수록 또한 체류시간이 감소할수록 생성분말의 입자크기가 작아지는 것을 알 수 있었다. 반응물농도가 증가할수록 입자크기가 증가하였고, 또한 반응물질의 예비가열온도가 증가하여도 입자크기는 큰 변화가 없음을 알 수 있었다. 본 연구조건에서 제조된 초미립 실리카분말의 평균 입자크기는 30~58 nm이었다.

• 수산해양교육연구
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• 제28권4호
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• pp.1143-1151
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• 2016

To study the dispersion process and residence time of anthropogenic pollutant in Masan bay, a three-dimensional hydrodynamic model coupled to a particle tracking model, EFDC, is applied. Particle tracking model simulated the instantaneous release of particles emulating discharge from river and wastewater treatment plant to show the behaviour of pollutant in terms of water circulation and water exchange. Modelled outcomes for water circulation were in good agreement with tidal elevation and current data. The results of particle tracking model show that over half of particles released from northern Masan bay transport to out of area while the particles from Dukdong wastewater treatment plant transport to northern area. This meant pollution source from inside and outside of the northern area can affect water quality of northern Masan bay.