• Title/Summary/Keyword: Partial Substitution

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Lanthanum Nickelates with a Perovskite Structure as Protective Coatings on Metallic Interconnects for Solid Oxide Fuel Cells

  • Waluyo, Nurhadi S.;Park, Beom-Kyeong;Song, Rak-Hyun;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Lee, Jong-Won
    • Journal of the Korean Ceramic Society
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    • v.52 no.5
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    • pp.344-349
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    • 2015
  • An interconnect is the key component of solid oxide fuel cells that electrically connects unit cells and separates fuel from oxidant in the adjoining cells. To improve their surface stability in high-temperature oxidizing environments, metallic interconnects are usually coated with conductive oxides. In this study, lanthanum nickelates ($LaNiO_3$) with a perovskite structure are synthesized and applied as protective coatings on a metallic interconnect (Crofer 22 APU). The partial substitution of Co, Cu, and Fe for Ni improves electrical conductivity as well as thermal expansion match with the Crofer interconnect. The protective perovskite layers are fabricated on the interconnects by a slurry coating process combined with optimized heat-treatment. The perovskite-coated interconnects show area-specific resistances as low as $16.5-37.5m{\Omega}{\cdot}cm^2$ at $800^{\circ}C$.

Piezoelectric properties of Pb(Sb,Mn) $O_3$- Pb(Zr,Ti) $O_3$ Ceramics doped L $u_2$ $O_3$ (L $u_2$ $O_3$ 치환에 따른 Pb(Sb,Mn) $O_3$-Pb(Zr,Ti) $O_3$ 세라믹스의 압전특성)

  • ;;Sergey Kucheiko
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.60-63
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    • 1997
  • Dieletric ailed piezoelectric properties of Pb[$Zr_{0.45}$/ $Ti_{0.5-x}$/L $u_{x}$ (M $n_{1}$3//S $b_{2}$3)$_{0.05}$] $O_3$(0$\leq$x $\leq$0.03) were investigated. The partial substitution of $Ti^{4+}$ by a L $u^{3+}$ permitted improvement of the piezoelectric constant( $d_{33}$ ), electromechanical coupling factor ( $k_{p}$ ) and dielectric constant($\varepsilon$$_{33}$ /Sup T/). The dielectric loss(tan $\delta$ ) increased and mechanical quality factor(Qm) decreased with an increase of x were observed. A new piezoelectric material for actuator application was developed at x=0.02 with $d_{33}$ =370$\times$10$^{-2}$ /C/N, $k_{p}$ =58.5%, $\varepsilon$$_{33}$ $^{T}$ =1321, $Q_{m}$ =714 and tan $\delta$ =0.98%.%..%.%.

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Influence of Blast Furnace Slag Addition on the Strength of Cold Bonded Pellet (고로 급냉슬래그를 첨가한 비소성 펠릿의 강도거동)

  • 피용진;반봉찬;김태동
    • Resources Recycling
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    • v.8 no.1
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    • pp.29-36
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    • 1999
  • Utilization of iron bearing dusts has been needed agglomeration prior to use as a burden in blast furnace The cold bonded pellet process using iron bearing dusts has been developed as an alternative to the conventional heat indurated pelletizing process. Partial substitution of cements with cheaper materials would decrease the production cost of pellet. This paper discusses the strength of pellet containing blast furnace slag as a bonding material in pelletizing a cold bonded agglomerates. Depending upon the quality, half of the cement required may be replaced by slag in the pellets with a strength of around 150 kgf. Some of the physicochemical properties of the bonding materials are also investigated in the present work.

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Kinetics and Mechanisms of the Oxidation of Carbon Monoxide on $Eu_{1-x}Sr_xCoO_{3-y}$ Perovskite Catalysts

  • Dong Hoon Lee;Joon Ho Jang;Hong Seok Kim;Yoo Young Kim;Jae Shi Choi;Keu Hong Kim
    • Bulletin of the Korean Chemical Society
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    • v.13 no.5
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    • pp.511-516
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    • 1992
  • The catalytic oxidation of CO on perovskite $Eu_{1-x}Sr_xCoO_{3-y}$, has been investigated at reaction temperatures from 100 to $250^{\circ}C$ under stoichiometric CO and $O_2$ partial pressures. The microstructure and Sr-substitution site of the catalyst were studied by means of infrared spectroscopy. The reaction rates were found to be correlated with 1.5-and 1.0-order kinetics with and without a $CO_2$ trap, respectively; first-and 0.5-order with respect to CO and 0.5-order to $O_2$ with the activation energy of 0.37 eV $mol^{-1}$. It was found from IR, ${\sigma}$ and kinetic data that $O_2$ adsorbs as an ionic species on the oxygen vacancies, while CO adsorbs on the lattice oxygens. The oxidation reaction mechanism is suggested from the agreement between IR, ${\sigma}$ and kinetic data.

Flapwise and non-local bending vibration of the rotating beams

  • Mohammadnejad, Mehrdad;Saffari, Hamed
    • Structural Engineering and Mechanics
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    • v.72 no.2
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    • pp.229-244
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    • 2019
  • Weak form integral equations are developed to investigate the flapwise bending vibration of the rotating beams. Rayleigh and Eringen nonlocal elasticity theories are used to investigate the rotatory inertia and Size-dependency effects on the flapwise bending vibration of the rotating cantilever beams, respectively. Through repetitive integrations, the governing partial differential equations are converted into weak form integral equations. The novelty of the presented approach is the approximation of the mode shape function by a power series which converts the equations into solvable one. Substitution of the power series into weak form integral equations results in a system of linear algebraic equations. The natural frequencies are determined by calculation of the non-trivial solution for resulting system of equations. Accuracy of the proposed method is verified through several numerical examples, in which the influence of the geometry properties, rotatory inertia, rotational speed, taper ratio and size-dependency are investigated on the natural frequencies of the rotating beam. Application of the weak form integral equations has made the solution simpler and shorter in the mathematical process. Presented relations can be used to obtain a close-form solution for quick calculation of the first five natural frequencies of the beams with flapwise vibration and non-local effects. The analysis results are compared with those obtained from other available published references.

Strength properties of concrete with fly ash and silica fume as cement replacing materials for pavement construction

  • Chore, Hemant Sharad;Joshi, Mrunal Prashant
    • Advances in concrete construction
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    • v.12 no.5
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    • pp.419-427
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    • 2021
  • The overuse level of cement for civil industry has several undesirable social and ecological consequences. Substitution of cement with industrial wastes, called by-products, such as fly ash, ground granulated blast furnace slag, silica fume, metakaoline, rice husk ash, etc. as the mineral admixtures offers various advantages such as technical, economical and environmental which are very important in the era of sustainability in construction industry. The paper presents the experimental investigations for assessing the mechanical properties of the concrete made using the Pozzolanic waste materials (supplementary cementitious materials) such as fly ash and silica fume as the cement replacing materials. These materials were used in eight trial mixes with varying amount of ordinary Portland cement. These SCMs were kept in equal proportions in all the eight trial mixes. The chemical admixture (High Range Water Reducing Admixture) was also added to improve the workability of concrete. The compressive strengths for 7, 28, 40 and 90 days curing were evaluated whereas the flexural and tensile strengths corresponding to 7, 28 and 40 days curing were evaluated. The study corroborates that the Pozzolanic materials used in the present investigation as partial replacement for cement can render the sustainable concrete which can be used in the rigid pavement construction.

Substitution of Fish Meal by Mealworm (Tenebrio molitor) in Practical Diets for Pacific White Shrimp, Litopenaeus vannamei

  • Jeong, Tae-Ho;Kim, Nam-Jeong;Park, Cheol;Kim, Ju-Min
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2019.10a
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    • pp.202-202
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    • 2019
  • Mealworm (Tenebrio molitor) was evaluated to investigate the effect of partial or total replacement of fish meal in diets for white shrimp, Litopenaeus vannamei. Experimental groups of shrimp with average initial body weight (2.43 ± 0.54 g) were fed each with 4 isonitrogeneous (38% crude protein) diets formulated to include 0, 25, 50 and 100% (diets 1 to 4, respectively) of fish meal substituted with mealworm. After eight weeks of feeding trials, shrimp fed with diet 3 and 4 revealed the highest values for live weight gain(8.01 ± 2.51 and 7.93 ± 1.12), specific growth rates (2.70 ± 1.12 and 2.59 ± 0.51) as well as better feed conversion ratio (2.69 ± 0.09 and 2.72 ± 0.19) compared to the control group with statistically significant manner (p<0.05). Survival range was 98% in all the treatments. An increase in weight gain and other growth associated parameters was observed with higher replacement. These results clearly indicate that 50% and 100% of fish meal protein in shrimp diet can be replaced by mealworm not only without any adverse effect but also the effect of promoting growth performance.

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Partial Interferon-γ Receptor Deficiency in Patients with Disseminated Tuberculosis (파종성 결핵 환자에서 interferon-γ 수용체의 부분결핍에 관한 연구)

  • Hwang, Jung Hye;Koh, Won-Jung;Lee, Shin Hye;Kim, Eun Joo;Kang, Eun Hae;Suh, Gee Young;Chung, Man Pyo;Kim, Hojoong;Kwon, O Jung
    • Tuberculosis and Respiratory Diseases
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    • v.58 no.1
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    • pp.11-17
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    • 2005
  • Background : Interferon-gamma ($IFN-{\gamma}$) is essential in the immune response to mycobacterial infections, and a complete or partial deficiency in the $IFN-{\gamma}$ receptor 1 ($IFN{\gamma}R1$) or the $IFN-{\gamma}$ receptor 2 ($IFN{\gamma}R2$) have been reported to confer susceptibility to a disseminated infection with nontuberculous mycobacteria. However, similar mutations in the $IFN-{\gamma}$ receptor have not been specifically examined in the patients with clinical tuberculosis. Methods : This study searched for mutations in the $IFN-{\gamma}$ receptor gene that resulted in a partial $IFN-{\gamma}$ receptor deficiency in six patients with disseminated tuberculosis. The previously identified $IFN{\gamma}R1$ and $IFN{\gamma}R2$ coding regions were sequenced after amplification. Results : There was no partial $IFN{\gamma}R1$ deficiency including a homozygous recessive missense mutation causing an amino-acid substitution in the extracellular domain of the receptor (I87T) and a hotspot for small deletions (818delT, 818del4, 818insA) found in any of the patients. In addition, a partial $IFN{\gamma}R2$ deficiency of the homozygous missense mutation (R114C) was not found in any of the patients. Conclusion : Genetic defects causing a partial $IFN-{\gamma}$ receptor deficiency were not identified in our patients with disseminated tuberculosis.

Synthesis and Photoluminescence Properties of Red-Emitting (Y,Al)VO4:Eu3+ Nanophosphors (적색 발광 (Y,Al)VO4:Eu3+ 형광체 나노입자의 합성과 발광 특성)

  • Seo, Jung-Hyun;Choi, Sung-Ho;Nahm, Sahn;Jung, Ha-Kyun
    • Korean Journal of Materials Research
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    • v.22 no.2
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    • pp.103-109
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    • 2012
  • Red-emitting $Eu^{3+}$-activated $(Y_{0.95-x}Al_x)VO_4$ (0 < x $\leq$ 0.12) nanophosphors with the particle size of ~30 nm and the high crystallinity have been successfully synthesized by a hydrothermal reaction. In the synthetic process, deionized water as a solvent and ethylene glycol as a capping agent were used. The crystalline phase, particle morphology, and the photoluminescence properties of the excitation spectrum, emission intensity, color coordinates and decay time, of the prepared $(Y_{0.95-x}Al_x)VO_4:Eu^{3+}$ nanophosphors were compared with those of the $YVO_4:Eu^{3+}$. Under 147 nm excitation, $(Y_{0.95-x}Al_x)VO_4$ nanophosphors showed strong red luminescence due to the $^5D_0-^7F_2$ transition of $Eu^{3+}$ at 619 nm. The luminescence intensity of $YVO_4:Eu^{3+}$ enhanced with partial substitution of $Al^{3+}$ for $Y^{3+}$ and the maximum emission intensity was accomplished at the $Al^{3+}$ content of 10 mol%. By the addition of $Al^{3+}$, decay time of the $(Y,Al)VO_4:Eu^{3+}$ nanophosphor was decreased in comparison with that of the $YVO_4:Eu^{3+}$ nanophosphor. Also, the substitution of $Al^{3+}$ for $Y^{3+}$ invited the improvement of color coordinates due to the increase of R/O ratio in emission intensity. For the formation of transparent layer, the red nanophosphors were fabricated to the paste with ethyl celluloses, anhydrous terpineol, ethanol and deionized water. By screen printing method, a transparent red phosphor layer was formed onto a glass substrate from the paste. The transparent red phosphor layer exhibited the red emission at 619 nm under 147 nm excitation and the transmittance of ~80% at 600 nm.

Effect of Partial Replacement of Wheat Flour with High Quality Cassava Flour on the Chemical Composition, Antioxidant Activity, Sensory Quality, and Microbial Quality of Bread

  • Eleazu, Chinedum;Eleazu, Kate;Aniedu, Chinyere;Amajor, John;Ikpeama, Ahamefula;Ebenzer, Ike
    • Preventive Nutrition and Food Science
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    • v.19 no.2
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    • pp.115-123
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    • 2014
  • In the current study, wheat flour was mixed with high quality cassava flour (HQCF) in several ratios: 90:10, 80:20, 70:30, and 60:40, and used to prepare 10%, 20%, 30%, and 40% National Root Crops Research Institute (NRCRI) cassava bread, respectively. 100% wheat bread was prepared as a control (100% wheat bread). Five bread samples were prepared per group. Antioxidant assays [i.e., 2,2-diphenyl-1-picrylhydrazyl radical (DPPH) scavenging assay, reducing power assay] revealed that the bread samples had considerable antioxidant capacities. Substitution of wheat flour with HQCF at various concentrations resulted in dose dependent decreases in the mineral and protein contents of the resulting bread samples. The crude fiber content of the bread samples was minimal, while the carbohydrate content of the bread samples ranged from 43.86% to 48.64%. A 20% substitution of wheat flour with HQCF yielded bread samples with a general acceptability that was comparable to that of 100% wheat bread. The mean bacteria counts of the bread samples ranged from $2.0{\times}10^3CFU/mL$ to $1.4{\times}10^4CFU/mL$, while the fungal counts ranged from 0 CFU/mL to $3{\times}10^3CFU/mL$. There was a positive correlation between the DPPH antioxidant activities and the reducing powers of the bread samples ($R^2=0.871$) and a positive correlation between the DPPH antioxidant activities and the flavonoid contents of the bread samples ($R^2=0.487$). The higher microbial load of the NRCRI cassava bread samples indicates that these bread samples may have a shorter shelf life than the 100% wheat bread. The significant positive correlation between total flavonoid content and reducing power ($R^2=0.750$) suggests that the flavonoids present in the lipophilic fractions of the bread samples could be responsible for the reductive capacities of the bread samples.