• 제목/요약/키워드: Paraffin Wax

검색결과 109건 처리시간 0.025초

생분해성 고분자를 이용한 발수 에멀션의 제조(II) - PLA 및 PBS 에멀션 코팅 과일봉지의 물성 비교 - (Preparation of Emulsion from Biodegradable Polymer(II) - Characteristics of paper treated as PLA and PBS emulsion -)

  • 김강재;이민형;엄태진
    • 펄프종이기술
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    • 제45권2호
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    • pp.13-20
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    • 2013
  • In this study, two biodegradable polymer(PLA, PBS) emulsions were treated on agricultural packaging paper such as fruit bagging paper. Water-repellency, mechanical properties, and SEM image with thermal aging were measured on the emulsion treated fruit bagging paper. Biodegradable polymers(such as poly lactic acid, poly butylene succinate) emulsion treated fruit bagging paper had higher water-repellency and strength than other water-repellent(such as acrylic repellent, linseed oil and paraffin wax) treated fruit bagging paper. According to FE-SEM results of polymer emulsion coated fruit bagging paper, the colloidal particles of emulsion after thermal treatment (looks like being) were adhered to the fibers. Thus, using biodegradable polymer emulsion is expected to protect a fruit for a long time.

수피(樹皮)보드의 새로운 제조방법(製造方法)과 그 물리기계적(物理機械的) 성질(性質)에 관(關)한 연구(硏究) (Studies on the new manufacturing process and physical, mechanical properties of barkboard)

  • 이화형
    • Journal of the Korean Wood Science and Technology
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    • 제17권4호
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    • pp.26-34
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    • 1989
  • This study was carried out to manufacture bark board from oak bark by new processes and to examine the physical and mechanical properties of the board. This process with no addition of adhesive used higher pressure and temperature than the conventional one and was applied with or without paraformaldehyde. The results are as follows: 1. The new manufacturing process allowed a good bark board with high absorption coefficient. 2. The best manufacturing process for the mechanical properties of bark board was paraformaldehyde 10%-$250^{\circ}C$-100kg/$cm^2$-3 minutes, (bending strength 40kg/$cm^2$, internal bonding strength 2kg/$cm^2$) and the best manufacturing process for both the mechanical properties of bark board and economic point of view was $250^{\circ}C$-100kg/$cm^2$-3 minutes (bending strength 28kg/$cm^2$, internal bonding strength 1.52kg/$cm^2$). 3. Bark board showed specific gravities from 0.94 to 1.03 and air dried moisture content 9.2% to 11.7%, but Bark board needed paraffin wax emusion treatment. 4. The absorption coefficient of bark boards had two peaks along with frequency; one in 200-400 cps, the other 1200-2000 cps. The former was low but the latter great.

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미립캡슐잠열재 제조 및 축열식 냉방기 적용실험 (An Experimental Study for Manufacturing MPCM Slurry and Its Application to a Cooling System)

  • 이효진;최준규;이재구
    • 설비공학논문집
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    • 제15권5호
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    • pp.352-359
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    • 2003
  • The present study has been conducted for manufacturing MPCM (microencapsulated phase change material) slurry with in-situ polymerization and proving their applicabilities for tooling system. The surface of MPCM is composed of melamine, while tetradecane, paraffin wax, is centered in the MPCM. The produced capsules are observed by the optical microscope and SEM for superficial shapes. Their thermal properties are measured by DSC. Their size distributions are observed by FA particle analyzer. A narrow size distribution from 1 to 10 ${\mu}{\textrm}{m}$ with 5 ${\mu}{\textrm}{m}$ of average diameter was observed. Melting temperature was 6.7$^{\circ}C$. The durability of MPCM was tested with various types of pump such as centrifugal, peristaltic, and mono pumps. During 10000 cycles the fraction of broken capsules was smaller than 6% for the centrifugal and peristaltic pumps, while bigger value of 8% for the mono pump. A cooling system, which adopted MPCM slurry as a media for transporting cold thermal energy, was designed to investigate the performance of the MPCM. The discharging times of 10 and 20 wt% MPCM slurry were lasted up to 105 and 285 minutes longer, respectively, than the water cooling system.

Eudragit $RS^{\circledR}$를 이용한 지속 방출형 아스피린 마이크로캅셀의 제조 및 평가 (Preparation and Evaluation of Sustained Release Aspirin Microcapsules Using Eudragit $RS^{\circledR}$ Polymer)

  • 전인구;신동원
    • 약학회지
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    • 제32권1호
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    • pp.26-39
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    • 1988
  • Eudragit $RS^{\circledR}$ polymer was used as a wall material for the microencapsulation of aspirin by a phase separation method from chloroform-cyclohexane system with 5% polyisobutylene (PIB) in cyclohexane, and microcapsules obtained were evaluated by particle size analysis, scanning electron microscopy (SEM), drug release and drug stability test. With PIB as a coacervation inducing agent, smooth and tight microcapsules with less aggregation were obtained. Below 1 : 0.3 core-wall ratio, it was possible to coat individual particle. Variation of production conditions showed that increasing the proportion of wall material, particle size and wall thickness of microcapsules and the concentration of paraffin wax in cyclohexane as a sealant sustained drug release rates effectively. SEM confirmed that larger microcapsules after drug release did not rupture into smaller particles but contained a few small pores on the surface. Aspirin release from Eudragit $RS^{\circledR}$ coated microcapsules was independent of the pH of medium, and the mechanism of drug release from non-sealed and sealed microcapsules appeared to fit Higuchi matrix model kinetics. Aspirin in the mixture of aspirin microcapsules and sodium bicarbonate was by far more stable than that in the mixture of pure aspirin and sodium bicarbonate.

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Ultrasonic Estimation and FE Analysis of Elastic Modulus of Kelvin Foam

  • Kim, Nohyu;Yang, Seungyong
    • 비파괴검사학회지
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    • 제36권1호
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    • pp.9-17
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    • 2016
  • The elastic modulus of a 3D-printed Kelvin foam plate is investigated by measuring the acoustic wave velocity of 1 MHz ultrasound. An isotropic tetrakaidecahedron foam with 3 mm unit cell is designed and printed layer upon layer to fabricate a Kelvin foam plate of 14 mm thickness with a 3D CAD/printer using ABS plastic. The Kelvin foam plate is completely filled with paraffin wax for impedance matching, so that the acoustic wave may propagate through the porous foam plate. The acoustic wave velocity of the foam plate is measured using the time-of-flight (TOF) method and is used to calculate the elastic modulus of the Kelvin foam plate based on acousto-elasticity. Finite element method (FEM) and micromechanics is applied to the Kelvin foam plate to calculate the theoretical elastic modulus using a non-isotropic tetrakaidecahedron model. The predicted elastic modulus of the Kelvin foam plate from FEM and micromechanics model is similar, which is only 3-4% of the bulk material. The experimental value of the elastic modulus from the ultrasonic method is approximately twice as that of the numerical and theoretical methods because of the flexural deformation of the cell edges neglected in the ultrasonic method.

Recent research activities on hybrid rocket in Japan

  • Harunori, Nagata
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2011년도 제36회 춘계학술대회논문집
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    • pp.1-2
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    • 2011
  • Hybrid rockets have lately attracted attention as a strong candidate of small, low cost, safe and reliable launch vehicles. A significant topic is that the first commercially sponsored space ship, SpaceShipOne vehicle chose a hybrid rocket. The main factors for the choice were safety of operation, system cost, quick turnaround, and thrust termination. In Japan, five universities including Hokkaido University and three private companies organized "Hybrid Rocket Research Group" from 1998 to 2002. Their main purpose was to downsize the cost and scale of rocket experiments. In 2002, UNISEC (University Space Engineering Consortium) and HASTIC (Hokkaido Aerospace Science and Technology Incubation Center) took over the educational and R&D rocket activities respectively and the research group dissolved. In 2008, JAXA/ISAS and eleven universities formed "Hybrid Rocket Research Working Group" as a subcommittee of the Steering Committee for Space Engineering in ISAS. Their goal is to demonstrate technical feasibility of lowcost and high frequency launches of nano/micro satellites into sun-synchronous orbits. Hybrid rockets use a combination of solid and liquid propellants. Usually the fuel is in a solid phase. A serious problem of hybrid rockets is the low regression rate of the solid fuel. In single port hybrids the low regression rate below 1 mm/s causes large L/D exceeding a hundred and small fuel loading ratio falling below 0.3. Multi-port hybrids are a typical solution to solve this problem. However, this solution is not the mainstream in Japan. Another approach is to use high regression rate fuels. For example, a fuel regression rate of 4 mm/s decreases L/D to around 10 and increases the loading ratio to around 0.75. Liquefying fuels such as paraffins are strong candidates for high regression fuels and subject of active research in Japan too. Nakagawa et al. in Tokai University employed EVA (Ethylene Vinyl Acetate) to modify viscosity of paraffin based fuels and investigated the effect of viscosity on regression rates. Wada et al. in Akita University employed LTP (Low melting ThermoPlastic) as another candidate of liquefying fuels and demonstrated high regression rates comparable to paraffin fuels. Hori et al. in JAXA/ISAS employed glycidylazide-poly(ethylene glycol) (GAP-PEG) copolymers as high regression rate fuels and modified the combustion characteristics by changing the PEG mixing ratio. Regression rate improvement by changing internal ballistics is another stream of research. The author proposed a new fuel configuration named "CAMUI" in 1998. CAMUI comes from an abbreviation of "cascaded multistage impinging-jet" meaning the distinctive flow field. A CAMUI type fuel grain consists of several cylindrical fuel blocks with two ports in axial direction. The port alignment shifts 90 degrees with each other to make jets out of ports impinge on the upstream end face of the downstream fuel block, resulting in intense heat transfer to the fuel. Yuasa et al. in Tokyo Metropolitan University employed swirling injection method and improved regression rates more than three times higher. However, regression rate distribution along the axis is not uniform due to the decay of the swirl strength. Aso et al. in Kyushu University employed multi-swirl injection to solve this problem. Combinations of swirling injection and paraffin based fuel have been tried and some results show very high regression rates exceeding ten times of conventional one. High fuel regression rates by new fuel, new internal ballistics, or combination of them require faster fuel-oxidizer mixing to maintain combustion efficiency. Nakagawa et al. succeeded to improve combustion efficiency of a paraffin-based fuel from 77% to 96% by a baffle plate. Another effective approach some researchers are trying is to use an aft-chamber to increase residence time. Better understanding of the new flow fields is necessary to reveal basic mechanisms of regression enhancement. Yuasa et al. visualized the combustion field in a swirling injection type motor. Nakagawa et al. observed boundary layer combustion of wax-based fuels. To understand detailed flow structures in swirling flow type hybrids, Sawada et al. (Tohoku Univ.), Teramoto et al. (Univ. of Tokyo), Shimada et al. (ISAS), and Tsuboi et al. (Kyushu Inst. Tech.) are trying to simulate the flow field numerically. Main challenges are turbulent reaction, stiffness due to low Mach number flow, fuel regression model, and other non-steady phenomena. Oshima et al. in Hokkaido University simulated CAMUI type flow fields and discussed correspondence relation between regression distribution of a burning surface and the vortex structure over the surface.

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Changes of superoxide dismutase and glutathione peroxidase in light damaged rat retina

  • Kaidzu, Sachiko;Tanito, Masaki;Takanashi, Taiji;Ohira, Akihiro
    • Journal of Photoscience
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    • 제9권2호
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    • pp.430-432
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    • 2002
  • The changes in expression of copper-zinc superoxide dismutase (CuZn-SOD), manganese superoxide dismutase (Mn-SOD) and glutathione peroxidase (GPX) in light-damaged rat retinas were examined. Sprague-Dawley rats (male, 6-weeks-old) were maintained on a cyclic photoperiod (12 hours light and 12 hours darkness) for 2 weeks. The illumination intensity during the light period was 80 lux. To induce light damage to the retina, a high-intensity illumination (3000-lux) was applied to the animals for 24 hours. After light exposure, the animals were returned to cyclic lighting. Eyes were enucleated 12 and 24 hours after light exposure started or 1,3, and 7 days after light exposure ended. Eyes were fixed and embedded in paraffin wax. Tissues were cut into 4${\mu}{\textrm}{m}$-thick sections. Sections were immunostained using antibody against CuZn-SOD, Mn-SOD, GPX and 8-hydroxy-deoxyguanocine (8-OHdG) as oxidative stress marker. 8-OHdG was observed in the outer nuclear layer (ONL) and retinal pigment epithelium (RPE) during light exposure. In light-damaged retinas CuZn-SOD labeling was up regulated in the ONL and RPE. Mn-SOD labeling was up regulated in rod inner segments (RIS) during light exposure and that in the RPE was up regulated after exposure. GPX labeling was observed in rod outer segments (ROS) during light exposure. GPX labeling was also observed in the RPE during and after light exposure. All three enzymes were observed in the outer retina, which suffered light damage, but occurred in defferent layers except within the RPE, in which case all three were expressed. These enzymes may play complementary roles as protective factors in light-damaged retinas.

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폴리아미드계 수지를 이용한 핫멜트 접착제의 기능 향상 -(I) 접착제의 물성- (Functional Improvement of Hot Melt Adhesive Using Polyamide Type Resin -(I) Physical Properties of Adhesives-)

  • 전영식;홍영근;정경호
    • 공업화학
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    • 제7권1호
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    • pp.194-202
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    • 1996
  • 기존의 ethylene-vinyl acetate 핫멜트 접착제는 시간에 따른 크리프 특성과 내열성 등의 한계로 사용에 제한이 있으므로 물성의 향상을 위해 폴리아미드계 수지를 이용한 새로운 핫멜트 접착제 개발에 관하여 연구하였다. 폴리아미드 단일중합체의 경우 융점과 용융점도가 매우 높기 때문에 대신 나일론6, 나일론66, 나일론12로 이루어진 삼원공중합체 혹은 블렌딩 수지를 사용하므로써 분자쇄의 규칙성 파괴로 인해 용융점도와 용융점을 강하시킬 수 있었다. 이로써 선택된 수지가 핫멜트 접착제의 베이스 수지로 적절함을 알 수 있었다. 또한 베이스 수지에 테르펜 수지, butyl benzyl phthalate, 파라핀왁스 등을 첨가하여 접착제를 구성함에 따라 유변학적 거동도 쉽게 조절될 수 있었다. 용융점도와 접착제 자체의 인장물성 결과에 따르면 사용된 CM831과 843형 폴리아미드 수지를 약 75/25~50/50의 무게비로 블렌딩함이 최적의 접착력을 나타내리라 평가되었다. 또한 steel간의 접착력 평가 결과 steel 표면의 거칠음 정도가 접착력에 직접 영향을 미치는 결과를 얻었다.

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독일세퍼드견에서의 폐전이 소견의 양측성 신장 낭선암종 (Bilateral renal cystadenocarcinoma with lung metastasis in German sheperd dog)

  • 박우희;류문영;이현경;최은진;소병재;이경현
    • 한국동물위생학회지
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    • 제38권4호
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    • pp.249-252
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    • 2015
  • Primary renal tumors are uncommon in dogs with prevalence rate of approximately 1%. Renal carcinoma originating from epithelium of proximal convoluted tubules are more likely to be affected to Middle-aged dogs (average age, 8y), males about twice as often as bitches. A 10-year-old, female, German Shepherd dog with history of anorexia, vomitting and hematuria was referred to the Animal Disease Diagnostic Division in Animal and Plant Quarantine Agency. The dog was necropsied and several organs were collected, fixed in 10% phosphate-buffered formalin, embedded in paraffin wax and sectioned for histopathology. Grossly, the kidneys were bilaterally enlarged ($18{\times}12{\times}8cm$; left, $18{\times}10{\times}8cm$; right). The numerous cysts varying sizes from 3 to 6 cm in diameter were protruding from the surface of both kidney. A large nodule ($10{\times}6{\times}6cm$) was discovered between cardiac and diaphragmatic lobe in the right lung. Immunohistochemical examination revealed strong positive reaction to cytokeratin and ki-67 in the nuclei of the epithelial tumor cells. But showed negative reactions to vimentin and CD10. Based on the pathological and immunohistochemical examination, we diagnosed as the bilateral renal cystadenocarcinoma in German shepherd dog.

캡슐화된 PCM을 이용한 유동층 축열조에서 열전달 특성 연구 (Heat Transfer Chracteristics in a Fluidized bed Heat Storage System Using Encapsulated PCM)

  • 윤영호;한귀영;강용혁;곽희열;이태규;전명석
    • 태양에너지
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    • 제18권3호
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    • pp.89-94
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    • 1998
  • 태양열 응용을 위한 한 방편으로 캡슐화된 PCM을 이용한 유동층 축열조에서 축열 및 방열과정에서 열전달 특성을 살펴보았다. 유동층 축열조는 원통형으로 높이는 40cm, 직경은 5.0cm 이었다. 축열물질은 무기염의 일종인 sodium acetate 였으며, 이것은 파라핀 왁스와 PMMA 로 코팅되었다. 캡슐화된 PCM의 크기는 약 $2{\sim}3mm$였으며, 용융점은 $58^{\circ}C$였다. 축열 및 방열과정시 유동층 축열조의 시간에 따른 온도분포, 순간 열저장 및 방출 속도를 측정하였으며 이로부터 유동층 축열조의 체적 열전달 계수를 도출하였다. 또한 유동층 축열조의 조업변수인 열전달 유체의 유속, 유입온도에 대한 열전달 계수의 영향도 관찰하였다.

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