• Title/Summary/Keyword: Paleozoic

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Fluid Inclusion Studies of the Fluorite Deposits in Korea (우리나라 형석광상(螢石鑛床)의 유체포유물(流體包有物) 연구(硏究))

  • Park, Hee In
    • Economic and Environmental Geology
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    • v.9 no.1
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    • pp.27-43
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    • 1976
  • The flourite in Hwacheon, Hwanggangri and Keumsan district are major fluorite producing areas in Korea. The fluorite deposits of Hwacheon district are wholly fissure filling hydrothermal veins embedded in Precambrian gneiss and schists and Jurassic granites. Also some fluorite deposits are emplaced in felsite whose age is unknown. Emplacement of most fluorite veins of the district are controlled by EW fracture system. Fluorites are generally accompanied to chalcedonic quartz and also kaolinite, montmorillonite, dickite and calcite in parts. Vertical and lateral mineral zonings are not distinct. The fluorite deposits in the Hwanggangri district are wholly embedded in limestone and other calcareous sediments of Paleozoic Yeongweol Group. Most of the fluorite deposits belong to one of two categories which are steeply. dipping veins and gently dipping replacement deposits adjacent to Late Cretaceous(83-90mys) granite bodies. The strikes of fluorite veins of Hwanggangri district mostly occupy the fractures of $N30^{\circ}-40^{\circ}E$ and $N30^{\circ}-40^{\circ}W$ system. Fluorites are accompanied to calcite, milky quartz, chalcedonic quartz, and also montmorillonite, kaolinite in parts. But in some deposits, scheelite, various sulfide minerals and barite are accompanied. Emplacement of fluorite deposits are largely controlled by lithology and structures of this district. In some deposits fluorite veins gradate to scheelite veins and also telescoping of the mineral zones are found in this district. In the Keumsan district, fissure-filled fluorite veins and replacement deposits are mostly emplaced in limestone of Paleozoic Yeongweol Group, late Cretaceous quartz-porphyry, granite and sandstone. Some deposits are emplaced in Precambrian metasediments. Mineralogy and other characteristics of the deposits in this district is similar to those of Hwanggangri district. Fluid inclusion studies reveal the difference of salinities, $CO_2$ contents of ore fluid and temperatures during fluorite mineral deposition in the these districts. In Hwacheon district, ore-fluids were comparatively dilute brine and low $CO_2$ content. Filling temperatures ranges $104^{\circ}C$ to $170^{\circ}C$. In the Chuncheonshinpo mine, most deeply exploited one in this district, salinitles range 0.5-2. 2wt. % NaCl and filling temperatures range from $116^{\circ}C$ to $143^{\circ}C$. In the Hwanggangri district, ore fluids were complex and filling temperature ranges very widly. In the contact metasomatic fluorite deposits, ore fluid were NaCl rich brines with moderate $CO_2$ content and filling temperatures range from $285^{\circ}C$ to above $360^{\circ}C$. Fluids inclusions in tungsten and sulfide minerals bearing fluorite veins show high $CO_2$ content up to 31wt. %. Filling temperature ranges from $101^{\circ}C$ to $310^{\circ}C$. Fluids inclusions In mainly fluorite bearing veins were more dilute brine and low $CO_2$ contents. Filling temperatures range from $95^{\circ}C$ to $312^{\circ}C$. Filling temperature of fluid inclusions of Keumsan district are between $95^{\circ}C$ and $237^{\circ}C$. Data gathered from geologic, mineralogic and fluid inclusion studies reveal that fluorite mineralization in H wacheon district proceeded at low temperature with dilute brine and low $CO_2$ content. In Hwangganri district, fluorite mineralization proceeded by several pulse of chemically distinct ore fluids and formed the mineralogically different type of deposits around cooling granite pluton which emplaced comparatively shallow depth.

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Case Study on the Mitigation of Dangerous Slope Considering the Value of Geoheritage (지질유산 가치를 고려한 위험비탈면 보존 방안 사례 연구)

  • Jeong, Jun-Ho;Kim, Seung-Hyun;Park, Byung-suk;Woo, Yong-Hoon;Kang, Yun-seok;Koo, Ho-bon;Son, Moon
    • The Journal of Engineering Geology
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    • v.30 no.1
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    • pp.71-84
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    • 2020
  • Various geological structures are found on the slope of Bangnim district in Pyeongchang, Gangwon-do, based on the Paleozoic Joseon Supergroup Limestone. The recumbent fold observed on the slope is a very rare geological structure that has not been found in Korea, and has important academic value in exploring the formation process of the Paleozoic geological structures in the Gangwon region. In this study, discussed the geological value of the geological structure observed on the slope of the road, and studied the management method of rockfall problem slopes. The state of development of recumbent folds has conservation value in geological scarcity and specificity. Preservation management measures should be prepared through the protection of slopes and measures to reduce of rockfall risks as geoheritage with an important value in geology science and education. Furthermore, it is expected to be preserved and utilized as a geopark.

Geochronology and Petrogenetic processes of the so-called Hongjesa granite in the Seogpo-Deogku Area (석포(石浦)-덕구간(德邱間)에 분포(分布)하는 소위(所謂) 홍제사화강암(洪濟寺花崗岩)의 지질연대(地質年代)와 생성과정(生成過程)에 대(對)한 硏究(연구))

  • Kim, Yong Jun;Lee, Dai Sung
    • Economic and Environmental Geology
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    • v.16 no.3
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    • pp.163-221
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    • 1983
  • Main aspects of this study are to clarify geochronology and petrogenetic processes of the so-called Hongjesa granite, which is a member of various intrusive rocks exposed in the northeastern part of the Ryongnam Massif, one of the Precambrian basements of South Korea. In this study, the Hongjesa grainte is divided into four rock units based on the geologic age, mineralogical and chemical constituents, and texture: the Precambrian Hongjesa granite gneiss (Hongjesa granite Proper) and leucogranite gneiss, the Paleozoic gnessic two mica granite, and the Jurassic muscovite granite. The Hongjesa granite gneiss is identified by its grayish color, slight foliation, and porphyroblastic texture. The leucogranite gneiss is distinct by its light gray color, sand medium to coarse grained texture. The gneissic two mica granite is distinguished from others by its strong foliation, containing gray-colored feldspar phenocrysts with biotite and muscovite in varying amounts. The muscovite granite occurs as a small stock containing feldspar phenocrysts along margin of the stock. These granitic rocks vary widely in composition, reflecting the facts that they partly include highly metamorphosed xenolith and schlierens as relics of magmatic and anatectic processes. In particular, grayish porphyroblasts of microcline perthite is characteristic of the Hongjesa granite gneiss, whereas epidote and garnet occur in both the Hongjesa granite gneiss and leucogranite gneiss. These minerals are considered to be formed by potassic metasomatism and contamination of highly metamorphosed rocks deeply buried under the level of the Hongjesa granite emplacement. The individual synchronous granitic rocks plotted on Harker diagram show mostly similar trends to the Daly's values. The plots of the Hongjesa granite gneiss and gneissic two mica granite concentrate near the end part of the calc-alkalic rock series on the AMF diagrams, whereas those of the leucogranite gneiss and muscovite granite indicate the trend of the Skaergaard pluton. These granitic rocks plotted on a Q-Ab-Or diagram (petrogeny's residua system) fall well outside the trough of the system. This can be attributed to the potassic matasomatism of these rocks. On the ACF diagram, these rocks appear to be dominantly I-type prevailing over S-type. The K-Ar ages, obtained from a total of 7 samples of the leucogranite gneiss, gneissic two mica granite, muscovite granite, porphyritic alkali granite, and rhyolitic rock, in addition to the Rb/Sr ages of the Hongjesa granite gneiss by previous workers, permit the rock units to be arranged in the following chronological order: The middle Proterozoic Hongjesa granite gneiss (1714-1825 m.y.), the upper proterozoic leucogranite gneiss (875-880 m. y.), the middle Paleozoic gneissic two mica granite (384 m. y.) the upper Jurassic muscovite granite (147 m. y.), the Eocene alkali granite (52 m. y.), and the Eocene rhyolitic rock (45 m. y.). From the facts and data mentioned above, it is concluded that the so-called Hongjesa granite is not a single granitic mass but is further subdivided into the four rock units. The Hongjesa granite gneis, leucogranite gneiss, and gneissic two mica granite are postulated to be either magmatic or parautochtonous, intrusive, and the later muscovite granite is to be magmatic in origion.

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SHRIMP Zircon Ages of the Basement Gneiss Complex in the Pyeongchang-Wonju Area, Gyeonggi Massif, Korea (명창-원주 지역의 경기육괴 기반암 편마암 복합체에 대한 SHRIMP 저어콘 연대 측정)

  • Song, Yong-Sun;Park, Kye-Hun;Seo, Jae-Hyeon;Jo, Hui-Je;Yi, Kee-Wook
    • The Journal of the Petrological Society of Korea
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    • v.20 no.2
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    • pp.99-114
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    • 2011
  • Precambrian gneiss complex in the Pyeongchang-Wonju area, which lies west of the Paleozoic sedimentary basin of the Yeongwol-Taebaek area, is being considered as a part of the Gyeonggi massif, but its ages of formation and metamorphic events are not well defined yet. In this study, SHRIMP zircon U-Pb ages were determined from the gneiss complex in the area, We obtained the discrete ages of magmatic (ca. 1960 Ma) and metamorphic (ca. 1860 Ma) events through the interpretation of the SHRIMP data based on the internal structures of zircons. These are almost the same to the ages of main intrusion and metamorphism reported from the Precambrian basements of Gyeonggi, Yeongnam and Nangnim massifs of the Korean Peninsula, Ages of 3200~3300 Ma, 2900 Ma, 2660 Ma, 2430 Ma, 2260 Ma, and 2080~2070 Ma obtained from inherited cores of studied zircons are also very similar to the frequently reported ages from the basement rocks of the Gyeonggi and Yeongnam massifs, Lower intercept age of about 270 Ma calculated from the rim data seems to indicate that the study area suffered from a late Paleozoic metamorphism (Okcheon Orogeny), but we need more reasonable and sufficient data to confirm it. According to the results of this study, it is suggested that the Bangnim group unconformably overlying the gneiss complex was deposited after the Paleoproterozoic granitic magmatism (ca. 1960 Ma) and metamorphism (ca. 1860 Ma).

A Review on the Depositional Age and Provenance of the Taean Formation in the Western Gyeonggi Massif (서부 경기육괴에 분포하는 태안층의 퇴적시기와 기원지에 대한 고찰)

  • Choi, Taejin;Park, Seung-Ik
    • Economic and Environmental Geology
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    • v.52 no.5
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    • pp.347-356
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    • 2019
  • Various studies regarding the sedimentary environment, depositional age, provenance, and metamorphic history have been carried out on the Taean Formation in the western part of Gyeonggi Massif, since the unique detrital zircon age pattern was revealed. This review paper introduces the previous researches on the Taean Formation and discusses the depositional age and provenance. The Taean Formation was traditionally regarded as a Precambrian stratigraphic unit, but recently it is interpreted to be a middle or upper Paleozoic formation due to the occurrence of large amounts of Early to Middle Paleozoic detrital zircons. The Taean Formation consists of metasandstone, argillaceous schist, and phyllite which are mainly made up of quartz and mica. The protoliths are interpreted as turbidites deposited in deep sea fan environment. The Taean Formation has been interpreted to be deposited between the Devonian to Triassic ages given the age differences between detrital zircons and intrusive rocks. There are two opinions that the deposition age is close to the Devonian or the Permian period. The provenance of this formation is supposed to be South China block, Chinese collisional belt, or Gyeonggi Massif. Given the available detrital zircon ages of the Taean Formation and other Korean (meta)sedimentary rocks, the Taean Formation shares major source rocks with Yeoncheon Group and Pibanryeong Unit of the Okcheon Supergroup, but their source regions are not entirely consistent. Considering the existing hypotheses about the depositional timing and provenance, we put weight on the possibility that the Taean Formation was deposited between Permian and Early Triassic periods. However, further studies on the stratigraphy and sedimentary petrology are needed to clarify its definition and to elucidate the provenance.

A Study on Geology and Mineralization in San Luis Potosi, Mexico (멕시코 산 루이스 포토시주의 지질 및 광화작용에 대한 고찰)

  • Oh, Il Hwan;Heo, Chul Ho
    • Journal of the Korean earth science society
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    • v.40 no.2
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    • pp.163-176
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    • 2019
  • The Potosinian geological basement in central Mexico is comprised of the Upper Paleozoic metamorphic rocks, which crop out on the Sierra de Catorce nucleus located in the northeastern part of the state. The sedimentary sequence that covers unconformably the Paelozoic basement is represented by an Upper Triassic marine sedimentary sequence, correlating to the Zacatecas Formation and the Upper Triassic continental Huizachal Formation red beds, which in turn are covered either by La Joja Formation Jurassic red beds or by Upper Jurassic marine sediments. This sequence is overlain by the conformable Cretaceous calcareous marine sedimentary rocks in all the state of San Luis Potosi. The Cenozoic sequence unconformably covers some of the aforementioned rocks and is represented by undifferentiated volcanic rocks as well as by marine clastic rocks. The existing intrusive igneous rocks are felsic to intermediate composition, and they intrude the metamorphic basement and sedimentary rocks. Conglomerates with evaporitic sediments were deposited during the Pleistocene. The Quaternary sequence includes basalt flows, piedmont deposits, alluvium, and occasionally evaporites and caliche layers. In the state of San Luis Potosi, a great diversity of mineral deposit types is known as both metallic and nonmetallic. The host rocks of these deposits vary from one another including formations that represent from Paleozoic up to Tertiary. The mineralization age corresponds approximately to Tertiary (75%), and is mainly epigenetic. Conclusively, the data on geology and mineralization in San Luis Potosi, Mexico are helpful to predict a hidden ore body and select promising mineralized zone(s) when the domestic company makes inroads in the mining sector of Mexico.

Geothermometrical Studies of Fluorite Deposits with special reference to the Studies of Fluorites from the Wolaksan area and Cheonil Mine, Chungcheongbuk-Do (형석광상(螢石鑛床)의 지질온도측정(地質溫度測定) 연구(硏究) 특(特)히 충북(忠北) 월악산지대(月岳山地帶) 및 천일광산(天一鑛山) 형석(螢石)의 연구(硏究)를 중심(中心)으로)

  • Yun, Suckew
    • Economic and Environmental Geology
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    • v.6 no.4
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    • pp.195-200
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    • 1973
  • Temperature environments of the formation of fluorite deposits in the Wolaksan area and the Cheonil Mine, Chungcheongbuk-Do are presented and interpreted in brief. These deposits occur more or less near the contact zone between the Paleozoic limestone formations and the Cretaceous biotite granites as a number of hydrothermal veins or replacement deposits. The homogenization temperatures of fluorite crystals from the Wolaksan area fall within the narrow range of $149{\sim}167^{\circ}C$, of which lower limit is quite high, while those of the Cheonil Mine show wide range of $126{\sim}177^{\circ}C$, which indicates much lower mean temperature of formation. If the possible correction for pressure, which may not exceed $+30^{\circ}C$ as the depth of the deposits was 1.5km, were applied, the possible highest value of the true formation temperatures of fluorites in both area might be reached to around $200^{\circ}C$ that means these deposits were formed as a series of early products of the epithermal stage of hydrothermal processes.

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Isotope Geochemistry of Uranium Ore Deposits in Okcheon Metamorphic Belt, South Korea (옥천변성대내(沃川變成帶內)에 분포(分布)하는 우라늄광상(鑛床)의 동위원소(同位元素) 지구화학적(地球化學的) 연구(硏究))

  • Kim, Kyu Han
    • Economic and Environmental Geology
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    • v.19 no.spc
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    • pp.163-173
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    • 1986
  • Black and graphite slates from the Okcheon metamorphic belt contain enriched values of uranium (average 200~250ppm) and molybdenum (average 150~200ppm). Uranium mineralization is closely associated with quartz and sulfide veinlets which are formed diagenetically in graphite slate. The uranium minerals were concentrated in outer part of graphite nodules. The ${\delta}^{13}C$ values of organic carbon from the metasediments including uranium bearing graphite slate range from -15.2 to -26.1‰ with a mean of -23.5‰. Meanwhile, ${\delta}^{13}C$ values of coal and coaly shale from some Paleozoic coal fields of South Korea vary from -19.4 to -23.9‰ with an average of -22.5‰. Isotopic compositions of vein calcite in uranium bearing slate range from -13.4 to -15.4‰ in ${\delta}^{13}C$ and +11.3 to +15.1‰ in ${\delta}^{18}O$ could indicate a reduced organic carbon source isotopically exchanged with a graphite of biogenic origin. Metamorphic temperature determined by a calcite-graphite isotope geothermometer was 383~$433^{\circ}C$ which corresponded to greenschist facies by Miyashiro (1973) and is consistent with metamorphic facies estimated by mineral assemblages (Lee, et al., 1981, and Kim, 1971). The fixation of uranyl species by carbonaceous matter in marine epicontinental environment, and remobilization of organouranium by diagenetic processes have attributed to the enrichment of uranium and heavy metals in the graphite slate of Okcheon metamorphic belt.

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Paleomagnetism of the Pyongan Supergroup in the Samcheok Area (삼척지역에 분포하는 평안누층군에 대한 고지자기 연구)

  • Doh, Seong-Jae
    • Economic and Environmental Geology
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    • v.28 no.6
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    • pp.559-569
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    • 1995
  • Paleomagnetic data have been obtained from the Upper Carboniferous-Permian Komok and Cheolam Groups which are exposed in the E-W trending Baekunsan syncline comprising the Pyongan Supergroup in eastern Korea. Two ancient components of magnetization are recovered in these groups by detailed thermal demagnetization: a post-folding component and a pre-folding component. The post-folding component $(D/I=54.0/54.6^{\circ},\;{\alpha}_{95}=14.6^{\circ})$ is a magnetic signature of the Oaebo Orogeny and appears to have been confined mainly to Cretaceous Normal Superchron. It has been rotated clockwise since this magnetization has been acquired. The pre-folding components ($D/I=341/-9.2^{\circ},\;{\alpha}_{95}=7.2^{\circ})$, paleopole at $335.7^{\circ}E$, $44.6^{\circ}N$ for Upper Carboniferous; $D/I=358.3/11.5^{\circ},\;{\alpha}_{95}=6.3^{\circ})$, paleopole at $311.9^{\circ}E$, $58.7^{\circ}N$ for Permian) pass fold and reversal tests. These paleopoles correspond only with the contemporaneous poles from the North China Block: they are removed from the poles from the South China Block. If the results of this study are corrected for the clockwise rotation deduced from the prefolding component, the enhanced agreement with North China Block can be achieved. Therefore, a first-order correlation between the Korean Peninsula and North China at least since Upper Paleozoic times is identified in this study.

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A brief review on Oyster shells origin and sedimentary evolution for the formation of limestone

  • Ramakrishna, Chilakala;Thriveni, Thenepalli;Whan, Ahn Ji
    • Journal of Energy Engineering
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    • v.27 no.3
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    • pp.48-56
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    • 2018
  • The shell waste biomineralization process has known a tremendous metamorphosis and also the nanostructure with the identification of matrix proteins in oyster shells. However, proteins are represented in minor shell components and they are the major macromolecules that control biocrystal synthesis. Aragonite and calcite were derived from molluscan shells and evaluated the source of carbonate minerals and it helps for the formation of limestone. The oyster shell wastes are large and massive. The paleoecological study of oyster beds has discovered a near-shore and thin Upper Rudeis formation with storm influence during the accumulation of oysters with highly altered by disarticulation, bioerosion, and encrustation. It is possible even in the Paleozoic mollusks provided sufficient carbonate entirely to the source of microcrystalline of limestone. The present review is to discuss paleoecologically a number of oyster shell beds accumulated and sediment to form the different types of limestone during the Middle Miocene time.