• Bulletin of the Korean Chemical Society
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• v.22 no.7
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• pp.673-677
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• 2001

Pseudo-first-order rate constants have been measured spectrophotometrically for the reactions of 8-(5-nitroquinolyl) 3-furoate with alkali metal ethoxides in anhydrous ethanol. The plot of kobs vs the concentration of alkali metal ethox ides is linear for the reactions performed in the presence of a complexing agent, 18-crown-6 ether, but exhibits upward curvatures for the corresponding reactions performed in the absence of the complexing agent, indicating that the alkali metal ions in this study behave as catalysts. Second-order rate constants were determined for the reactions with dissociated free ethoxide (kEtO-) and with ion paired alkali metal ethoxides (kEtO-M + ) from ion pairing treatments. The magnitude of catalytic effect (kEtO-M + /kEtO-) was found to be 1.7, 3.4 and 2.5 for the reaction of 8-(5-nitroquinolyl) 3-furoate, while 1.4, 3.6 and 4.2 for that of 4-nitrophenyl 2-furoate, 1.8, 3.7 and 2.4 for that of 8-(5-nitroquinolyl) benzoate, and 2.0, 9.8 and 9.3 for that of 8-(5-nitroquinolyl) 2-furoate with EtO- Li+ , EtO- Na+ and EtO- K+ , respectively. A 5-membered chelation at the leaving group is suggested to be responsible for the catalytic effect shown by alkali metal ions.

• Journal of the Korean Society of Propulsion Engineers
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• v.1 no.1
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• pp.33-45
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• 1997

Axisymmetric shear layers around a free jet is forced by co-flowing and counter-flowing secondary jets from/to an annular tube around the jet nozzle. The jet potential core extends far downstream with co-flowing secondary jets due to inhibited vortex developing and pairing. For counter-flowing cases, the axisymmetric shear layer around the jet transits from convective instability to absolute instability for velocity ratios R＝1.3～l.65 for the uniform velocity jets. Consequently, the jet potential core length increases and the turbulence level in the jet core is reduced significantly. The jets are controlled better with extension collars attached to the outer nozzle exit because the annular secondary flow is guided well by the extension collars. For the vectoring of jet, the annular tube around the jet is divided in two parts and the only one part is used for suction. The half suction makes the different shear layer around the jet and vectoring the jet by Coanda effect. The vectoring and turbulent components are varied significantly by the suction ratio. The experiments are carried out to investigate the characteristics of forced free jets using flow visualization, velocity and turbulence measurements.

• Journal of the Korea Institute of Information Security & Cryptology
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• v.28 no.3
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• pp.563-577
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• 2018

In order to support secure communication in VANET(Vehicular Ad hoc Network), messages exchanged between vehicles or between vehicle and infrastructure must be authenticated. In this paper, we propose a hierarchical anonymous authentication system for VANET. The proposed system model reduces the overhead of PKG, which is a problem of previous system, by generating private keys hierarchically, thereby enhancing practicality. We also propose a two-level hierarchical identity-based signature(TLHIBS) scheme without pairings so that improve efficiency. The proposed scheme protects the privacy of the vehicle by satisfying conditional privacy and supports batch verification so that efficiently verifies multiple signatures. Finally, The security of the proposed scheme is proved in the random oracle model by reducing the discrete logarithm problem(DLP) whereas the security proof of the previous ID-based signatures for VANET was incomplete.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.9
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• pp.1253-1262
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• 2001

Experimental study is conducted to investigate the heat/mass transfer and flow characteristics for the flow over backward-facing step and cavities. A naphthalene sublimation method has been employed to measure the mass transfer coefficients on the duct wall and LDV system has been used to obtain mean velocity profiles and turbulence intensities. Reynolds number based on the step height and free stream velocity is 20,000 and St numbers of acoustic excitations given to separated flow are 0.2 to 0.4. The spectra of streamwise velocity fluctuation show a sharp peak forcing frequency for an acoustically excited flow. The results reveal that the vortex pairing and overall turbulence level are enhanced by the acoustic excitation and a significant decrease in the reattachment length and the increased turbulence intensity are observed with the excitation. A certain acoustic excitation increases considerably the heat/mass transfer coefficient at the reattachment point and in the recirculation region. For the cavities, heat/mass transfer is enhanced by the acoustic excitation due to the elevated turbulence intensity. For the 10H cavity, the flow pattern is significantly changed with the acoustic excitation. However, for the 5H cavity, the acoustic excitation has little effect on the flow pattern in the cavity.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.8
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• pp.1023-1032
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• 2003

The effect of local forcing on the separated flow over a backward-facing step is investigated through hot-wire measurements and flow visualization with multi-smoke wires. The boundary layer upstream of the separation point is laminar and the Reynolds number based on the free stream velocity and the step height is 13800. The local forcing is given from a slit located at the step edge and the forcing signal is always defined when the wind tunnel is in operation. In case of single frequency forcing, the streamwise velocity and the reattachment length are measured under forcing with various forcing frequencies. For the range of 0.010〈S $t_{\theta}$〈0.013, the forcing frequency component of the streamwise velocity fluctuation grows exponentially and is saturated at x/h = 0.75 , while its subharmonic component grows following the fundamental and is saturated at x/h = 2.0. However, the saturated value of the subharmonic is much lower than that of the fundamental. It is observed that the vortex formation is inhibited by the forcing at S $t_{\theta}$ = 0.019 . For double frequency forcing, natural instability frequency is adopted as a fundamental frequency and its subharmonic is superposed on it. The fundamental frequency component of the streamwise velocity grows exponentially and is saturated at 0.5 < x/ｈ < 0.75, while its subharmonic component grows following the fundamental and is saturated at x/ｈ= 1.5 . Furthermore, the saturated value of the subharmonic component is much higher than that for the single frequency forcing and is nearly the same or higher than that of the fundamental. It is observed that the subharmonic component does not grow for the narrow range of the initial phase difference. This means that there is a range of the initial phase difference where the vortex parring cannot be enhanced or amplified by double frequency forcing. In addition, this effect of the initial phase difference on the development of the shear layer and the distribution of the reattachment length shows a similar trend. From these observations, it can be inferred that the development of the shear layer and the reattachment length are closely related to the vortex paring.