• 한국진공학회:학술대회논문집
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• 한국진공학회 1999년도 제17회 학술발표회 논문개요집
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• pp.110-110
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• 1999

Polyvinylidenefluoride (PVDF) is most used in piezoelectric polymer industry. Electrode effect on the electrical properties of PVDF has been investigated. al has been used due to fair adhesion for PVDF. Work function of metal plays an important role on the electrical properties of ferroelectrics for top and /or bottom electrode. However, Al has much lower work function than Pt or Au and so leakage current of Al/PVDF/Al may be large. Pt or Au has not been used for electrode of PVDF system due to poor adhesion. PVDF irradiated by Ar+ ion beam with O2 environment takes good adhesion to inert metal. Contact angle of PVDF to triple distilled water was reduced from 75$^{\circ}$ to 31$^{\circ}$ at 1$\times$1015 Ar+/cm2. Working pressure was 2.3$\times$10-4 Torr and base pressure was 5$\times$10-6 Torr. Pt was deposited by ion beam sputtering and thickness of pt film was about 1000$\AA$. in previous study, enhancing adhesion of Pt on PVDF was shown. in this study, effect of electrode on PVDF will be represented.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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• pp.690-693
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• 2002

This paper is concerned on method of simultaneous force(stress) and temperature sensing with PVDF film. PVDF film has piezoelectric and pyroelectric properties. Therefore, it senses changes of stress and temperature. But it's output is affected with two properties. Using different medium in a sensing element, this problem is solved. Two structures induce different equations that its solutions are changes of stress and temperature. This method and result is applicable in skin sensor that has complexity of material and structure.

• 한국진공학회지
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• 제8권3A호
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• pp.194-200
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• 1999

In this paper studied was the piezoelectric properties of the $\beta$-PVDF organic thin films prepared by physical vapour deposition method. The molecular orientation of organic thin films was controlled by the application of an electric field and variation of substrate temperature during the evaporation process. Optimum conditions of manufacturing $\beta$-PVDF organic thin film by physical vapor deposition method is to keep at the substrate temperature of $80^{\circ}C$, at the applied electric field of 142.8 kV/cm. The voltage output coefficient increased from 1.39 to 7.04V increasing the force moment.

• E2M - 전기 전자와 첨단 소재
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• 제2권2호
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• pp.127-136
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• 1989

PVDF 필름의 압전성과 결정구조와의 관계를 조사하기 위하여 X선 회절과 압전계수를 측정하였다. 코로나 분극처리된 PVDF의 압전계수는 분극전압에 비례하여 증가하고 결정구조도 .alpha.형, 극성.alpha.형, .betha.형의 순으로 변화하였다. 이와같은 결과로부터 PVDF의 압전특성은 결정영역내의 쌍극자 배향에 의한 결정구조변화에 기인됨을 알 수 있었다.

• International journal of advanced smart convergence
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• 제2권2호
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• pp.16-18
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• 2013

In this paper, we develop a method to design a flexible thin film audio systems utilizing Polyvinylidene fluoride. The system we designed showed the properties of increased transparency and sound pressure levels. As an input terminal transparent oxide thin film is adopted. In order to provide dielectric insulation, a transparent insulating oxide thin film is coated to obtain double -layered structure. In the range of visible light, the output from the output of the system showed an increased and improved sound pressure level. The piezoelectric polymer film of polyvinylidene fluoride (PVDF) is used to produce mechanical vibration due to the applied electrical voltage signal. An analog electric voltage signal is transformed into sound waves in the audio system.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2001년도 학술대회 논문집 전문대학교육위원
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• pp.35-39
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• 2001

The purpose of this paper is improvement the piezoelectric of Polyvinylidene fluoride(PVDF) organic thin films is fabricated by vapor deposition method. The piezoelectric of PVDF organic thin films attributed to dipole orientation in crystalline region. Also, the piezoelectric characteristic reduced that dipole moments orientation in crystalline region interfered with impurity carriers. Therefore, PVDF organic thin films fabricated with high substrate temperature condition for crystallinity improvement. The crystallinity of PVDF organic thin films fabricated by this condition increase from 47 to 67.8%. The ion density of PVDF organic thin films fabricated by substrate temperature variation from $30^{\circ}C$ to $105^{\circ}C$ decreased from $1.62{\times}10^{16}cm^3$ to $6.75{\times}10^{11}cm^3$ when temperature and frequency were $100^{\circ}C$, 10Hz, respectively. The $d_{33}$ and piezo-voltage coefficient of PVDF organic thin films increased from 20pPC/N to 33pC/N and $162.9{\times}10^{-3}V{\cdot}m/N$ to $283.2{\times}10^{-3}V{\cdot}m/N$, respectively. For the sake of the applications of piezoelectric sensor, we analyzed the output voltage characteristic as a function of the distance between an oscillator of 28kHz and PVDF organic thin film transducer. From this, we found that the output voltage is inversely proportional to the distance. At this time, the period was about $35.798{\mu}s$ and equal the oscillator frequency.

• Composites Research
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• 제15권5호
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• pp.7-13
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• 2002

압전필름센서는 복합재 구조물의 저속충격응답을 관측하기에 우수한 특성을 지니고 있다. 본 연구에서는 Gr/Ep 복합재 적층판이 손상이 발생할 수 있을 정도의 충격에너지를 받았을 때 압전필름센서 신호를 이용하여 충격거동을 모니터링할 수 있는 가능성에 대하여 고찰하였다. 손상이 발생하지 않는 저에너지 충격조건부터 국부적인 손상을 유발할 수 있는 충격조건까지 압전필름센서가 부착된 Gr/Ep 복합재 적층판에 대하여 16가지의 저속충격시험을 수행하였다. 세 가지 조거의 충격시험에서 기지균열 및 층간분리 등의 국부적인 손상이 발생하였으나, 충격력과, 변위, 변형률, 압전센서 신호와의 관계를 이용한 선형해석 모델을 사용하여 충격하중에 의한 복합재 적층판의 응답을 예측하는 정방향 문제와 압전센서 신호로부터 충격력을 복원하는 역방향 문제에서 시험과 해석 결과는 비교적 잘 일치하는 경향을 보였다. 복원된 충격력으로부터 국부적인 손상이 발생할 정도의 충격까지는 압전필름센서 신호를 이용하여 충격력을 정확히 복원할 수 있음을 확인하였다.

• 한국전기전자재료학회논문지
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• 제24권5호
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• pp.422-426
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• 2011

Piezoelectric materials can be used to convert mechanical energy into electrical energy. In this study, we investigated the possibility of harvesting from mechanical vibration force using a high efficient piezoelectric material-polyvinylidene fluoride (PVDF). A piezoelectric energy harvesting system consists of rectifier, filter capacitor, resistance. The experiments were carried out with impacting force to PVDF film with the thickness of 1 ${\mu}m$. The output power was measured with change in the load resistance value from 100 ${\Omega}$ to 2.2 $M{\Omega}$. The highest power was obtained under optimization by selection of suitable resistive load and capacitance. A power of 0.3082 ${\mu}W/mm^2$ was generated at the external vibration force of 5 N (10 Hz) across a 1 $M{\Omega}$ optimal resistor. Also, the maximum power of 0.345 ${\mu}W/mm^2$ was generated at 22 ${\mu}F$ and 1 $M{\Omega}$. The developed system was expected at a solution to overcome the critical problem of making up small size energy harvester.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2003년도 춘계학술발표대회 논문집
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• pp.125-128
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• 2003

Low-velocity impact damage is a major concern in the design of structures made of composite materials, because impact damage is hidden inside and cannot be detected by visual inspection. The piezoelectric thin film sensor can be used to detect variations in structural and material properties for structural health monitoring. In this paper, the PVDF and PZT sensors were used for monitoring impact damage initiation in Gr/Ep composite panel to illustrate this potential benefit. A series of impact test at various impact energy by changing impact mass and height is performed on the instrumented drop weight impact tester. The wavelet transform(WT) is used to decompose the piezoelectric sensor signals in this study. Test results show that the particular waveform of sensor signals implying the damage initiation and development are detected above the damage initiation impact energy. And it is found that both PZT and PVDF sensors can be used to detect the impact damage.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2003년도 추계학술발표대회 논문집
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• pp.158-162
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• 2003

The PVDF(polyvinylidene fluoride) film sensor as one of smart sensors has good characteristics to detect the impact damages of composite structures. The capabilities of the PVDF film sensor for evaluating impact behaviors and damages of Gr/Ep laminates subjected to low-velocity impact were examined. From sensor signals, the specific wave-forms implying the damage were detected. The wavelet transform(WT) and Short Time Fourier Transform(STFT) were used to decompose the piezoelectric sensor signals in this study. The impact behaviors of Gr/Ep laminates were simulated and the impact forces were reconstructed using the sensor signals. Finally, the impact damages were predicted by finite element analysis with the reconstructed forces. For experimental verification, a series of low-velocity impact tests from low energy to damage-induced energy were carried-out. The extent of damage in each case was examined by means of ultrasonic C-scan and the measured damage areas were agreed well with the predicted areas by the F.E.A.