• Title/Summary/Keyword: PVD method

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Electrochemical Properties of MnO$_2$electrode for supercapactor wish a Diffuser (Polyvinylalcohol) (분산제 PVA에 따른 수퍼커패시터용 이산화망간전극의 전기 화학적 특성)

  • 이상오;김한주;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.753-756
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    • 2001
  • This research made a study of MnO$_2$electrode for supercapacitor with a diffuser (Polyvinyl alcohol). Manganese dioxide was used as active material. We tried to increase specific surface area by adding PVA. Manganese dioxide was synthesized by a sol-gel method using fumaric acid and oxalic acid in low temperature with high yield. Therefore, We prepared Manganese dioxide powder. This powder was used by active materials. The electrode was made by a mixture of active material, ketjen-black which is a large specific surface area, and PVdF-co-HFP as binder agent with using Nickel mesh as current collector. Here we reported on the synthesis and electrochemical performance of a enhanced material. All active materials have been submitted to X-ray diffraction and Scanning electron microscopy.

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Effect of Coating and Machining Parameters on Surface Finish in Dry Drilling of Aluminium 6061 (Al 6061의 드릴가공에서 공구코팅과 공정변수가 표면정도에 미치는 영향)

  • Choi, Man Sung
    • Journal of the Semiconductor & Display Technology
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    • v.14 no.2
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    • pp.47-52
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    • 2015
  • In this paper, the performance of uncoated- and Titanium nitride aluminium TiAlN-PVD coated- carbide twist drills were investigated when drilling aluminium alloy, Al 6061. This research focuses on the optimization of drilling parameters using the Taguchi technique to obtain minimum surface roughness and thrust force. A number of drilling experiments were conducted using the L9 orthogonal array on a CNC vertical machining center. The experiments were performed on Al 6061 material l blocks using uncoated and coated HSS twist drills under dry cutting conditions. Analysis of variance(ANOVA) was employed to determine the most significant control factors. The main objective is to find the important factors and combination of factors influence the machining process to achieve low surface roughness and low cutting thrust force. From the analysis of the Taguchi method indicates that among the all-significant parameters, feed rate are more significant influence on surface roughness and cutting thrust than spindle speed.

Numerical Analysis of Soil Vapour Extraction Remediation System using Prefabricated Vertical Drain (토목섬유 연직배수재를 활용한 토양증기추출복원시스템의 수치해석)

  • Shin, Eun-Chul;Park, Jeong-Jun;Lee, Kyu-Woong
    • Journal of the Korean Geosynthetics Society
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    • v.7 no.4
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    • pp.1-8
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    • 2008
  • Soil vapor extraction (SVE) is an effective and cost efficient method of removing volatile organic compounds (VOCs) and petroleum hydrocarbons from unsaturated soils. However, soil vapor extraction becomes ineffective in soils with low gas permeability, for example soils with air permeabilities less than 1 Darcy. The aim of this study is to investigate numerically the performance of a prefabricated vertical drain (PVD) as a SVE well, and the pattern of the induced air flow. A validated numerical model for a single PVD extraction well is developed based on the result of a well-designed laboratory model test. The validity of the simple analytical approach to determine air permeability based on the results of model tests is also discussed.

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Study on manufacturing mechanism of functional carbon membrane (기능성 카본막의 제조 Mechanism에 관한 연구)

  • Bae, Sang-Dae
    • The Journal of the Convergence on Culture Technology
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    • v.4 no.2
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    • pp.211-216
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    • 2018
  • Separation technology combining adsorption and membrane is expected to be applied in many fields such as water treatment. In this fusion technique, a functional carbon membrane having a carbon whisker grown on the surface of the membrane was developed to inhibit membrane fouling, which is a problem in the membrane separation process. In this study, to elucidate the mechanism of manufacturing the functional carbon membrane, the membrane was pretreated with the polymer latex of each mixing ratio and the membrane was formed by the CVD (Chemical Vapor Deposition) method. The membrane was analyzed by scanning electron microscope (SEM), CHN analyzer (Elemental Analyzer), and X-ray diffraction (XRD). As a result, the diameter and density of carbon whiskers were higher in case of polyvinyl di-chloride (PVdC): polyvinyl chloride (PVC) = 4.5: 55. It seems possible to control the diameter and density of the carbon whiskers according to the hydrogen content of the polymer latex.

High Quality Nickel Atomic Layer Deposition for Nanoscale Contact Applications

  • Kim, Woo-Hee;Lee, Han-Bo-Ram;Heo, Kwang;Hong, Seung-Hun;Kim, Hyung-Jun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.22.2-22.2
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    • 2009
  • Currently, metal silicides become increasingly more essential part as a contact material in complimentary metal-oxide-semiconductor (CMOS). Among various silicides, NiSi has several advantages such as low resistivity against narrow line width and low Si consumption. Generally, metal silicides are formed through physical vapor deposition (PVD) of metal film, followed by annealing. Nanoscale devices require formation of contact in the inside of deep contact holes, especially for memory device. However, PVD may suffer from poor conformality in deep contact holes. Therefore, Atomic layer deposition (ALD) can be a promising method since it can produce thin films with excellent conformality and atomic scale thickness controllability through the self-saturated surface reaction. In this study, Ni thin films were deposited by thermal ALD using bis(dimethylamino-2-methyl-2-butoxo)nickel [Ni(dmamb)2] as a precursor and NH3 gas as a reactant. The Ni ALD produced pure metallic Ni films with low resistivity of 25 $\mu{\Omega}cm$. In addition, it showed the excellent conformality in nanoscale contact holes as well as on Si nanowires. Meanwhile, the Ni ALD was applied to area-selective ALD using octadecyltrichlorosilane (OTS) self-assembled monolayer as a blocking layer. Due to the differences of the nucleation on OTS modified surfaces toward ALD reaction, ALD Ni films were selectively deposited on un-coated OTS region, producing 3 ${\mu}m$-width Ni line patterns without expensive patterning process.

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The electrochemical properties of PVD-grown WC-( $Ti_{1-x}$A $I_{x}$)N multiplayer films in a 3.5% NaCl solution

  • Ahn, S.H.;Yoo, J.H.;Kim, J.G.;Lee, H.Y.;Han, J.G.
    • Journal of the Korean institute of surface engineering
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    • v.34 no.5
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    • pp.435-444
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    • 2001
  • WC-( $Ti_{1-x}$ A $l_{x}$) N coatings of constant changing Al concentration were deposited on S45C substrates by high-ionization sputtered PVD method. The Al concentration could be controlled by using evaporation source for Al and fixing the evaporation rate of the metals (i.e, WC- $Ti_{0.86}$A $l_{0.14}$N, WC- $Ti_{0.72}$A $l_{0.28}$N, and WC- $Ti_{0.58}$A $l_{0.42}$N). The corrosion behavior of WC-( $Ti_{1-x}$ A $l_{x}$)N coatings in a deaerated 3.5% NaCl solution was investigated by electrochemical corrosion tests and surface analyses. The measured galvanic corrosion currents between coating and substrate indicated that WC- $Ti_{0.72}$A $l_{0.28}$N coating showed the best resistance of the coating tested. The results of potentiodynamic polarization tests showed that the WC- $Ti_{0.72}$A $l_{0.28}$N coating deposited with 32W/c $m^2$ of Al target revealed higher corrosion resistance. This indicated that the WC- $Ti_{0.72}$A $l_{0.28}$N coating is effective in improving corrosion resistance. In EIS, the WC- $Ti_{0.72}$A $l_{0.28}$N coating showed one time constant loop and increased a polarization resistance of coating ( $R_{coat}$) relative to other samples. Compositional variations of WC-( $Ti_{1-x}$ A $l_{x}$)N coatings were analyzed by EDS and XRD analysis was performed to evaluate the crystal structure and compounds formation behavior. Surface morphologies of the films were observed using SEM and AFM. Scratch test was performed to measure film adhesion strength.strength. adhesion strength.strength.

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A Study on the preparation of optimum piezoelectric organic thin films of PVD method and switch characteristic (진공증착법을 이용한 최적의 압전성 유기박막의 제조와 스위치 특성에 관한 연구)

  • 박수홍;이선우;이희규
    • Journal of the Korean Vacuum Society
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    • v.8 no.3A
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    • pp.194-200
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    • 1999
  • In this paper studied was the piezoelectric properties of the $\beta$-PVDF organic thin films prepared by physical vapour deposition method. The molecular orientation of organic thin films was controlled by the application of an electric field and variation of substrate temperature during the evaporation process. Optimum conditions of manufacturing $\beta$-PVDF organic thin film by physical vapor deposition method is to keep at the substrate temperature of $80^{\circ}C$, at the applied electric field of 142.8 kV/cm. The voltage output coefficient increased from 1.39 to 7.04V increasing the force moment.

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The study of X-ray detection characteristic and fabrication photoconductor film thickness for Screen printing method (Screen printing method로 제작된 의료용 광도전체 필름의 Tickness의 따른 X선 검출 특성 평가)

  • Lee, Y.K.;Yon, M.S.;KIM, D.H.;Chun, S.L.;Jung, B.D.;Gang, Sang-Sik;Park, J.G.;Mun, C.W.;Nam, S.H.
    • Journal of the Korean Society of Radiology
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    • v.3 no.2
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    • pp.11-16
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    • 2009
  • Mercury Iodide as good sensitivity at radiation and has an easy peculiarity that operates at low voltage for other photoconductors(a-Se, a-Si, Ge, etc) Based on this characteristic, we studied about an efficiency of the digital x-ray detector in acccordance with the thickness of photoconductor. To solve the problem that is difficult to make a large area film using PVD(Physical Vapor Deposition)method, we used a PIB(Particle In Binder)method. To make a binder paste, we used a PVB(Polyvinylbutyral) as a binder and a DGME(Diethylene Glycol Monobutyl Ether), DGMEA(Diethylene Glycol Monobutyl Ether Acetate) as a solvent. Using this binder paste, we made a polycrystal mercury iodide film that has an each thickness. To evaluate the electrical properties of this films, we measured a darkcurrent, sensitivity and SNR(Signal to Noise Ratio). Mercury iodide film of the 200um thickness has good electrical properties as a result of the measurement. From this result there is a good chance that replace the existing a-Se(Amnorphous seleinum; a-se) with the mercury iodide.

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Experimental investigation of lateral displacement of PVD-improved deposit

  • Chai, Jin-Chun;Xu, Fang
    • Geomechanics and Engineering
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    • v.9 no.5
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    • pp.585-599
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    • 2015
  • Laboratory model tests were conducted to investigate the effect of surcharge loading rate on the magnitude of lateral displacement of prefabricated vertical drains (PVDs) improved deposit. The test results indicate that under the condition that the system had sufficient factor of safety (FS) ($FS{\geq}1.2$), for the similar model ground under the same total applied surcharge load, the lateral displacement increases with the increase of loading rate. The test results have been used to check the validity of a previously proposed method for predicting the maximum lateral displacement, and it shows that the data points are around the middle line of the predicted range, which supports the usefulness of the proposed method. The basic idea of the prediction method is an empirical relationship between the normalized lateral displacement (NLD) and a ration of load to the undrained shear strength of the deposit (RLS). The model test results offer some modifications of the NLD-RLS relationship: (1) instead of a bilinear relationship, NLD-RLS relationship may be entirely nonlinear; (2) the upper bound value of RLS for the proposed method can be used may be limited to 2.1 instead of the originally proposed value of 3.0.

Fabrication and Characterization of Porous Carbon Electrode for Electrosorption (전기흡착용 다공성 탄소전극의 제조 및 특성 분석)

  • Park, Nam-Soo;Choi, Jae-Hwan
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.4
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    • pp.409-414
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    • 2008
  • Porous carbon electrode for electrosorption was prepared by a wet phase inversion method. Carbon slurry that was a mixture of activated carbon powder(ACP) and PVdF solution was cast directly upon a graphite sheet by means of a casting knife. Porous carbon electrodes were fabricated by immersing the cast film in pure water as a non solvent. Physical and electrochemical properties of carbon electrodes prepared with various ACP contents(50.0, 75.0, 83.3, 87.5, 90.0 wt %). From the SEM images we can verify that the electrode was porous. The average pore sizes determined for the electrodes fabricated with various ACP contents ranged from 72.7 to 86.4 nm and the size decreased as the ACP content increased. The electrochemical properties were characterized by cyclic voltammetry(CV) method. All of the voltammograms showed typical behavior of an electric double layer charging/discharging on the carbon surface. The capacitance increased with the ACP content and the values ranged from 2.18 F/cm$^2$ for 50 wt% ACP to 4.77 F/cm$^2$ for 90 wt% ACP.