• Title/Summary/Keyword: PVB film

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Photooxidation of Poly(vinyl butyral) Films by UV/Ozone Irradiation (자외선/오존 조사에 의한 Poly(vinyl butyral)의 광산화)

  • Joo, Jin-Woo;Jang, Jinho
    • Textile Coloration and Finishing
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    • v.27 no.2
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    • pp.113-118
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    • 2015
  • Poly(vinyl butyral), PVB was photooxidized by UV/ozone irradiation and the effect of UV energy on the surface properties of the UV-irradiated PVB film were investigated by the measurement of reflectance, surface roughness, contact angles, elemental composition, and zeta potential. With increasing UV energy, reflectance decreased in the visible and ultraviolet regions particularly at the wavelength of 400nm. The irradiation produced nano-scale surface roughness including the maximum peak-to-valley roughness increased from 274nm for the unirradiated PVB to 370nm at the UV energy of $5.3J/cm^2$. The improved hydrophilicity was due to the higher $O_{1s}/C_{1s}$ resulting from the introduction of polar groups such as C=O bonds. The surface energy of the PVB film increased from $35.3mJ/m^2$ to $39.3mJ/m^2$ at the irradiation of $15.9J/cm^2$. While the zeta potentials decreased proportionally with increasing UV energy, the cationic dyeability of the PVB increased accordingly resulting from the improved affinity of the irradiated PVB surfaces containing the photochemically introduced anionic and dipolar dyeing sites.

Analysis of the Polymer Properties and Sound Characteristics of Interlayer Films for Laminated Glass (접합유리용 고분자 필름의 물성 및 음향학적 특성 분석)

  • Ko, Sangwon;Hong, Jiyoung;Sunwoo, Yerim;Kim, Young Jun
    • Journal of the Korean Society for Railway
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    • v.19 no.1
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    • pp.1-10
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    • 2016
  • To improve the sound insulation performance of laminated glass in high speed trains, it is beneficial to study the relationship between the characteristics of interlayer films and the acoustical performance. In addition to those of conventional PVB (polyvinyl butyral), the dynamic mechanical properties of PVB derivatives and PC (polycarbonate), which are candidates for interlayer films, were analyzed. We assumed that PVB-HEMU, which has a glass transition temperature ($T_g$) around room temperature and a large tan ${\delta}$ (loss tangent) value, can be made to damp efficiently. The damping capability was tested utilizing sound transmission loss measurement and simulation under the identical structure of laminated glass in high speed trains. We also built a database for analysis of relations between interlayer film characteristics and acoustical performance; this was followed by the determination of sound transmission loss using the intensity technique and FEA.

Development of the Functional Films Coated with Nano-TiO2 Particles for Food Packaging and Removal of Off-flavor from Soybean Sprouts (나노 TiO2를 적용한 식품 포장 필름 개발 및 콩나물의 이취 제거)

  • Choi, Yeonwook;Jeon, Kyu Bae;Song, Kihyeon;Kim, Jai Neung
    • Korean Journal of Food Science and Technology
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    • v.47 no.6
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    • pp.733-737
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    • 2015
  • For testing the ultraviolet (UV)-blocking property of functional films coated with Nano-$TiO_2$ particles, UV-Vis spectra of oriented polypropylene (OPP) films uncoated and coated with $TiO_2$ of 3% and 5% in Polyurethane (PU) and polyvinyl butyral (PVB)-Cellulose binders were measured. The result of UV-Vis analyses showed that the film coated with 5% $TiO_2$ in PVB binders had a significant effect on UV protection of 90% compared with the film uncoated. Also The result of The photodegradation of methylene blue (MB), OPP films coated with 5% in both PU and PVB binders had a high photocatalytic activity for MB degradation. To evaluate the effect of the developed functional film coated with Nano-$TiO_2$ particles, fresh soybean sprouts were used. Nano-$TiO_2$ coated film was observed to decompose the off-flavor produced by soybean sprouts within packages during distribution, but uncoated film did not. Therefore, Nano-$TiO_2$ coated film package could give the greatest effect in extending the shelf life of soybean sprouts.

The analysis on PVB film optical characteristics for PV module generating in high-temperature (고온용 PV module을 위한 PVB film 광특성 연구)

  • Lee, Sang-Hun;Kim, Kyung-Soo;Kang, Gi-Hwan;Yu, Gwon-Jong;Ahn, Hyung-Keun;Han, Deuk-Young
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1320-1321
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    • 2011
  • According to the advance that solar power plants go into the desert, power plants are getting greater capacity. The desert is unspoiled resources and it is well suited to build a solar power plant, because of abundant solar radiation and long sunshine duration. but existing PV modules have several weaknesses and don't generate lower the rated power, because it wasn't designed to produce in extreme environments like a desert climate. The one of the weaknesses of PV modules is that the characteristics of the temperature of the Encapsulants(EVA sheet) are not good in a desert climate, because the EVA sheet is melt at high temperature. In this study, a decrease phenomenon of the transmittance depending on the melting point of the Encapsulant(PV module using EVA sheet : $75^{\circ}C$ PV module using PVB film : $110^{\circ}C$) is suggested, it would be the one of the important factors to achieve rated output of the PV modules in high temperature climate regions.

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A Comparative Study on the Sound Insulation Characteristics of Laminated Glass in Accordance with Material and Composition of Interlayer Film (Interlayer film 재료 및 구성에 따른 접합유리 차음성능 비교)

  • Hong, Jiyoung;Ko, Sangwon;Koh, Hyo-In;Jang, Seungho
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2013.10a
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    • pp.501-505
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    • 2013
  • It is well known that monolithic glass has specific coincidence dip allowing transmittance of noise around the critical frequency. Laminated glass, made of a polyvinyle butyral(PVB) interlayer sandwiched by two panes of glass sheet, has long served for the advantage in noise attenuation properties as well as the safety purpose. More research on the improvement of sound insulation performance is needed, considering much of the noise is still transmitted through the glass. As a preliminary study, authors have made several test specimens, varied combinations of glass and interlayer film, to optimize the acoustic performance. Experimental investigation was carried out to study the sound transmission loss of test specimens in the reverberation chamber by using sound intensity method. Several new applications, instead of the existing PVB laminated glass, show better results in sound transmission loss and low temperature have a bad influence on the acoustic performance.

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A Study on Glass/Mo/ZnO/Glass Thin-film-heaters for Water Heating (수중 발열을 위한 Glass/Mo/ZnO/Glass 구조의 박막형 발열체 연구)

  • Kim, Jiwoo;Choi, Dooho
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.1
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    • pp.43-47
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    • 2022
  • In this study, we demonstrated an eco-friendly thin-metallic-film-based heater which can be operated in water. Based on the materials stability, Mo was selected as the heating element to secure long-term stability. Using a magnetron sputtering, 40 nm-thick Mo layers were deposited onto a glass substrate, followed by the deposition of 60-nm-thick ZnO layer to prevent oxidation during the heater fabrication process. Then, PVB (Polyvinyl Butyral) was applied on top of ZnO layer and an additional glass substrate was placed, which were heated at 150℃ for 2 hr. The PVB was cured with strong adhesion by the processing condition. We operated the Glass/Mo/ZnO/Glass heater in water, and it was shown that the water temperature reached 50℃ within 2 minutes, with a minimal resistance change of the heater. Finally, the heaters exhibit a semi-transparency, and this aesthetic advantage is expected to contribute to the added value of the heater.

Preparation of reflexite collimating film (RCF) by ink-jet technique with organic-inorganic hybrid precursor

  • Hu, Yi;Liu, Jiun-Shing;Lyu, Jhong-Ming;Liu, Tung-Cheng
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1459-1461
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    • 2009
  • In this study, we prepared the multi-refraction film thin by ink-jet technique with sol-gel precursor. The precursors were prepared by using some transition metal alk-oxide and the tetraethylorthosilicate (TEOS) mixed separately with n-Butyl Alcohol and PVB (Poly(vinyl butyral)).The structure and morphology of the resulting films were investigated by atomic force microscope (AFM). It is shown that the shape of the pattern of the films would affect the refraction proportion.

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The study of X-ray detection characteristic and fabrication photoconductor film thickness for Screen printing method (Screen printing method로 제작된 의료용 광도전체 필름의 Tickness의 따른 X선 검출 특성 평가)

  • Lee, Y.K.;Yon, M.S.;KIM, D.H.;Chun, S.L.;Jung, B.D.;Gang, Sang-Sik;Park, J.G.;Mun, C.W.;Nam, S.H.
    • Journal of the Korean Society of Radiology
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    • v.3 no.2
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    • pp.11-16
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    • 2009
  • Mercury Iodide as good sensitivity at radiation and has an easy peculiarity that operates at low voltage for other photoconductors(a-Se, a-Si, Ge, etc) Based on this characteristic, we studied about an efficiency of the digital x-ray detector in acccordance with the thickness of photoconductor. To solve the problem that is difficult to make a large area film using PVD(Physical Vapor Deposition)method, we used a PIB(Particle In Binder)method. To make a binder paste, we used a PVB(Polyvinylbutyral) as a binder and a DGME(Diethylene Glycol Monobutyl Ether), DGMEA(Diethylene Glycol Monobutyl Ether Acetate) as a solvent. Using this binder paste, we made a polycrystal mercury iodide film that has an each thickness. To evaluate the electrical properties of this films, we measured a darkcurrent, sensitivity and SNR(Signal to Noise Ratio). Mercury iodide film of the 200um thickness has good electrical properties as a result of the measurement. From this result there is a good chance that replace the existing a-Se(Amnorphous seleinum; a-se) with the mercury iodide.

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The electrical properties study with specific of phase transition of Lead Monoxide by PIB(Particle In Binder) (PIB(Particle In Binder) 방법으로 제조된 산화납의 특이상전이에 따른 전기적 특성 평가)

  • Kim, Sung-Hyun;Kim, Young-Bin;Jung, Suk-Hee;Kim, Min-Woo;Oh, Kyung-Min;Park, Ji-Gun
    • Journal of the Korean Society of Radiology
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    • v.2 no.3
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    • pp.19-25
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    • 2008
  • Commercial analog x-ray detectors based on film cassettes have been showing problems such as with image storage and image transmission. Recently direct conversion material, photoconductor whit flat panel have been researched which generate the electron hole-pair (EHP). In this paper, we researched the electrical properties of the PbO and Lead(II) oxide PbO. film which fabricated by Particle-In-Binder(PIB) method. We compared tetragonal ${\alpha}$-PbO with orthorhombic ${\beta}$-PbO physical property. Tetragonal material was more than orthorhombic material in other paper. The solution was Poly Vinyl Butyral(PVB) in the PIB. We discussed about the sample of x-ray sensitivity, leakage current, Signal to Noise Rate and investigated SEM for the physical property of sample. We need to think more research ${\alpha}$-PbO material fabrication.

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Experimental Study and Finite Element Analysis about Vehicle Laminated Glass Subject to Headform Impact (머리모형 충돌에 의한 자동차 접합유리의 실험적 연구 및 유한요소해석)

  • Choi, Jihun;Oh, Wontek;Kim, Jonghyuk;Park, Jongchan
    • Transactions of the Korean Society of Automotive Engineers
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    • v.25 no.3
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    • pp.374-379
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    • 2017
  • In vehicle to pedestrian accidents, cracks occur in the vehicle laminated glass due to impact of a pedestrian's head. In this study, FMH(Free Motion Headform) was used to experiment on and analyze the crack patterns on a vehicle laminated glass that collides with an adult headform at speeds of 20 km/h, 30 km/h, and 40 km/h, respectively. Applying the acquired experimental data and material property of the vehicle laminated glass to the structural analysis program LS-Dyna, we could develop the FE model of vehicle laminated glass similar to real vehicle laminated glass. We could estimate the head impact velocity and pedestrian's vehicle impact velocity using the Madymo program.