• 한국염색가공학회:학술대회논문집
• /
• 한국염색가공학회 2003년도 춘계학술대회 논문집
• /
• pp.192-196
• /
• 2003

폴리비닐알코올[poly(vinyl alcohol)(PVA)]은 1924년에 Herrmann과 Haehnel이 폴리아세트산비닐[(poly(vinyl acetate)(PVAc)]의 비누화 도중 처음 합성되었으며, 2차 세계대전 이후 일본에서 비닐론 섬유용 수지로 상업화되기 시작했다. PVAc의 비누화로부터 제조되는 PVA는 흰색의 분말상 고분자로 필름 및 섬유의 형성이 용이하고 표면 활성도가 높으며, 기계적 성질 및 접착 강도가 높고, 용해도와 화학적 반응성이 우수하다. (중략)

• 한국섬유공학회:학술대회논문집
• /
• 한국섬유공학회 2003년도 가을 학술발표회 논문집
• /
• pp.181-182
• /
• 2003

Poly(vinyl alcohol) (PVA) is a semicrystalline polymer whose hydroxyl groups produce inter-and intramolecular hydrogen bonding. The extent of hydrogen bonding is greatly affected by stereoregularity of hydroxyl groups, so-called tacticity, of PVA[1-3]. Hydrogen bonding has a profound effect on the rheological and mechanical properties of the polymer, which is largely determined by the density and spatial arrangement of hydroxyl groups. (omitted)

• 한국섬유공학회:학술대회논문집
• /
• 한국섬유공학회 2001년도 가을 학술발표회 논문집
• /
• pp.187-190
• /
• 2001

The poly(vinyl alcohol) (PVA) fiber is recognized as the best candidate because of its good machanical properties together with excellent resistance to alkalis[1-5]. PVA cannot be prepared by the direct polymerization due to tautomerism of vinyl alcohol monomer. Thus PVA is obtained by the saponification of poly(vinyl ester) like poly(vinyl acetate) (PVAc). (omitted)

• 한국건축시공학회지
• /
• 제15권4호
• /
• pp.383-389
• /
• 2015

ALC 블록(0.6품) 성능 수준의 습식형 경량 기포콘크리트 배합설계 제시를 위하여 7배합의 섬유가 혼입된 기포콘크리트 배합실험을 수행하였다. 수화열에 의한 온도균열제어를 위해 결합재에 고로슬래그를 30% 치환하였으며, 기포콘크리트의 균열저항성을 높이기 위하여 PVA 및 PA섬유를 혼입하였다. 고로슬래그를 30% 치환한 결합재는 시멘트 100% 대비 최대 열발생률 및 콘크리트 내부 최고 온도를 각각 28% 및 9% 저감시킬 수 있었다. 실험결과 섬유가 혼입된 경량기포 콘크리트의 압축강도, 공극분포, 휨 강도를 고려하면 PVA 및 PA 섬유 $0.6kg/m^3$ 혼입이 추천될 수 있었다.

• 한국섬유공학회:학술대회논문집
• /
• 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
• /
• pp.61-62
• /
• 2003

To identify the effect of critical molecular parameters of poly(vinyl alcohol) (PVA) such as syndiotacticity, degree of saponification, and molecular weight on the change of morphology, we prepared various PVAs. Also, the structures of these PVA were investigated.

• 한국섬유공학회:학술대회논문집
• /
• 한국섬유공학회 2007년도 학술발표회 논문집
• /
• pp.181-182
• /
• 2007

• 한국섬유공학회:학술대회논문집
• /
• 한국섬유공학회 2003년도 가을 학술발표회 논문집
• /
• pp.104-107
• /
• 2003

Poly(vinyl alcohol) (PVA) obtained by the saponification of poly(vinyl ester) like poly(vinyl acetate) o. poly(vinyl pivalate) is a linear semicrystalline polymer, which has been widely used as fibers for clothes and industries, films, membranes, medicines for drug delivery system, and cancer cell-killing embolic materials[1-3]. PVA fibers and films have high tensile and compressive strengths, high tensile modulus, and good abrasion resistance due to its highest crystalline lattice modulus. (omitted)

• 한국섬유공학회:학술대회논문집
• /
• 한국섬유공학회 2003년도 가을 학술발표회 논문집
• /
• pp.46-48
• /
• 2003

Poly(vinyl alcohol) (PVA) obtained from PVPi has the highest syndiotacticity among (PVA)s obtained via radical polymerization, and the s-diad content of PVA prepared by low temperature polymerization of vinyl pivalate (VPi)[1-5] comes to eve. 60%, Therefore, we an obtain (PVA)s with various tacticities through the copolymerization of vinyl acetate (VAc) and VPi and can examine the relation between physical properties of (PVA)s and their tacticities. (omitted)

• 한국섬유공학회:학술대회논문집
• /
• 한국섬유공학회 2001년도 가을 학술발표회 논문집
• /
• pp.324-325
• /
• 2001

Poly(vinyl alcohol) (PVA) is useful for biomaterials such as contact lens, drug delivery system, and biological tissues, because of good biocompatibility and no toxicity. Particularly, hydrogels have unique position in biomaterial fields because of their high water contents.[1-2] Because atactic PVA (a-PVA) is very weak in water, a-PVA need to be chemically crosslinked with crosslinking agent such as glutaradehyde to prepare PVA hydrogels with high water-resistance and good physical properties.[3] (omitted)

• 복합신소재구조학회 논문집
• /
• 제6권4호
• /
• pp.58-63
• /
• 2015

The purpose of this experimental research is to evaluate the workability and strength properties of hybrid fiber reinforced concrete containing amorphous steel fiber and organic fiber. For this purpose, the hybrid fiber reinforced concrete containing amorphous steel fiber(ASF) with polyamide(PA) and polyvinyl alcohol(PVA) fiber, respectively were made according to their total volume fraction of 0.5% for water-binder ratio of 33%, and then the characteristics such as the workability, compressive strength, and flexural strength of those were investigated. It was observed from the test results that the workability and compressive strength at 7 and 28 days were decreased and the flexural strength at 7 and 28 days was increased with increasing ASF and decreasing organic fiber.