• Title/Summary/Keyword: PU

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Recycling of PC/ABS Blend Used in Instrument Panel of Automotive (자동차 Instrument Panel에 사용된 PC/ABS계의 재활용)

  • Lee, Chang Hyung;Jung, In Kwon;Lee, Yong Moo;Oak, Sung Hyun;Choi, Hyeong Ki
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.118-123
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    • 1999
  • The recycle of the polycarbonate(PC)/acrylonitrile-butadiene-styrene(ABS) separated from the instrument panel (In-Panel) of the automotive was investigated. The small amount of polyurethane(PU) foam contained in the separated PC/ABS decreased the mechanical properties of the recycled PC/ABS. However, it is found that the PU foam formed the dispered phase of small particles at high temperature ($260^{\circ}C$) under high shear of the twin extruder, whereas it formed the big particles at low extrusion temperature ($220^{\circ}C$). The mechanical properties of the recycled PC/ABS extruded at high temperature was better than those at low temperature, which enabled the recycled PC/ABS seperated from In-Panel to be applied to the radiator grille without the addition of the compatibilizers or virgin PC/ABS. This was ascribed to the smaller particle sizes of the PU foam formed at high extrusion temperature under high shear.

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Study on the Separation of MAs from HLLW and Their Extraction Behavior Using New Extractants of Amido Podand

  • An, Ye-Guo;Luo, Fang-Xiang;Zhu, Zhi-Xuan;Zhang, Xiang-Ye;Zhu, Wen-Bin
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.02a
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    • pp.245-256
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    • 2004
  • The extraction of three kinds of amido podands, N,N,N'N'-tetrabutyl-3-oxa-pentanedi- amide (TBDGA), N,N,N'N'-tetra-isobutyl-3-oxa-pentanediamide(TiBDGA) and N,N,N'N'-tetra- butyl-3,6-dioxa-oct-anediam- ide(TBDOODA) on U(VI),Pu(IV), Am(III), Eu(III) and other metal ions is studied in nitric acid solutions. 40%octanol-kerosene is chosen as diluents to eliminate third phase and emulsion. TBDGA and TiBDGA show extraction selectivity to An(III) and Ln(III) much higher than to U(VI) and Pu(IV). Fe, Ru and Mo is poorly extracted by the three kinds of amid podands in 2~3mol/L $HNO_3$ solutions. Aiming to eliminate interface crude when using simulated HLLW solution in the system of 0.2mol/L TBDGA/Octanol+kerosene, acetohydroxyamic acid was adapted. Distribution ratio of zirconium was decreased when adding acetohydroxyamic acid in aqueous solution, and interface crude disappeared as mixing extractant with HLLW. The counter-current extraction test is carried out in a set of miniature mixer-settler, with 0.2mol/L TBDGA/ 40% octanol-kerosene as extractant to separate U(VI), Pu(IV), Am(III) and Eu(III) from simulated high level liquid waste(HLLW) solution. In battery A, lanthanides and actinides are coextracted into organic phase with the recovery of 99.98% for U(Ⅵ), >99.99% for Pu(IV), and >99.99% for Am(III) and Eu(III) respectively. In battery R1, 99.99% U, 86.2% Pu and a part of Am or Eu are stripped into aqueous phase by 0.2mol/L acetohydroxyamic acid (AHA) in 0.01mol/L $HNO_3$ solution. In battery $R_2$, Am, Eu and remained Pu are completely back-extracted by 0.2mol/L AHA. This separation process contains no salt reagent, and it is not necessary to dilute HLLW feed.

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A Study on Enhancement of the Durability of Permeable Pavement Material (투수성 도로포장재의 내구성 향상에 관한 연구)

  • Oh, Hun-Su;Hong, Young-Keun
    • Elastomers and Composites
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    • v.42 no.2
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    • pp.93-101
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    • 2007
  • In this study, for enhancing the durability of permeable pavement material polyurethane(PU) adhesives were developed, and the physical properties upon polymerization and additives were studied. PU polymerization followed the bulk polymerization of free solvent type considering ecological aspect. Additives used in this study were carbon black, calcium carbonate and ultra violet stabilizer. The property changes upon different environment were evaluated with the compressive strength which is the principal measurement of the property of pavement materials. Among polymerized PU, one formulated with esterpolyol and crosslinkable chain extender gave the highest compressive strength of $74.9kgf/cm^2$, better than commercial $60kgf/cm^2$. The strength was the highest when the material specimen contained carbon black and calcium carbonate 20 wt%, respectively. However, UV stabilizer did not show good weathering properties.

CNT Buckypaper-Polyurethane Composite with Enhanced Strength, Toughness and Flexible (고강도, 고강성, 그리고 유연한 탄소나노튜브 버키페이퍼-폴리우레탄 나노복합체)

  • Ha, Yu-Mi;Lim, Da-un;Kim, Yoong Ahm;Jung, Yong Chae
    • Composites Research
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    • v.29 no.4
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    • pp.161-166
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    • 2016
  • Carbon nanotube buckypaper (CNTs-BP)/thermoplastic polyurethane (PU) elastomer composites were successfully fabricated. The CNTs-BP/PU nanocomposites exhibited simultaneous improvements in both tensile modulus and strength by 1360 and 430%, respectively, as compared to pure PU. Possible reinforcing mechanisms were evidenced by SEM analyses and tensile tests. The CNTs-BP/PU nanocomposites can be potentially used as an inter-reinforcing agent in ultra-lightweight, high-strength aircraft, carbon-fiber-reinforced plastics, etc.

Overview of the Interaction between Warfarin and Korean Herbal Medicine (와파린과 상호작용하는 한약재에 대한 고찰)

  • Lee, In;Park, Sang-Moo;Park, Seung-Chan;Kim, Do-Hyung;Cho, Min-Kyoung;Han, Chang-Woo;Kwon, Jeong-Nam;Hong, Jin-Woo
    • The Journal of Internal Korean Medicine
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    • v.33 no.2
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    • pp.160-171
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    • 2012
  • Background and Objective : Warfarin is the standard anticoagulation treatment for atrial fibrillation, venous thromboembolism (VTE), and mechanical heart valves. Close monitoring of the International Normalized Ratio (INR) is required due to the drug's very narrow therapeutic window. Many factors can affect INR levels. Drug and food interactions are frequently cited as causes of adverse events with warfarin. We discussed interactions between herbs and warfarin studied in this research. Methods : In this review, PubMed was used to search medical journals. Keywords "warfarin AND interaction" were applied. Results : 55 articles were included. The possibility of correlation between warfarin and single herbal medicines such as Salviae Miltiorrhizae Radix, Angelicae Gigantis Radix, Ginseng Radix Alba, Lycii Fructus, Ginkgo Folium, Menthae Herba, Trigonellae semen was suggested. Furthermore, some herbal compounds interacting with warfarin were reported. The conclusion of studies reporting the effect of herbal medicine on warfarin were controversial due to small size or quality of research. Conculsions : We suggest that we should prescribe therapeutic herbal medicines to patients using warfarin more carefully and do INR follow-up regularly.

A New Hardware Architecture of High-Speed Motion Estimator for H.264 Video CODEC (H.264 비디오 코덱을 위한 고속 움직임 예측기의 하드웨어 구조)

  • Lim, Jeong-Hun;Seo, Young-Ho;Choi, Hyun-Jun;Kim, Dong-Wook
    • Journal of Broadcast Engineering
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    • v.16 no.2
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    • pp.293-304
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    • 2011
  • In this paper, we proposed a new hardware architecture for motion estimation (ME) which is the most time-consuming unit among H.264 algorithms and designed to the type of intellectual property (IP). The proposed ME hardware consists of buffer, processing unit (PU) array, SAD (sum of absolute difference) selector, and motion vector (MVgenerator). PU array is composed of 16 PUs and each PU consists of 16 processing elements (PUs). The main characteristics of the proposed hardware are that current and reference frames are re-used to reduce the number of access to the external memory and that there is no clock loss during SAD operation. The implemented ME hardware occupies 3% hardware resources of StatixIII EP3SE80F1152C2 which is a FPGA of Altera Inc. and can operate at up to 446.43MHz. Therefore it can process up to 50 frames of 1080p in a second.

Transparent Conductive Films Composite with Copper Nanoparticle/Graphene Oxide Fabricated by dip Process and Electrospinning

  • Kim, Jin-Un;Kim, Gyeong-Min;Kim, Yong-Ho;Kim, Su-Yong;Jo, Su-Ji;Lee, Eung-Sang;Seok, Jung-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.382.2-382.2
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    • 2014
  • We explain a method to fabricate multi-layered transparent conductive films (TCF) using graphene oxide (GO), copper powder and polyurethane (PU) solution. The flexible graphene nanosheets (GNSs) serve as nanoscale connection between conductive copper nanoparticles (CuNps) and PU nanofibers, resulting in a highly flexible TCF. To fabricate conductive films with high transmittance, polyurethane (PU) nanofibers were used for a conductive network consisting of CuNps and GNSs (CuNps-GNSs). In this experiment, copper powder and graphene oxides were mixed in deionized water with the ultrasonication for 2 h. NaBH4 solution is used as a reduction agents of CuNps and GNSs (CuNps-GNSs) under a nitrogen atmosphere in the oil bath at 100% for 24 h to mixed. The purified and dispersed CuNp-GNS were obtained in deionized water, and diluted to a 10wt.% based on the contents of GNSs. Polyurethane (PU) nanofibers on a PET substrate were formed by electrospinning method. PET slides coated with the PU nanofibers were immersed into CuNp-GNS solution for several second, rinsed briefly in deionized water, and dried to obtain self-assembled CuNp-GNS/PU films. The morphology of the multi-layered films were characterized with a field emission scanning electron microscope (FE-SEM, Hitachi S-4700) and atomic force microscope (AFM, PSIA XE-100). The electrical property was analysed by the I-V measurement system and the optical property was measured by the UV/VIS spectroscopy.

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DETERMINATION OF THE TRANSURANIC ELEMENTS INVENTORY IN HIGH BURNUP PWR SPENT FUEL SAMPLES BY ALPHA SPECTROMETRY

  • Joe, Kih-Soo;Song, Byung-Chul;Kim, Young-Bok;Han, Sun-Ho;Jeon, Young-Shin;Jung, Euo-Chang;Jee, Kwang-Yong
    • Nuclear Engineering and Technology
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    • v.39 no.5
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    • pp.673-682
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    • 2007
  • The contents of transuranic elements in high-burnup spent fuel samples were determined. The activity amounts of $^{238}Pu,\;^{239}Pu,\;^{240}Pu,\;^{241}Am,\;^{244}Cm\;and\;^{242}Cm$ were measured by alpha spectrometry using $^{242}Pu\;and\;^{243}Am$ as tracers, respectively. A spike addition method for $^{237}Np$ was established by an alpha and gamma spectrometry using $^{239}Np$ as a spike after the optimum conditions for the measurements of $^{237}Np\;and\;^{239}Np$, respectively, were obtained. A separation system using anion exchange chromatography and diethylhexylphosphoric acid extraction chromatography was applied for the separation of these elements. This method was applied to high-burnup spent nuclear fuel samples $(40{\sim}60GWD/MTU)$. The contents of the transuranic elements were compared with those by ORIGEN-2 code. Measurements and the calculations of the contents of the plutonium isotopes $^{238}Pu,\;^{239}Pu\;and\;^{240}Pu$ agreed to within 10% on average. The contents of $^{237}Np$ agreed to within approximately 5% except for one instance of a calculation, while those of $^{241}Am,\;^{244}Cm\;and\;^{242}Cm$ showed higher values by approximately 19%, 35% and 14% on average, respectively, compared to the calculations according to the burnup.

Morphology and Properties of PP/PU Blends Prepared by Compositional Quenching (Compositional Quenching으로 제조한 PP/PU 블렌드의 모폴로지 및 물성)

  • Lim, Gyeong-Taek;Ju, Min-Hyuk;Kim, Do-Heyoung;Song, Ki-Chan;Kim, Su-Kyung
    • Elastomers and Composites
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    • v.36 no.3
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    • pp.177-187
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    • 2001
  • Polypropylene(PP)/polyurethane(PU) blends with reactive compatibilizers were prepared by the compositional quenching process. Maleic anhydride grafted PP(MPP) and hydroxyethyl maleimide grafted PP(HPP) were introduced as reactive compatibilizers. The formation of HPP and the reactions of compatibilizers with the PU components were confirmed by FT-IR spectroscopy. The morphology, tensile properties, thermal stability, and surface property were studied. The blends prepared by the compositional quenching showed better dispersed domain morphology than the melt blends. The PU domain size became more uniform and reduced in size with increasing the amount of compatibilizers. The blends with HPP showed sightly smaller domain sire than the blends with MPP. The blends with compatibilizers all showed improved tensile properties, surface property. and thermal stability due to the interfacial adhesion effect. The blends with MPP showed higher surface energy than the blends with HPP, but the latter showed better thermal stability compared to the former.

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An Effective Multiplication Factor Calculation of Uniform Lattices of $UO_2-PuO_2$ Fueled System ($UO_2-PuO_2$ 노심에서의 유효증배계수계산)

  • Sang Keun Lee;Ji Bok Lee;Chang Saeng Rim;Chang Kun Lee;Chang Hyun Chung
    • Nuclear Engineering and Technology
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    • v.14 no.3
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    • pp.138-147
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    • 1982
  • A theoretical basis for analysis of plutonium-hearing fuel in a thermal nuclear power reactor has been established. The analysis of UO$_2$-PuO$_2$ fueled, light water moderated uniform lattice experiments has been performed. A unit cell program, KARATE, which is based on the theoretical models of GAM and THERMOS with some modifications, has been developed to generate a few-group cross-sections. These cross-sections are subsequently used in the diffusion theory code, KIDD, to compare the calculated values of the effective multiplication factor with the measured. The average value of the effective multiplication factor for 41 selected critical experiments is estimated to be 0.9997 with standard deviation of 0.43%. This illustrates the fact that KARATE/KIDD system can be effectively used for the analysis of uniform lattices of UO$_2$-PuO$_2$fuels.

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