• KEPCO Journal on Electric Power and Energy
• /
• v.7 no.1
• /
• pp.137-143
• /
• 2021

As an electrochemical water electrolysis for green hydrogen production, both polymer electrolyte membrane (PEM) and alkaline electrolyte are being developed extensively in various countries. The PEM electrolyzer with high current density (above 2 A/cm²) has the advantage of being able to design a simple structure. Also, it is known that it has high response to electrical output fluctuations. However, the cost problem of major components is the most important issue that a PEM electrolyzer must overcome. Instantly, there are platinum group metal (PGM)-based electrocatalysts, fluorine-based polyfluoro sulfuric acid (PFSA) membrane, Ti felt (porous transport layer, PTL) and so on. Another challenging issue is productivity. A securing outstanding productivity brings price benefits of the electrolytic cells. From this point of view, we conducted basic studies on manufacturing electrode and membrane electrode assembly (MEA) for PEM electrolyzer production.

• Transactions of the Korean hydrogen and new energy society
• /
• v.20 no.3
• /
• pp.194-201
• /
• 2009

The e1ectrocatalytic properties of heteropolyacids(HPAs) entrapped in covalently cross-linked sulfonated polyetheretherketone(CL-SPEEK/HPA) membranes have been studied for water electrolysis. The HPAs, including tungstophosphoric acid(TPA), molybdophosphoric acid(MoPA), and tungstosilicic acid(TSiA) were used as additives in the composite membranes. The MEA was prepared by a non-equilibrium impregnation-reduction(I-R) method, using reducing agent, sodium borohydride(NaBH4) and tetraamineplatinum(II) chloride(pt(NH$_3$)$_4$Cl$_2$). The electrocatalytic properties of composite membranes such as the cell voltage were in the order of magnitude CL-SPEEKlMoPA40 (wt%) > /TPA30 > /TSiA40. In the optimum cell applications for water electrolysis, the cell voltage of PtlPEM/Pt-Ru MEA with CL-SPEEKlTPA30 membrane was 1.75 V at 80$^{\circ}$C and I A/cm$^2$ and this voltage carried lower than that of 1.81 V of Nafion 117. Consequently, in regards of electrochemical and mechanical characteristics and oxidation durability, the newly developed CL-SPEEKITPA30 composite membrane exhibited a better performance than the others, but CLSPEEKlMoPA40 showed the best electrocatalytic activity (1.71 Vat 80$^{\circ}$C and 1 A/cm$^2$) among the composite membranes.

• Journal of Life Science
• /
• v.18 no.4
• /
• pp.488-493
• /
• 2008

Phosphate, a favorable phosphorous form for plant, is one of major nutrient elements for growth and development in plants. Plants exhibit various physiological and biochemical responses in reaction to phosphate starvation in order to maintain phosphate homeostasis. Of them, expression of high affinity phosphate transporter gene family and efficient uptake of phosphate via them is a major physiological process for adaption to phosphate deficient environment. Although the various genetic resources of high affinity phosphate transporter are identified recently, little is known about their functions in plant that is prerequisite information before applying to crop plants to generate valuable transgenic plants. We demonstrated that Arabidopsis transgenic plants over-expressing two different high affinity phosphate transporter gens, OsPT1 and OsPT7, derived from rice, exhibit better growth responses compared with wild-type under phosphate starvation condition. Specially, OsPT7 gene has proven to be more effective to generate Arabidopsis transgenic plant tolerant to phosphate deficiency than OsPT1. Furthermore, the expression level of AtPT1 gene that is one of reporter genes specifically induced by phosphate starvation was significantly low compared with wild-type during phosphate starvation. Taken together, these results collectively suggest that over expression of OsPTl and OsPT7 genes derived from monocotyledonous plant function efficiently in the dicotyledonous plant, relieving stress response caused by phosphate starvation and leading to better growth rate.

• Journal of Korean Society of Forest Science
• /
• v.95 no.1
• /
• pp.55-59
• /
• 2006

The objectives of this study, an analysis of the morphological characteristics among six provenances of a rare Rhododendron micranthum could be used for the conservation of gene resources and could provide information on superior trees selection. The following results were obtained. Approximately Mt.worak region showed larger values at petal character. On the other hand, Bonghwa region showed smaller values at petal character. Yeonha-ri region showed larger values at leaf character. On the other hand, Bonghwa region showed smaller values at leaf character. The results of principal component analysis (PCA) for morphological characteristics showed that the first for principal components(PC's) explained 41.6% of the total variation. From th third PC explained 81.5% of the total variation. The first PC was correlated with those characteristics that were mainly related to the Petal length (PL), Leaf length (LL) width (LW), Stigma length (SL). The second PC was correlated with the Petiole length (PTW), Anther length (AL). The third PC was correlated with the Flower pedicel length (FPL), Filament length (FL). Therefore, these characteristics was important to analysis of the variation for morphological characteristics among provenances of Rhododendron micranthum. Cluster analysis using single linkage method based on morphological characteristics showed that six provenances of Rhododendron micranthum could be clustered into three groups. Group I is Jicdong-ri, Group II is Mt.worak and Yeonha-ri, and Group III is Taeback, Bonghwa, and Samcheok. These results corresponded well with that of principal component analysis.

• International Journal of Highway Engineering
• /
• v.8 no.4 s.30
• /
• pp.125-133
• /
• 2006

In this study, the Korean Industrial Standard(KS) penetration grade system was examined to evaluate its statistical validity. It was found from this limited study that the system has no gap between each grade, the binder falling out of limit trespasses into other binder grade. Therefore, many products can have similar property level with an adjacent grade even though the mean value is within the specification limit. It was also found out that the equal range setup of each grade, such as 20 for 40-60, 60-80, 80-100, has no statistical foundation. Since KS penetration grade is defined without gap between each grade, the producer must maintain the coefficient of variation below the level by the ASTM system to satisfy the normal quality control limit of products. Due to its lack of a gap between grades, higher percentage of products will be duplicated even if the mean is at the median of the specification limits due to material's quality uncertainty. Especially if the mean moves toward the upper limit, a half or more of the binder grade will be overlapped with the upper binder grade. Therefore, KS penetration specification should be immediately modified by statistically valid methodologies.