• Journal of the Korean Wood Science and Technology
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• v.23 no.4
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• pp.1-9
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• 1995

This study was carried out to experiment the dimensional stabilization of woods of red pine (Pinus densiflora S. et Z.) and sugi(Cryptomeria japonica D. Don) by vacuum impregnation of polyehtylene glycols(PEG) with mo. wt. 200, 400, 600, 1000; polypropylene glycols (PPG) with mo. wt. 425,725 ; PEG-acryloylates, and PPG-acryloylates synthesized, and then by water soaking. The results obtained are as follows: 1. The density of sapwood and heartwood was different from each other in both species. 2. The PEG and PEG-macromers with lower molecular weight by impregnation has increased the density of wood specimens more higher, thereby caused their higher volume expansion, and those with higher molecular weight than 600 has tended to down their density increment. 3. Before and after water soaking, the density decrease of specimen impregnated was high in woods impregnated with simple PEG and PPG, while lower in specimens impregnated with PEG-macromers and PPG-macromers. 4. So PEG-macromer was expected to hold the original dimension of decayed wood for antiques, but it was necessary to develop another penetration method as well as aqueous solvent.

• Elastomers and Composites
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• v.27 no.3
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• pp.161-173
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• 1992

A series of polyurethane block copolymers based on hydroxyterminated poly(dimethyl siloxane), poly(propylene glycol) and poly(tetramethylene glycol) soft segments of molecular weights 1,809, 2,000 and 2,000, respectively, were synthesized. The hard segments consisted of 4,4'-diphenylmethane diisocyanate and 1,4-butanediol as the chain extender. Samples with different molar ratios were prepared. We tried to synthesize poly(dimethyl siloxane)-based polyurethane(PDMS-PU) containing a hard block as major fraction and a soft block as minor fraction for preparing toughened rigid systems. After a study of the pure PDMS-PU, poly(propylene glycol)-based polyurethane(PPG-PU) and poly(tetramethylene glycol)-based polyurethane(PTMG-PU), (mixed polyol)-based block copolymers and blends between PDMS-PU, PPG-PU and PTMG-PU were prepared, and characterized by means of differential scanning calorimetry, tensile testing and scanning electron microscopy. In (mixed polyol)-based PU and in lower hard segment content blends, macro-phase separation was shown, but blends with higher hard segment contents showed significant reduction in amounts of phase separation.