• Title/Summary/Keyword: PP2A

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Liquefaction Characteristics of Polyethylene-Polypropylene Mixture by Pyrolysis at Low Temperature (Polyethylene-Polypropylene 혼합물의 저온 열분해에 의한 액화특성)

  • Cho, Sung-Hyun;Choi, Hong-Jun;Na, Byung-Ki;Lee, Bong-Hee
    • Clean Technology
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    • v.15 no.2
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    • pp.109-115
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    • 2009
  • The low temperature pyrolysis of polyethylene (PE), polypropylene (PP) and polyethylene-polypropylene (PE-PP) mixture in a batch reactor at the atmospheric pressure and $450^{\circ}C$ was carried out to investigate the synergy effect of PE-PP mixture. The pyrolysis time was from 20 to 80 mins. The products formed during pyrolysis were classified into gas, gasoline, kerosene, gas oil and heavy oil according to the petroleum product quality standard of Korea Institute of Petroleum Quality. The analysis of the product oils by GC/MS showed that no new component was detected and no synergy effect was made by mixing of PE and PP. Conversions and yields of PE-PP mixtures were linearly dependent on the mixing ratio of samples.

A Study on the Water Absorption Velocity of Sized Fabrics (푸새직물의 흡수속도에 관한 일연구)

  • 오화자
    • Journal of the Korean Home Economics Association
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    • v.25 no.2
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    • pp.31-38
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    • 1987
  • This paper aims to examine the velocity of water absorption of cotton, hemp, and T/C fabrics sized by rice, wheat, potato, corn flour and pp.V.A.. Experimental variables such as the concentration of sizing agents, the moisture regain of unsized fabrics and the ironing temperature showed the following results. 1. When the fabrics were sized, the velocity of water absorption increased according to the order of corn, rice, potato, wheat flour and pp.V.A. for cotton fabrics, of corn, potato, rice, wheat flour and pp.V.A. for hemp fabrics, and of corn, wheat, rice, potato flour and pp.V.A. for T/C fabrics; corn flour showed the highest velocity of water absorption and pp.V.A. did the lowest among all the others mentioned above. 2. The higher fabric density, the higher velocity of water absorption. The finer the count of fabric yarn, the higher velocity of water absorption. 3. The material of sized fabrics most affected the velocity of water absorption than other factors of those. 4. To a certain extent, the higher the concentration of sizing agent, the higher the velocity of water absorption. 5. The fabrics with moisture regain of 20% before sizing showed the highest velocity of water absorption. 6. The ironing temperature after sizing fabrics mentioned below showed the highest velocity of water absorption; 180$^{\circ}C$ for cotton, 200$^{\circ}C$ for hemp, and 160$^{\circ}C$ for T/C fabrics.

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DNA Rearrangement of TOL Plasmid in Pseudomonas putida PpGl Harbouring CAM Plasmid (CAM 플라스미드를 함유하는 Pseudomonas putida PpG1에서 TOL 플라스미드이 DNA 재배열)

  • 전효곤;조경연;고영희
    • Microbiology and Biotechnology Letters
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    • v.18 no.4
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    • pp.433-436
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    • 1990
  • The TOL plasmid, pWWO, conjugally transferred from Pseudomonas putida mt-2 was dissociated into TOL* and TOL $\Delta$A in P. putidu PpGl carrying CAM plasmid. The TOL* was integrated into the CAM plasmid, and the resulting plasmid was designated as CAM::TOL*. The introduction of NAH plasmid, belonging to Inc P9 incompatibility group, into P. putida CSTBA carrying CAM::TOLt plasmid and TOL A plasmid did not affect m-toluate catabolism, but resulted in expelling the TOL $\Delta$ plasmid.

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Effect of waste cement bag fibers on the mechanical strength of concrete

  • Marthong, Comingstarful
    • Advances in materials Research
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    • v.8 no.2
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    • pp.103-115
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    • 2019
  • Polypropylene (PP) fibers for making fabric which is used for packing cement have a high strength and high tear resistance. Due to these excellent properties the present study investigates the effect of PP fibers on the mechanical strength of concrete. Mechanical strength parameters such as compressive strength, splitting tensile strength and flexural strength are evaluated. Structural integrity of concrete using Ultrasonic Pulse Velocity (UPV) was also studied. Concrete containing PP fibers in percentage of 0%, 0.15%, 0.25%, 0.5% and 0.75% was developed with a characteristic compressive strength of 25 MPa. Concrete cubes, cylinder and prismatic specimens were cast and tested. It was found that the UPV values recorded for all specimens were of the similar order. Test results indicated the used of PP fibers can significantly improve the flexural and splitting tensile strengths of concrete materials whereas it resulted a decreased in compressive strength. The relative increase in split tensile and flexural strength was optimum at a fiber dosage of 0.5% and a mild decreased were observed in 28 days compressive strength. The findings in this paper suggested that PP fibers deriving from these waste cement bags are a feasible fiber option for fiber-reinforced concrete productions.

Ferulate, an Active Component of Wheat Germ, Ameliorates Oxidative Stress-Induced PTK/PTP Imbalance and PP2A Inactivation

  • Koh, Eun Mi;Lee, Eun Kyeong;Song, Chi Hun;Song, Jeongah;Chung, Hae Young;Chae, Chang Hoon;Jung, Kyung Jin
    • Toxicological Research
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    • v.34 no.4
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    • pp.333-341
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    • 2018
  • Ferulate is a phenolic compound abundant in wheat germ and bran and has been investigated for its beneficial activities. The aim of the present study is to evaluate the efficacy of ferulate against the oxidative stress-induced imbalance of protein tyrosine kinases (PTKs), protein tyrosine phosphatases (PTPs), and serine/threonine protein phosphatase 2A (PP2A), in connection with our previous finding that oxidative stress-induced imbalance of PTKs and PTPs is linked with proinflammatory nuclear factor-kappa B $(NF-{\kappa}B)$ activation. To test the effects of ferulate on this process, we utilized two oxidative stress-induced inflammatory models. First, YPEN-1 cells were pretreated with ferulate for 1 hr prior to the administration of 2,2'-Azobis(2-methylpropionamidine) dihydrochloride (AAPH). Second, 20-month-old Sprague-Dawley rats were fed ferulate for 10 days. After ferulate treatment, the activities of PTKs, PTPs, and PP2A were measured because these proteins either directly or indirectly promote $NF-{\kappa}B$ activation. Our results revealed that in YPEN-1 cells, ferulate effectively suppressed AAPH-induced increases in reactive oxygen species (ROS) and $NF-{\kappa}B$ activity, as well as AAPH-induced PTK activation. Furthermore, ferulate also inhibited AAPH-induced PTP and PP2A inactivation. In the aged kidney model, ferulate suppressed aging-induced activation of PTKs and ameliorated aging-induced inactivation of PTPs and PP2A. Thus, herein we demonstrated that ferulate could modulate PTK/PTP balance against oxidative stress-induced inactivation of PTPs and PP2A, which is closely linked with $NF-{\kappa}B$ activation. Based on these results, the ability of ferulate to modulate oxidative stress-related inflammatory processes is established, which suggests that this compound could act as a novel therapeutic agent.

A Study on the Mechanical, Thermal, Morphological, and Water Absorption Properties of Wood Plastic Composites (WPCs) Filled with Talc and Environmentally-Friendly Flame Retardants (친환경 난연제와 탈크를 첨가한 목재·플라스틱 복합재의 기계적, 열적, 형태학적 및 수분흡수 특성에 관한 연구)

  • Lee, Danbee;Kim, Birm-June
    • Journal of the Korea Furniture Society
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    • v.27 no.2
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    • pp.137-144
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    • 2016
  • Wood plastic composite (WPC) is a green composite made of wood flour and thermoplastics to provide better performance by removing the defects of both wood and plastics. However, relatively low thermal stability and poor fire resistance of wood and plastics included in WPC have been still issues in using WPC as a building material for interior applications. This study investigated the effect of environmentally-friendly flame retardants (EFFRs) on the mechanical, thermal, morphological, and water absorption properties of wood flour (WF)/talc/polypropylene (PP) composites in comparison with neat PP. The whole EFFRs-filled WF/talc/PP composites showed higher values in flexural strength, flexural modulus, and impact strength compared to neat PP. In thermal properties, aluminum hydroxide (AH)-filled composite showed a $36^{\circ}C$ reduction in maximum thermal decomposition temperature ($T_{max}$) compared to neat PP, but magnesium hydroxide (MH) played an important role in improving thermal stability of filled composite by showing the highest $T_{max}$. From this research, it can be said that MH has potentials in reinforcing PP-based WPCs with improvement of thermal stability.

Purification and Characterization of Protein Phosphatase 2C from Rat Liver

  • Oh, Joung-Sook;Hwang, In-Seong;Choi, Myung-Un
    • BMB Reports
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    • v.30 no.3
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    • pp.222-228
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    • 1997
  • Protein phosphatase 2C (PP2C) is one of the four major serine/threonine phosphatases which is dependent on $Mg^{2+}$ for its activity. PP2C was purified from rat liver cytosol and its characteristics were investigated. The substrate employed for routine assay was $[^{32}P]casein$ phosphorylated by PKA. The purification process involved DEAE chromatography, ammonium sulfate fractionation, phenyl sepharose chromatography, sephacryl 5-200 gel filtration, and histone agarose chromatography. The SDS-PAGE of PP2C showed one major single protein band at a position corresponding to a molecular mass of 43 kd and the purification fold was 637. The enzyme showed a pH optimum of 8 and $K_M$ value was $1.9\;{\mu}M$. However, when the substrate was changed to $[^{32}P]histone$, the pH optimum was shifted to 7 and $K_M$ value was $2.3\;{\mu}M.\;Mg^{2+}$ was essential to the enzyme activity and okadaic acid did not exert any inhibitory effect on the enzyme. To examine residue in the active site of PP2C effects of some protein-modifying reagents were tested.

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In Vitro Study of Fluorescence Detection for Protoporphyrin IX Induced from 5-Aminolevulinic Acid in Incubated Lung Cancer Cells (폐암 세포주에서 5-Aminolevulinic Acid에 의해 유도된 Protoporphyrin IX의 형광 진단을 위한 In Vitro 연구)

  • Kim, Myung-Hwa;Kim, Hyun-Jeong;Lee, In-Seon;Kim, Kyung-Chan;Lee, Chang-Seop
    • KSBB Journal
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    • v.22 no.2
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    • pp.67-72
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    • 2007
  • This study investigates the optimal method of administrating 5-aminolevulinic acid (5-ALA) in the context of fluorescence detection by analyzing protoporphyrin IX (PpIX) fluorescence in the cultured normal and cancer cells. 5-ALA was injected as a photosensitizer to the lung cancer cells (A549, NCI-H460) and normal lung cells (HeI299). Hel299, A549, and NCI-H460 cells were incubated with various concentrations of 5-ALA ($0\sim800{\mu}g/mL$). The accumulation of PpIX induced by 5-ALA was observed in A549, NCI-H460 and Hel299 cells. The cell viability was estimated by means of the MTT assay. Formation of PpIX was measured by fluorescence spectroscopy. Especially, formation of PpIX in cancer cells was higher than normal cells. This study suggests that the difference of PpIX induced in normal and cancer cells treated with 5-ALA may use by means of fluorescence diagnosis for cancer.

The Study on the Properties of Polypropylene/Nylon6 with Various Compatibilizers (Polypropylene/Nylon6 블렌드에서 이종의 상용화제에 따른 물성연구)

  • Kim, H.C.;Lee, K.Y.;Kim, H.I.
    • Applied Chemistry for Engineering
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    • v.10 no.4
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    • pp.497-501
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    • 1999
  • The changes of properties were studied for the polypropylene(PP)/Nylon6 blends containing different kinds of compatibilizer made by either reactive extrusion of solution reaction. The compatibilizers were PP grafted with maleic anhydride (MAH) made by reactive extrusion and solution reaction. The grafted MAH contents were 0.3 wt %, and 2.7 wt %, respectively. The composition of the PP/nylon6 blend was fixed at 75/25 by weight. Blending was carried out with twin-screw extruder (L/D=30, ${\psi}=30$) at 300 rpm. As the content of PP-g-MAH was increased, the crystallization peak of Nylon6 decreased gradually then finally disappeared. Disappearance of crystallization peak of Nylon6 was mostly affected by grafted MAH content rather than the preparation method and the amount of compatibilizer. The portion of Nylon6 that could not crystallize in its normal crystallization temperature crystallized together with PP at the crystallization temperature of PP. So called concurrent crystallization was observed. Meanwhile two more peaks were observed during heating cycle. One was exothermic peak at $193^{\circ}C$ near to crystallization temperature of Nylon6, the other was endothermic peak at $215^{\circ}C$ that was $5^{\circ}C$ lower than normal endothermic peak of Nylon6. To analyze the peaks, nylon6 was annealed in the differential scanning calorimeter. As a result, the peak at $193^{\circ}C$ was crystallization peak of imperfect crystalline of Nylon6 and the other peak at $215^{\circ}C$ was melting peak of imperfect crystalline of nylon6.

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The Effects of Zeolite-Type Catalysts on the Pyrolysis Reaction of PP to Produce Fuel-oil (폴리프로필렌 수지 이용 연료유 생성을 위한 열분해 반응에서 제올라이트계 촉매의 영향)

  • Bak, Young-Cheol;Choi, Joo-Hong;Oh, Se-Hui
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.442-448
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    • 2012
  • The effects of zeolite-type catalysts addition on the thermal decomposition of the PP resin have been studied in a thermal analyzer, a Pyrolyser GC-mass, and a small batch reactor. The zeolite type catalysts tested were natural zeolite, used FCC catalyst, and ZSM-5. As the results of TGA experiments, the pyrolysis starting temperature for PP varied in the range of $330{\sim}360^{\circ}C$ according to the heating rate. Addition of the zeolite type catalysts in the PP resin increased the pyrolysis rate in the order of used FCC catalyst> natural zeolite> ZSM-5 > PP resin. Adding the used FCC catalyst in the PP reduced most effectively the pyrolysis finishing temperature. In the PY-G.C. mass experiments, addition of zeolite type catalysts decreased the molecular weight of pyrolyzed product. In the batch system experiments, the mixing of used FCC catalyst enhanced best the initial yield of fuel oil, but the final yield of fuel oil was 2% higher in the case of mixing of natural zeolite. Also in the carbon number analysis, used FCC catalyst was the most useful one in this experiments for fuel oil.