• Title/Summary/Keyword: PP Composite

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A Study on the Phase Separation and Mechanical Properties of Wood Flour-Polypropylene Composites (목분-폴리프로필렌 복합체의 상분리 및 기계적 특성에 관한 연구)

  • Lee, Kyoung Hee;Byon, Sungkwang
    • Elastomers and Composites
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    • v.48 no.3
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    • pp.216-220
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    • 2013
  • The phase separation in Wood Flour-Polymer Composite (WPC) was investigated and the reasons for change in mechanical properties with the content of wood flour were explored. The wood flour-polypropylene composite samples with different wood flour contents were prepared. From differential scanning calorimetry (DSC) thermograms of WPC samples, the trend of crystallinity and melting temperature ($T_m$) were analyzed. The crystallinity and melting temperature increased and then decreased as the content of wood flour increased. From these results, it was confirmed that at the low wood flour content the wood flours were dispersed into the polypropylene matrix but at the high wood flour content, the phase separation between polymer and wood flour phases appeared. The tensile strength of WPC samples was continuously decreased with the increase of wood flour content. At a low wood flour content, the low interfacial bonding and the decrease in crystallinity were the main reasons for the decrease in tensile strength with the increase of wood flour content. At a high wood flour content, the decrease in tensile strength resulted from the interfacial defects between the polymer and wood flour phases. The impact strength of the WPC sample showed the maximum behavior with the content of wood flour. At a low wood flour content, the impact strength was enhanced owing to the decrease in brittleness, which results from the decrease in crystallinity. At a high wood flour content, however, the impact strength decreased due to phase separation.

Evaluation of the Field Application of the Ready-mixed Shotcrete using the Synthetic Fiber (합성섬유를 혼입한 레디믹스트 숏크리트의 현장적용성 평가)

  • Choi, Hee-Sup;Nam, Kwan-Woo;Nam, Gi-Mok;Seo, Sin-Seok
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.1536-1539
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    • 2009
  • In this paper, The Ready-mixed Shotcrete which Factory with automatic production system is made Materials using synthetic fiber is evaluated the field application. Result of whole test, synthetic fiber(PP, PVA) is indicated almost equal result of steel fiber by rebound rate, compressive strength and bending test. especially, PP fiber(40mm, 12kg) is showed that bending strength and toughness is better than steel fiber, also I reason in that field application of synthetic fiber(PP, PVA) is proved.

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Characterizations of Polypropylene/Functionalized Multiwalled Carbon Nanotube Films (폴리프로필렌/기능화된 다중벽 탄소나노튜브 나노복합체 필름의 특성 연구)

  • Ko, Jeong-Ho;Kim, Jeong-Cheol;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.33 no.4
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    • pp.333-341
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    • 2009
  • Polypropylene (PP)/functionalized multiwalled carbon nanotube (F-MWNT) nanocomposites were prepared by using solution intercalation method with different F-MWNT loads. The PP composite films, which contain dodecanol-MWNT (DDO-MWNT) or dodecylamine-MWNT (DDA-MWNT) as reinforcing additive, were evaluated by thermomechanical properties, morphology, electrical conductivity and gas permeability. The images from electron microscopy (SEM and TEM) showed that F-MWNTs were homogeneously dispersed in PP matrix, while they were agglomerated in some other part. The addition of F-MWNT could improve thermomechanical properties of the films. The maximum enhancement was observed at 2 wt% F-MWNT. DDO-MWNT was more effective than DDA-MWNT for both tensile modulus and optical transparency of the films.

Preparation and Characterization of Wood Polymer Composite by a Twin Screw Extrusion (이축 압출공정을 이용한 Wood Polymer Composite의 제조 및 특성 분석)

  • Lee, Jong-Hyeok;Lee, Byung-Gab;Park, Ki-Hun;Bang, Dae-Suk;Jhee, Kwang-Hwan;Sin, Min-Cheol
    • Elastomers and Composites
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    • v.46 no.3
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    • pp.211-217
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    • 2011
  • Wood Polymer Composite (WPC) has attracted a great deal of attention in environmental industries due to renewable resources, processability, excellent physical properties and logging regulations for application to housing units and engineering construction materials. In this study, commercial WPCs were prepared by using a modular intermeshing co-rotating twin screw extruder. The effect of three main factors such as wood flour contents, coupling agent concentrations and pre-treatment of wood flour on the properties of WPCs was extensively investigated. It was found that tensile strength and thermal stability were decreased with increasing wood flour contents whereas the water absorption was increased. Addition of maleic anhydride grafted polypropylene (PP-g-MA) into WPC exhibited better physical properties. On the contrary, the water absorption was slightly decreased with PP-g-MA. Finally the sample, which was prepared with pre-treated wood flour, represented the highest tensile strength. However, the water absorption of the sample was increased due to the transition of crystalline structure of cellulose.

Development of Lightweight Piezo-composite Curved Actuator (곡면형 압전 복합재료 작동기 LIPCA 개발)

  • Park, Ki-Hoon;Yoon, Kwang-Joon;Park, Hoon-Cheol
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.5
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    • pp.94-100
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    • 2002
  • This paper is concerned with the development, and performance test of LIPCA (Lightweight Piezo-composite Curved Actuator) that is lighter than other conventional piezo-composite type actuators. LIPCA is composed of top fiber composite layers with a high modulus and low CTE (Coefficient of Thermal Expansion), a middle PZT cermaic wafer, and base layers with a high modulus and high CTE. The performance of each actuator was evaluated using an actuator test system consisting of an actuator supporting jig, a high voltage actuating power supplier, and a non-contact laser measuring system. The simply supported condition actuator was excited by the power supplier with 1.0Hz cycle and up to $100\sim400V_{pp}$. The displacement at the center point of actuator was measured with non-contact laser displacement measuring system, It has been shown that the LIPCA-C2 can 34% decrease in mass and 13% increase in displacement compared to THUNDER.

Temperature Effects on Impact Fracture Mechanisms of Glass Fiber/Polypropylene Campsites (유리섬유/폴리프로필렌 복합재료의 충격파괴기구에 대한 온도효과)

  • KOH S. W.;Um Y. S.
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.05a
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    • pp.314-319
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    • 2004
  • Many of researches regarding mechanical properties of composite materials are associated with humid environment and temperature. Especially the temperature is a very important factor influencing the design of thermoplastic composites. However, the effect of temperature on impact behavior of reinforced composites have not yet been fully explored. An approach which predicts critical fracture toughness GIC was performed by the impact test in this work The main goal of this work is to study effects of temperature in the impact test with glass fiber/polypropylene(GF/pp) composites. The critical fracture energy and failure mechanisms of GF/PP composites are investigated in the temperature range of $60^{\circ}C\;to\;-50^{\circ}C$ by impact test. The critical fracture energy shows a maximum at ambient temperature and it tends to decrease as temperature goes up or goes down. Major failure mechanisms can be classified such as fiber matrix debonding, fiber pull-out and/or delamination and matrix deformation.

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Formability for AA5182 sheet and AA5182/PP/AA5182 sandwich sheet (AA5182판재와 AA5182/PP/AA5182 샌드위치 판재의 성형성 평가)

  • 김대용;김기주;정관수;신광선;유동진
    • Composites Research
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    • v.13 no.2
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    • pp.81-90
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    • 2000
  • For automotive applications, a sandwich sheet which was made of a 5182 aluminum alloy (AA5182) sheet and a polypropylene (PP) sheet, AA5182/PP/AA5182, has been developed. In order to evaluate its formability, the forming limit diagrams (FLD) of the 5182 aluminum alloy sheet with 0.2mm thickness and the sandwich sheet with 1.2mm thickness have been obtained based on the modified Marciniak-Kuczynski (M-K) theory. To account for the anisotropy of the sheet, Hill's 1948 yield function has been applied. The FLD of the sandwich sheet was predicted to be better than that of the AA5182 sheet, which was well confirmed by experiments.

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Recycling of Sound Insulation Headliner Waste Material (흡음재 폐기물의 재활용 방안)

  • Hong, Young-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.6
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    • pp.3089-3095
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    • 2013
  • The headliner was made of polyurethane(PU) and glass fiber(GF) composite materials are widely used as a sound insulation material. A large amount of waste materials occurs as a by-product in the headliner manufacturing process. In order to efficiently reuse the headliner waste materials, separation process of the components are very necessary. According to the results of thermal analysis, weight loss showed increase in the order polyurethane foam> non-foaming polyurethane> non-woven fabric> 1st layer> glass fiber in the range of up to $400^{\circ}C$. Analysis of the DSC characteristics, HDPE, LLDPE, PP, and Master Batch by adding additives the wasted scrap. As a result, except for the PP, there was no exothermic transition due to the crystallization.

Study on the Preparation of the Modified PP composite resin for Automobile parts Materials (기능성 변성PP 제조 및 자동차부품용 복합수지 제조 기술 개발)

  • Ahn, Tae-Kwang;Hwang, Young-Hyun;Jun, Young-Jin
    • Proceedings of the KAIS Fall Conference
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    • 2009.05a
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    • pp.212-215
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    • 2009
  • 요구되는 접착력과 그라프트율을 만족시킬 수 있는 변성폴리프로필렌의 제조 기술 확립을 목표로 변성폴리프로필렌의 최적 합성을 위한 과산화물, 변성폴리프로필렌의 최적 합성을 위한 촉매 및 반응몰비, 변성폴리프로필렌의 최적 합성을 위한 반응온도, 반응시간 확립을 통한 변성 PP 제조기술을 개발하였으며, $90{\Phi}$ extruder에서 상업 생산을 위한 공정 제어 기술 확립과 접착력과 그라프트율 등을 나타내는 변성폴리프로필렌의 최적 합성 조건 확립을 통한 폴리프로필렌 엘라스토머 복합수지용은 물론 강관 코팅용, 시트 및 필름용 등의 변성 폴리프로필렌 제조기술을 개발하였다. 이들 변성 PP를 활용하여 매트릭스 및 필러, 분산 조건 변경 시험, 엘라스토머 폴리프로필렌 컴파운드 최적 분산 조건 확립, 엘라스토머 폴리프로필렌 컴파운드 pilot 생산 및 제품 분석을 통하여 초고강성 범퍼, 룸미러 케이스 소재, 인패널, 도어용으로 사용될 수 있는 자동차 부품용 폴리프로필렌 복합수지 개발을 완료하였다.

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Characterization of Pervaporation Membranes and Its Operation Parameters for Alcohol Concentration (알코올 농축을 위한 투과증발막의 특성 및 조업변수 연구)

  • 임군택;김현일;김성수
    • Membrane Journal
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    • v.9 no.2
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    • pp.107-113
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    • 1999
  • Alcohol concentration via pervaporation process was performed by using commercial PDMS(polydimethylsiloxane) composite membrane and plasma treated PP(polypropylene) membranes. Effects of operating parameters of pcrvaporation process were examined. With the increase of butanol concentration in the feed, flux and selectivity increased due to the greater affinity of butanol with PDMS than that of water. As the operating temperature increased, free volume as well as the solubilities and diffusivities of alcohol and water increased to result in the greater flux and less selectivity of the membrane. As solubility parameter difference between alcohol and PDMS membrane decreased, high flux and good selectivity were obtained. When PP membrane was plasma treated with methanol, it has 6 times greater flux than PDMS membrane with equivalent separation factor. With the increase of plasma treatment time, flux and selectivity were enhanced. However, excess treatment time caused pore blocking to result in the flux decrease.

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