• Title/Summary/Keyword: PP&E

Search Result 241, Processing Time 0.028 seconds

Effect of added ionomer on morphology and properties of PP/clay nanocomposites

  • Liu, Hongzhi;Lim, Hyoung-Taek;Kim, Yong-Kyoung;Han, Nam-Kun;Ahn, Kyung-Hyun;Lee, Seoung-Jong
    • Proceedings of the Polymer Society of Korea Conference
    • /
    • 2006.10a
    • /
    • pp.367-367
    • /
    • 2006
  • With poly (ethylene-co-methacrylic acid) ionomer (i.e. Surlyn) as a compatibilizer, PP/organoclay (Cloisite(R)20A) nanocomposites were prepared via melt compounding in a co-rotating twin-screw extruder. For comparison, the widely used PP-g-MA was also used as a reference. The content of organoclay was fixed at 5phr based on the total weight of polymer resins. The structures of nanocomposites were characterized by XRD, rheometry in small amplitude oscillatory shear, SEM, and TEM, respectively. It was found that PP/Surlyn/OMMT nanocomposites displayed higher intercalation degree and better dispersion effect than the corresponding PP/PP-g-MA/OMMT counterpart. Additionally, their mechanical properties and wettability were measured.

  • PDF

Dephosphorylation of DBC1 by Protein Phosphatase 4 Is Important for p53-Mediated Cellular Functions

  • Lee, Jihye;Adelmant, Guillaume;Marto, Jarrod A.;Lee, Dong-Hyun
    • Molecules and Cells
    • /
    • v.38 no.8
    • /
    • pp.697-704
    • /
    • 2015
  • Deleted in breast cancer-1 (DBC1) contributes to the regulation of cell survival and apoptosis. Recent studies demonstrated that DBC is phosphorylated at Thr454 by ATM/ATR kinases in response to DNA damage, which is a critical event for p53 activation and apoptosis. However, how DBC1 phosphorylation is regulated has not been studied. Here we show that protein phosphatase 4 (PP4) dephosphorylates DBC1, regulating its role in DNA damage response. PP4R2, a regulatory subunit of PP4, mediates the interaction between DBC1 and PP4C, a catalytic subunit. PP4C efficiently dephosphorylates pThr454 on DBC1 in vitro, and the depletion of PP4C/PP4R2 in cells alters the kinetics of DBC1 phosphorylation and p53 activation, and increases apoptosis in response to DNA damage, which are compatible with the expression of the phosphomimetic DBC-1 mutant (T454E). These suggest that the PP4-mediated dephosphorylation of DBC1 is necessary for efficient damage responses in cells.

Influence of Fluorinated Illite on Thermal, Antibiotic and Far-infrared Emission Properties of Polypropylene Non-woven Fibers (폴리프로필렌 부직포 섬유의 열, 항균 및 원적외선 방사 특성에 미치는 불소화 일라이트 첨가의 영향)

  • Kim, Jinhoon;Im, Ji Sun;Seo, Kyeong-Won;Lee, Young-Seak
    • Polymer(Korea)
    • /
    • v.37 no.1
    • /
    • pp.86-93
    • /
    • 2013
  • In this work, the thermal, antibiotic properties and far-infrared emissivity of fluorinated illite embedded polypropylene non-woven fibers (f-illite/PP fibers) were investigated in the presence of 0, 1, 3, 5 and 7 wt% illite powders. The thermal properties of f-illite/PP fibers were studied by thermogravimetric analysis (TGA). Their antibiotic properties were examined by Staphylococcus aureus and Klebsiella pneumoniae test. Their far-infrared emissivity was also investigated by Fourier transform infrared spectroscopy. From the experimental results, thermal, antibiotic properties and far-infrared emissivity of f-illite/PP fibers were improved by increasing fluorinated illite contents and the property values of 5 wt% f-illite/PP fibers were increased remarkably by about 10.3, 41.2 and 9.8% respectively in comparison with PP non-woven fibers having no fluorinated illite additive. This result was interpreted as the development of interfacial adhesion force between the polymer chains due to the fluorination of illite power.

Studies on the Synthesis of Aminated PP-g-GMA Fibrous ion Exchanger by E-beam Pre-irradiation and Their Properties of Selective Adsorption for $NO_{3} ^{-}$ (E-beam 전조사에 의한 $NO_{3} ^{-}$ 선택 흡착용 아민화 PP-g-GMA 섬유 이온교환체의 합성과 그 특성에 관한 연구)

  • 황택성;이선아;이면주
    • Polymer(Korea)
    • /
    • v.26 no.2
    • /
    • pp.153-159
    • /
    • 2002
  • In order to remove $NO_3;^-$ ion from ground-water, fibrous ion -exchangers, APP-g-GMA, were synthesized by GMA grafting onto PP trunk polymer with E-beam accelerator for pre-irradiation. Their degrees of grafting and amination yield increased up to $60^{\circ}C$ and showed maximum values as 133%, 88%, respectively. And their swelling ratio and ion exchange capacity at the maximum values are 86%, 2.5 meq/g, respectively which was higher than commercial ion-exchangers such as IMAC HP555 and Amberlite IRA 400. Optimum adsorption condition of $NO_3;^-$ ion was measured at pH 5~6 and -Cl form of APP-g-GMA containing trimethylammonium group showed the highest adsorption capacity.

Mechanical and electrical properties of insulating materials at cryogenic temperature (극저온에서의 절연재료의 기계적.전기적 성질)

  • 김상현;마대영;김현희;정순용;김영석
    • Electrical & Electronic Materials
    • /
    • v.9 no.10
    • /
    • pp.1033-1039
    • /
    • 1996
  • Electrical and mechanical properties of polymer sheet at cryogenic temperature have been investigated. Tensile stress(and strain at break) in liquid nitrogen(77K) of 79.7MPa(l.2%) and 117.4MPa(2.05%) are evaluated for films of Polypropylene (PP) and Kapton, respectively. Dielectric loss tangent(tan .delta.) of PP and Kapton films is almost independent of the frequency and tensile stress. Also, field strength of PP film at 77K decreases with increasing the tensile stress.

  • PDF

A PROOF OF STIRLING'S FORMULA

  • Park, June-Sang
    • Communications of the Korean Mathematical Society
    • /
    • v.9 no.4
    • /
    • pp.853-855
    • /
    • 1994
  • The object of present note is to give a very short proof of Stirling's formula which uses only a formula for the generalized zeta function. There are several proofs for this formula. For example, Dr. E. J. Routh gave an elementary proof using Wallis' theorem in lectures at Cambridge ([5, pp.66-68]). We can find another proof which used the Maclaurin summation formula ([5, pp.116-120]). In [1], they used the Central Limit Theorem or the inversion theorem for characteristic functions. In [2], pp. Diaconis and D. Freeman provided another proof similarly as in [1]. J. M. Patin [7] used the Lebesgue dominated convergence theorem.

  • PDF

A Study on the Antibacterial and Antifungal Properties of Zeolite/Zinc-polypeptide Coated Polypropylene Film (Zeolite/Zinc-polypeptide를 코팅한 폴리프로필렌필름의 항균 및 항진균 특성에 관한 연구)

  • Lee, Hakrae;Ko, Euisuk;Shim, Woncheol;Kim, Jongseo;Kim, Jaineung
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
    • /
    • v.27 no.1
    • /
    • pp.1-8
    • /
    • 2021
  • This study is for the application of functional antibacterial packaging to fresh food. Zeolite/Zinc-polypeptide was coated on PP film at concentrations of 5%, 10%, and 15%, degree of dispersion was verified through FESEM and FT-IR analysis. In addition, the antibacterial and antifungal properties of the films were analyzed according to the control group and the concentration of coating materials. As a result, the degree of dispersion of coating material was irregular but wide, depending on the concentration of Zeolite/Zinc-polypeptide on the surface of PP film. The antibacterial effect against E. coli was over 99.9%, and the growth of R. oryzae was inhibited about 70%. Therefore, it was confirmed that Zeolite/Zinc-polypeptide had antibacterial and antifungal properties against E. coli and R. oryzae even after coated on PP film. In conclusion, Zeolite/Zinc-polypeptide coating film is expected to be effective in preventing corruption and improving the shelf life of fresh food as a functional packaging material. In order to be applied to various fresh foods in the future, storage experiments are additionally required with temperature and humidity conditions according to fresh foods.

A study of size and frictional effect on the evolution of melting PartII: Twin screw extruder

  • Kim, D.S.;Lee, B.K.;Kim, H.S.;Lee, J.W.;C.G. Gogos
    • Korea-Australia Rheology Journal
    • /
    • v.13 no.2
    • /
    • pp.89-95
    • /
    • 2001
  • Effects of particulate size and frictional characteristics were examined on the melting behavior of PP(polypropylene) in a twin screw extruder. Powder and pellet types of PP were used and each component was blended with PE(polyethylene) wax and clay, respectively. It was observed that small size particulates, 1.e. powder systems exhibit accelerated melting behavior; and it was also found that the abrasive auditive acts as an effective agent for fast melting of PP powder. Retardation of melting due to the reduced friction was observed in both types of PP, contrary to the result found in a batch mixer. The tendency observed in variation of torque and exit temperature was explained in terms of frictional effect and length of compacted region formed during evolution of melting.

  • PDF

Spputtering Depposition and Anncaling of Pb(Zr,Ti)$O_3$Ferroelectric Thin Films (Pb(Zr,Ti)$O_3$ 강유전체 박막의 스퍼터링 증착과 열처리 연구)

  • 박재영;윤진모;장호정;임상규;정지근
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 1996.06a
    • /
    • pp.175-176
    • /
    • 1996
  • ppt/Ti/SiO2/Si 기판상에 고주파 마그네트론 스퍼터링 방식으로 ppZT 박막[두 께:3000$\AA$]을 증착하고 RTA 방식으로 후속 열처리[열처리온도:550~$650^{\circ}C$]를 실시하여 직 경 0.2mm 소자의 FECApps(ferroelectric cappacitors)를 제작하였다. 증착된 ppZT 박막을 강 유전성 pperovskite 결정상으로 만들기 위해 ppZT 박막의 열처리조건을 연구하였으며, 열처리 방식에 따른 ppZT 박막의 결정특성(상형상, 형상관찰, 성분분석 등)과 커패시터 소자의 전기 적 특성($\varepsilon$r,tan$\delta$,pp-E hysteresis curves, 누설전류 등)을 비교, 분석하였다.

  • PDF