• 제목/요약/키워드: POLYCARBONATE

검색결과 614건 처리시간 0.032초

Effect of viscosity ratio and AN content on the compatibilization of PC-SAN blends during ultrasound-assisted melt mixing

  • Kim, Hyung-Su;Yang, Hyun-Suk;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • 제17권4호
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    • pp.165-170
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    • 2005
  • In this study, high intensity ultrasound was employed to induce mechano-chemical degradation during melt mixing of polycarbonate (PC) and a series of styrene-acrylonitrile (SAN) copolymers. It was confirmed that generation of macroradicals of constituent polymers can lead to in-situ copolymer formation by their mutual combination, which should be an efficient path to compatibilize immiscible polymer blends and stabilize their phase morphology in the absence of other chemical agents. Based on the effectiveness of the compatibilization by ultrasound assisted mixing process, we investigated the effects of viscosity ratio of PC and SAN and AN content in SAN on the compatibilization of PC/SAN blends. It was found that effectiveness of compatibilization is optimal when the AN content is in the range of favorable interaction with PC and the viscosity of the matrix is higher than that of the dispersed phase. In addition, changes in the interfacial tension between PC and SAN were assessed by examining relaxation spectra which were obtained from measuring rheological properties of ultrasonically treated blends.

유리섬유가 첨가된 수지에서 사출성형품의 성형수축에 관한 연구 (Investigation of the Part Shrinkage in Injection Molding for Class Fiber Reinforced Thermoplastics)

  • 모정혁;류민영
    • 소성∙가공
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    • 제13권6호
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    • pp.515-521
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    • 2004
  • The shrinkages of injection molded parts are different in molding operational conditions and mold design. It also differs from resins. The shrinkages of injection molded parts fur PBT (polybutylene terephthalate), PC (polycarbonate), and glass reinforced PBT and PC have been studied for various operational conditions of injection molding. The part shrinkage of crystalline polymer, PBT was higher than that of amorphous polymer, PC by about two times. The part shrinkages of both polymers decreased as glass fiber content increases. Higher injection temperature and lower injection pressure resulted in a higher shrinkage in both PBT and PC resins. As mold temperature increases the part shrinkage of PC decreased. However, the part shrinkage of PBT increased as mold temperature increases. The part shrinkages of PBT and PC resins decreased as gate size increases since the pressure delivery is mush easier for a larger gate size. The part shrinkage of flow direction was less than that of the perpendicular direction to the flow for both pure and glass fiber reinforced resins. The part shrinkage at the position close to the gate was less than that of the position far from the gate.

고분자 소재의 표면보호를 위한 DLC 코팅 기술

  • 양지훈;정재인
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.265-265
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    • 2010
  • 고분자 소재(polycarbonate; PC)의 표면을 보호하고 광학적 특성을 유지하기 위해 산화물 다층 박막과 비정질 탄소 박막(diamond-like carbon; DLC)을 전자빔 증착(e-beam evaporation)과 이온빔 증착(ion-beam deposition)을 이용하여 고분자 소재에 코팅하였다. 전자빔 증착으로 코팅된 실리콘과 티타늄 산화물 다층 박막은 소재 표면에서 가시광선의 반사율을 낮추는 효과를 가지고 있어 다양한 광학 코팅분야에서 이용되고 있다. 비정질 탄소 박막은 경도가 높고 마찰계수가 낮기 때문에 기계부품의 수명향상을 향상하기 위해 주로 사용되며, 본 연구에서는 고분자 소재의 최상층에 코팅하여 보호막으로 이용하였다. 고분자 윈도우에 산화물 다층 박막을 코팅하면 코팅되지 않은 기판과 비교하여 투과율이 향상되었으며 보호막으로 코팅된 비정질 탄소 박막에 의해서 일어나는 투과율 저하를 부분적으로 상쇄하는 효과를 보였다. 산화물 다층 박막의 수는 광학 분야에서는 주로 5-7층을 이용하지만 고분자 소재는 코팅 공정이 길어지면 열 변형이 일어날 수 있기 때문에 산화막의 층수를 낮추는데 초점이 맞춰졌다. 5층과 3층으로 코팅된 산화물 박막 모두 투과율이 향상되었으며 3층에 비해서 5층의 투과율 향상효과가 큰 것으로 나타났다. 고분자 소재의 투과율은 평균 약 90%이었으며 산화물 다층 박막과 비정질 탄소 박막을 코팅한 후 투과율이 약 81%로 측정되었다. 비정질 탄소 박막과 산화물 다층 박막을 적절하게 설계하고 코팅한다면 고분자 소재의 보호막으로 이용될 수 있을 것으로 판단된다.

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반복적인 충격하중을 받은 PC 플라스틱 재료의 변형 및 수명 평가 (Deformation and Life Evaluation of PC Plastic Materials Subjected to Repeated Impact Loads)

  • 이진경
    • 한국산업융합학회 논문집
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    • 제23권4_2호
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    • pp.611-616
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    • 2020
  • Polycarbonate (PC) materials having electrical insulation properties, are thermoplastic material and are easily processed, have excellent strength and heat resistance characteristics, and also have transparent and hard characteristics. In this study, we tried to derive the ε-N curve of strain-life, which shows the relationship between the strain characteristics and the life of the material when repeated impact loads are applied to the PC plastic material. As the impact load increased to 3.0kg, 4.0kg, 5.0kg, and 6.0kg, the strain also increased linearly to 0.033, 0.041, 0.046, and 0.055. At 3.0kg of mass impact, the test piece broke with 12000 impact cycles, 8400 times at 3.5kg, 7400 times at 4.0kg, 6600 times at 4.5kg, 4700 times at 5.0kg, 3000 times at 5.5kg, and 1000 times at 6.0kg. The number of fractures exponentially decreased as the load gradually increased. Using these results, an ε-N curve for PC plastic was derived.

성인용 공기구동식 심실보조장치의 모의순환실험 (In Vitro Test of an Adult-Sized Pneumatic Type Ventricular Assist Device)

  • 김상현;장병철;김원기;김남현;조범구
    • 대한의용생체공학회:의공학회지
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    • 제14권2호
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    • pp.163-167
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    • 1993
  • We developed a ventricular assist device(VAD) to be used as a bridge to heart transplantation or a circulatory assist device for patients with end-stage heart disease or poor myocardial function after cardiac surgery. It is a pneumatic and diaphragm-type VAD and its stroke volume is 90 cc. The upper housing and diaphragm is made of a segmented polyurethane and the lower back plate is made of a polycarbonate. Two Carbomedics$^R$ mechanical valves are used as inlet and outlet valves. It was tested in vitro and the cardiac output of the VAD was 7 L/min at a heart rate of 70 bpm. The line pressure from a pressure transducer inserted in the pneumatic line was recorded and compared with the ideal pressure tracing.

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스윙 암 타입 초소형 광 픽업 시스템의 방열 설계 (Micro Thermal Design of Swing-Arm Type Small Form Factor Optical Pick-up System)

  • 이지나;김홍민;강신일;손진승;이명복
    • 정보저장시스템학회논문집
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    • 제2권1호
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    • pp.21-25
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    • 2006
  • The new multimedia information environment requires smaller optical data storage systems. However, one of the difficulties encountered in designing small form factor(SFF) optical pick-up is to emit the heat which is generated from laser diode(LD). Heat generated at the LD can reduce the optical performance of the system and the lifetime of LD. Therefore, it is important to include the thermal design in the design stage of SFF optical pick-up system for high performance and the longer lifetime of LD, and furthermore, to analyze the thermal characteristics of LD in detail micro heat transfer analysis is necessary. In the present study, micro heat transfer analysis was performed using the finite element method for the $28{\times}11{\times}2mm^3$ super slim swing-arm type optical pick-up actuator for Blu-ray disk. Two different materials were used for a swing-arm; a double layer polycarbonate/steel structure and a single aluminum structure.

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고속 회전 유연 디스크 시스템에서 곡면 안정기에 가공된 모세관형 오리피스의 감쇠계수 해석 (An Analysis of Damping Coefficients for Capillary Type Orifices on a Curved Stabilizer used in a High Speed Rotating Flexible Optical Disk System)

  • 송기욱;임윤철
    • 정보저장시스템학회논문집
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    • 제7권1호
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    • pp.25-30
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    • 2011
  • In the last couple of years, the flexible optical disk(FOD) system that consists of a thin polycarbonate(PC) film of 95 ${\mu}m$ thick, a rigid stabilizer, and a high speed spindle motor has been spot-lighted as the next-generation optical system for archival use of digital data. The air film between the rotating disk and stabilizer provides a means for damping out the lateral disk vibrations. However, its damping-capability drops significantly as the rotational speed of the disk exceeds a specific limit and, eventually, the disk vibration propagates inward causing the whole span of the disk exhibits large vibration amplitudes. Based on the numerical simulations as well as the experimental results, the present work aims to evaluate the damping coefficient of the air-film near the outer region of the disk where the capillary type orifices are applied to the edge of the curved stabilizer.

하이브리드 방식 (CNC+Laser)을 이용한 폴리머용접공정 (Hybrid (CNC+Laser) Process for Polymer Welding)

  • 유종기;이춘우;최해운
    • Journal of Welding and Joining
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    • 제28권3호
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    • pp.42-48
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    • 2010
  • Polycarbonate (PC) and Acrylonitrile Butadiene Styrene (ABS) were welded by a combination of a diode laser and a CNC machining center. Laser beam delivered through the transparent PC and was absorbed in an opaque ABS. Polymers were melted and joined by absorbed and conducted heat. Experiments were carried out by varying working distance from 44mm to 50mm for the focus spot diameter control, laser input power from 10W to 25W, and scanning speed from 100 to 400mm/min. The weld bead and cross-section were analyzed for weld quality, and tensile results were presented through the joint force measurement. With focus distance at 48mm, laser power with 20W, and welding speed at 300mm/min, experimental results showed the best welding quality which bead size was measured to be 3.75mm. The shear strength at the given condition was $22.8N/mm^2$. Considering tensile strength of ABS is $43N/mm^2$, shear strength was sufficient to hold two materials. A single process was possible in a CNC machining system, surface processing, hole machining and welding. As a result, the process cycle time was reduced to 25%. Compared to a typical process, specimens were fabricated in a single process, with high precision.

Measurement of the Elemental Composition in Airborne Particulate Matter Using Instrumental Neutron Activation Analys

  • Chung, Yong-Sam;Lim, Jong-Myoung;Moon, Jong-Hwa;Kim, Sun-Ha;Cho, Hyun-Je;Kim, Young-Jin
    • Nuclear Engineering and Technology
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    • 제36권5호
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    • pp.450-459
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    • 2004
  • For the evaluation of emission sources by air sampling, airborne particulate matter for fine (<2.5 ${\mu}m2$ EAD : $PM_{2.5}$) and coarse partical (2.5-10 ${\mu}m2$ EAD : $PM_{2.5-10}$ fractions were collected using a Gent stacked filter unit low volume sampler and two types of polycarbonate filters. Air samples were collected twice monthly at two regions in and around Daejeon city in the Republic of Korea from January to December 2002. Monthly mass concentration of $PM_{2.5}$ and $PM_{2.5-10}$ were measured and the concentrations of 10 marker elements (Al, Sc, Ti ; Na, Cl ; As, V. Sb, Br, Se) were determined by an instrumental neutron activation analysis. Analytical quality control was corried out using certified reference materials. Enrichment factors were also calculated from the monitoring data to classify the anthropogenic and crustal origins.

PC 펠렛의 마이크로웨이브 건조를 위한 에너지 효율 분석 (Analysis of Energy Consumption for Microwave Drying in PC Pellet)

  • 이현민;김재경;전의식
    • 반도체디스플레이기술학회지
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    • 제20권4호
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    • pp.44-48
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    • 2021
  • Semiconductor inspection equipment makes components using materials with insulating properties for functional inspection including current and voltage of semiconductor parts. A representative insulating material is plastic, and plastic is made of a component through an injection process using plastic pellet. When plastic pellets contain excessive moisture, problems such as performance degradation and product surface defects occur. To prevent this, pre-drying is essential, and the heat convective type is the most applied. However, the heat convective type has a problem of low consumption efficiency and a long drying time. Recently, many studies have been conducted on a drying method using microwaves due to high energy efficiency. In this paper, drying was performed using a microwave for drying PC pellets. Energy consumption and drying efficiency analyzed by set up an experimental apparatus of heat convective, microwave, and hybrid(heat convective + microwave) types. It was confirmed that energy consumption and drying efficiency were high when drying using microwaves, and it was confirmed that the hybrid method improved drying performance compared to the heat convective method. It is expected that the research results of this paper can be used as basic data for drying plastic pellets using microwave.