• Title/Summary/Keyword: POLYCARBONATE

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Synthesis and Electrical Properties of Polypyrrole Nanotubules (Polypyrrole Nanotubules의 합성과 전기적 특성)

  • 조영재;김현철;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.544-547
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    • 2000
  • Polypyrrole (PPy) was chemically synthesized within the pores of nanoporous polycarbonate (PC) Particle Track-etched Membranes (nano-PTM). Hollow tubules are formed because polypyrrole initially deposits on the surface of the pores walls. By running successive syntheses, we have obtained wires (filled tubules). The redox property of PPy nanotubules was investigated by cyclic voltammetry. The redox potential was lowered as much as 0.5V vs. Ag/AgC1, comparing with electrosynthesized PPy film. It suggests that an electron hopping mechanism of PPy nanotubules was improved. Electric conductivity of PPy nanotubules and nanowire was evaluated. We obtained good electric conductivity of PPy nanotubules even in the neutral state. The conductivity and activation energy were $10^1$ order at the room temperature and 25.3 meV respectively.

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Electrochemical Properties of Polypyrrole Nanotubules Enzyme Electrode Immobilized with Glucose Oxidase (포도당 산화효소가 고정화된 Popyrrole Nanotubules 효소전극의 전기화학적 특성)

  • 김현철;구할본;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.909-912
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    • 2000
  • We synthesized polypyrrole (PPy) nanotubules by oxidative polymerization of the pyrrole monomer within the pores of a polycarbonate template. The electrochemical behavior was investigated using cyclic voltammetry. The redox potential was about -0.5 V vs. Ag/AgCl reference electrode, while the potential was about 0 V for PPy film. It is considered as the backbone grows according to the pore wall. Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. By electrochemical doping of glucose oxidase (GOx) on PPy nanotubules, an enzyme electrode has been fabricated. The kinetic parameter of biochemical reaction with glucose was evaluated. The formal Michaelis constant and maximum current calculated by computer were about 11.4 mmol $dm^3$ and 170.85 A respectively. Obviously, an affinity for the substrate and current response of the PPy nanotubules enzyme electrode are rather good, comparing with that of PPy film.

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Electrical and Optical Properties of CdS Thin Films grown on the Flexible Substrate (유연한 기판위에 성장된 CdS 박막의 전기적, 광학적 특성)

  • Kim, Young-Dong;Na, Young-Il;Lee, Jae-Heong;Jung, Hak-Kee;Jung, Dong-Su;Lim, Dong-Gun;Yang, Kea-Joon;Yi, Jun-Sin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.276-279
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    • 2004
  • CdS thin films on polymer substrates such as polycarbonate(PC) and polyethylene terephthalat(PET) have many merits such as light weight, small volume and can make the obtained devices folded, easily carried. In present work, CdS thin films on glass, PC, and PET substrates have been prepared by chemical bath deposition. The structural and optical propertied of the films depending on substrate types have been investigated.

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Preparation of thransparent conductive film using flexible substrates (연성기판에 증착한 투명전도막의 제작)

  • Cho, Bum-Jin;Keum, Min-Jong;Kim, Kyung-Hwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.04a
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    • pp.39-40
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    • 2006
  • We prepared ZnO:Al (AZO) thin films on polycarbonate (Pc) and polyethersulfon (PES). Because the polymer substrate has weak thermal resistance. The AZO thin films were deposited at room temperature by facing targets sputtering (FTS) method In the work, AZO thin films were deposited with different thickness in 1mTorr and $O_2$ gas flow rate 0.05. The electrical, optical and crystallographic properties were measured From the results, the resistivity of $7.3{\times}10^{-4}{\Omega}cm$ and transmittance of over 80% in visible range were obtained.

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Effects of Sputter Power on the Structural and Optical Properties of CdS Thin Films (CdS 박막의 구조적, 광학적 특성에 미치는 스퍼터 전력 효과)

  • Lee, Jae-Hyeong;Choi, Sung-Hun;Jung, Hak-Kee;Lee, Jong-In;Lim, Dong-Gun;Yang, Kea-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.109-110
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    • 2005
  • Cadmium sulphide (CdS) films have been prepared on polycarbonate (PC), polyethylene terephthalate (PET), and Coming 7059 substrates by r.f. magnetron sputtering technique at room temperature. A comparison of the properties of the films deposited on polymer and glass substrates was performed. In addition, the influence of the sputter power on the structural and optical properties of these films was evaluated.

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Dependence of Substrate Type on the Properties of CdS Films deposited by r.f. magnetron sputtering (기판 종류에 따른 스퍼터 증착된 CdS 박막의 구조적, 광학적 특성)

  • Lee, Jae-Hyeong;Choi, Sung-Hun;Jung, Hak-Kee;Lee, Jong-In;Lim, Dong-Gun;Yang, Kea-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.145-146
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    • 2005
  • Cadmium sulphide (CdS) films have been prepared on polycarbonate (PC), polyethylene terephthalate (PET), and Coming 7059 substrates by r.f. magnetron sputtering technique at room temperature. A comparison of the properties of the films deposited on polymer and glass substrates was performed. In addition, the effect of the sputter pressure on the structural and optical properties of these films was evaluated.

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A Study on the Improvement of Calsium Test (Calsium Test의 정밀도 향상을 위한 연구)

  • Han, Jin-Woo;Hwang, Jung-Yeon;Seo, Dae-Shik;Kim, Young-Hun;Moon, Dae-Kyu;Han, Jung-In
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05a
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    • pp.169-172
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    • 2005
  • 공정시 플라스틱 기판의 변형을 방지하기 위해 PC(Polycarbonate) 기판을 약 12시간 동안 pre-annealing시킨 다음 SiN(silicon nitride)와 PI(Poly-imide)를 각각 Sputter와 Spin-Coater를 이용하여 Coating하였다. 완성된 PC 기판위에 Themal Evaporation으로 Calsium을 증착한 뒤 Al을 올렸다. Calsium 증착 된면에 삼성 코닝의 글래스를 UV resin으로 부착 시킨 다음 상온에서 투습률을 측정하였다. 측정 간격은 12시간으로 하였으며 Calsium Test 의 정확도 향상을 위해 CCD Camera로 측정하여 컴퓨터로 분석하였다. 그래픽 저장 파일은 저장시 이미지 손실을 방지하기 위해 Bitmap방식을 그대로 사용 하였으며 정확도 향상을 위한 분석 프로그램은 MicroSoft 사의 Visual C++로 작성하였다. 화상 처리 면적은 컴퓨터 시스템의 처리 속도를 감안하여 70*70 으로 하였다.

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Characteristics of ITO thin films prepared on PC substrate (PC 기판상에 제작된 ITO 박막의 특성)

  • Kim, Kyung-Hwan;Cho, Bum-Jin;Keum, Min-Jong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.420-421
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    • 2006
  • The ITO thin films were prepared by FTS (Facing Targets Sputtering) system on polycarbonate(PC) substrate. The ITO thin films were deposited with a film thickness of 100nm at room temperature. As a function of sputtering conditions, electrical and optical properties of prepared ITO thin films were measured. The electrical and optical characteristics of the ITO thin films were evaluated by Hall Effect Measurement(EGK) and UV-VIS spectrometer(HP), respectively. From the results, the ITO thin film was deposited with a resistivity $8{\times}10^{-4}[{\Omega}-cm]$ and transmittance over 80%.

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Dependence of Substrate Type on the Properties of ZnO Films deposited by r.f. magnetron sputtering (ZnO 박막의 기판종류에 따른 구조적, 광학적 특성)

  • Lee, Dong-Jin;Lee, Jae-Hyeong;Ju, Jung-Hun;Song, Jun-Tae;Lee, Kyu-Il;Yang, Kea-Joon;Lim, Dong-Gun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.125-126
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    • 2006
  • ZnO Films have been prepared on polycarbonate (PC), polyethylene terephthalate (PET), and Coming 7059 substrates by r.f. magnetron sputtering technique. A comparison of the properties of the films deposited on polymer and glass substrates was performed. In addition, the effect of the sputter power on the structural and optical properties of these films was evaluated.

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A study on Linear Pattern Fabrication of Plate-type PC (PC소재의 선형 패턴 제작에 관한 연구)

  • Joung, Y.N.;Lee, E.K.;Kang, C.G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.277-280
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    • 2008
  • Recently, a demand of nano/micro patterned polymer for display or biochip has been rising. Then many studies have been carried out. Nano/micro-embossing is a deformation process where the workpiece materials is heated to permit easier material flow and then forced over a planar patterned tool. In this work, the hot-emboss process is performed with different forming conditions; forming temperature, load, press hold time, to get the proper condition for linear pattern fabrication on plated-type polymers (PC). Replicated pattern depth increases in proportion to the forming temperature, load and time. Reduction of the workpiece thickness increases according to press hold time. In process of time, reduction ratio of workpiece thickness decreases because of surface area increment of the workpiece and pressure decline on it.

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