• Proceedings of the Polymer Society of Korea Conference
• /
• 2006.10a
• /
• pp.371-372
• /
• 2006

Poly(${\varepsilon}-caprolactone$) (PCL) is a highly crystalline polymer that is miscible with several amorphous polymers including chlorinated polyether, poly(vinylchloride), poly(hydroxyether) and Bisphenol A polycarbonate. The crystallization behavior of miscible blend of amorphous/crystalline polymers has widely been studied. Generally a depression of the crystallization ability has been found with addition of amorphous component because of the reduction of chain mobility, the change of free energy of nucleation as a result of a specific interaction, and so on [1]. In this work, for the first time, the blend of PCL and copolymer of polyurethane containing polycaprolactone as a soft segment is considered. The structural similarity of TPU soft segment with PCL affects on formation of the miscible component and crystallization behavior of PCL in the blend. This has been studied using differential scanning calorimetry (DSC) and Wide-angle X-ray Scattering (WAXS).

• YAKHAK HOEJI
• /
• v.23 no.3_4
• /
• pp.147-152
• /
• 1979

Experiments were carried out to investigate for the interaction between FAD solution and synthetic resin containers made of polyvinylchloride(PVC), polyethylene(PE), and polycarbonate(PC), and for the effect of glycyrrhizine or malic acid on stabilization of FAD in aqueous solution by accelerated stability analysis. Analysis of FAD was determined by means of spectrometer and by separating by paper chromatography and metal ions were detected by atomic absorption spectrophotometer, which were extracted from containers by means of Food and Additive Regulation Standard. The thermal decomposition of FAD in aqueous solution was pseudo first order reaction and it was inhibited by adding glycyrrhizine or malic into the solution. PVC, PE and PC containers accelerated the decomposition of FAD in solution. It is assumed that bivalent heavy metals in resin containers may catalize the hydrolysis of FAD. The metals detected from the containers were Ca, Zn, Cu, Fe, Pb and Cd. And the total amounts of detected metals from PVC were 6.2mcg/cm$^{2}$, PE, 5.5mcg/cm$^{2}$, and PC, 2.7mcg/cm$^{2}$ which were proportional to the rate constant of FAD decomposition in aqueous solution.

• The Korean Journal of Rheology
• /
• v.8 no.2
• /
• pp.119-128
• /
• 1996

폴리프로필렌(PP)/폴리카보네이트(PC) 블렌드의 유변학적 고찰을 통해 블렌드의 수 축현상과 분상상의 변형의 연관성을 연구했다. 블렌드의 수축현상은 압축과정에서 변형됐던 분산상이 고온에서 다시 원래의 무변형 상태로 복귀하면서 나타나는 탄성변형의 풀림으로 추정되고 압출팽윤의 데이터와도 부합된다. 압출온도를 최대한 낮게 해서(25$0^{\circ}C$) 제조한 블 렌드의 경우가 최대한 높게 한 경우 (29$0^{\circ}C$)보다 수축이더 큰 사실을 설명하기 위하여 순수 PC와 PP의 전단점도비와 신장점도비를 측정 비교한 결과 두 값이 공히 높은 온도의 경우 가 오히려 작게 되어 점성에 의한 분산상의 전단변형이나 신장변형이 수축의 원인이 아니라 는 것을 알아다. 한편 법선응력과 전단응력의 데이터로부터 얻은 물질풀림시간의 비는 낮은 온도의 경우가 작아서 수축현상이 분산상의 탄성에 의한 변형이라는 것을 확인했다.

• The Korean Journal of Rheology
• /
• v.8 no.3_4
• /
• pp.177-186
• /
• 1996

압출가공으로 제조된 Polycarbonate(PC)/Acrylonitrile-Butadiene-Styrene(ABS) 블 렌드의 사출조건에 따른 모폴로지와 기계적 성질의 변화와 그 상관관계를 고찰하였다. 사출 온도와 금형온도가 높아질수록 분산상간의 coalescence 현상이 활발히 진행되었으며 이러한 모폴로지 변화로 인하여블렌드의 인장강도 굴곡강도 그리고 충격강도 등의 기계적 성질이 급격히 저하되었다. 사출온도와 금형온도의 증가에 따른 coalescence의 심화는 높은 온도에 서 연속상과 분산상의 점도가 저하되어 분산상 사이에 존재하는 연속상 성분의 배출이 보다 용이하게 이루어져 나타난 현상으로 설명된다. 실용적으로 특정한 상용화제가 투입되지 않 는 PC/ABS 블렌드를 사출공정을 거쳐 제품을 생산할 경우에는 급격한 모폴로지와 물성변 화가 일어나지 않는 범위에서 사출온도를 유지하는 것이 제품의 품질관리 측면에서 매우 중 요하다.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2006.08a
• /
• pp.633-636
• /
• 2006

GE has developed a plastic substrate technology comprised of a superior high-heat polycarbonate substrate film and a unique transparent coating package that provides the ultrahigh barrier to moisture and oxygen, and chemical resistance to solvents used in device fabrication. This contribution will update recent progresses made at GEFlexible Ultra-high Gas Barrier Substrate for Organic Electronics on ultra-high barrier coated plastic substrate, both in batch mode and in roll-to-roll mode

• 한국정보디스플레이학회:학술대회논문집
• /
• 2003.07a
• /
• pp.266-269
• /
• 2003

TFT LCD mode has some well-documented performance limitations, namely limited viewing angle, inversion of the gray scale levels and poor luminance efficiency because of the necessity of using crossed polarisers attached to the display cell. During the last few years many initiatives have been undertaken to solve these problems by incorporation birefringent films of various designs into the LCD module. Controlling the optical performance of LCDs often requires combination of liquid crystal material properties, cell parameters and optical films. Such optical films have traditionally been made with stretched polymer materials such as polycarbonate, but recently coated liquid crystalline materials have been used to give improved optical films which can greatly enhance the performance of LCDs. We have now developed reactive mesogen materials to add ultra-thin optical layers into the display structure, and these allow the potential for many new applications.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.16 no.12
• /
• pp.1115-1120
• /
• 2003

In this paper, we investigated the position dependent stress distribution of indium-tin-oxide (ITO) film on Polycarbonate (PC) substrate by external bending force. It was found that there are the maximum crack density at the center position and decreasing crack density as goes to the edge, In accordance with crack distribution, it was observed that the change of electrical resistivity of ITO islands is maximum at the center and decrease as goes to the edge. From the result that crack density is increasing at same island position as face plate distance (L) decreases, it is evident that the more stress is imposed on same island position as L decreases.

• Carbon letters
• /
• v.11 no.2
• /
• pp.83-89
• /
• 2010

We prepared polycarbonate (PC)/poly(methyl methacrylate) (PMMA)/multiwall carbon nanotube (MWCNT) nanocomposites by co-rotating twin screw extruder at 533 K. Thermal analysis results indicate that the miscibility of PC and PMMA is enhanced by MWCNTs. Bead necklace-like morphology of PMMA-rich phase is observed in PC/PMMA/MWCNT nanocomposites with increasing PMMA weight fraction due to the bead necklace-like morphology. The tensile strength of PC/PMMA (75/25)/MWCNT (1 wt.%) nanocomposite is 3% higher than those of PC/PMMA (75/25) alloy. Suppression of die swell by MWCNT filler is observed in the melt flow of PC/PMMA/MWCNT nanocomposites during extrusion.

• Journal of Ocean Engineering and Technology
• /
• v.12 no.2 s.28
• /
• pp.147-152
• /
• 1998

In this study turbine flowmeters were used to predict volumetric flow rate of each phase in two-phase, gas-liquid, flowing in a vertical tube. To determine volumetric flow rates of two-phase, air-water, flowing vertically upward through the polycarbonate tube(57mm ID-inside diameter), two turbine flow meters were used. For void fraction measurements, two gamma densitometers were used at each location of the turbine flow meter, one at the upstream and the other at the downstream. It was determined that the turbine flowmeter's outputs were a function of actual volumetric flow rate of each of the two phases. A two-phase flow model was developed.

• Proceedings of the KSME Conference
• /
• 2003.04a
• /
• pp.1869-1874
• /
• 2003

Polymeric fibers with nanometer-scale diameters are produced by electrospinning. When the electrical forces at the surface of a polymer solution or melt overcome the surface tension then electrospinning occurs. Polyethylene oxide (PEO), Polycarbonate have been electrospun in our laboratory. Electrospun fibers are observed by optical microscopy or scanning electron microscopy. The average diameters of the electrospun fibers range from 300 nm to 30 nm when the electric field strength increasing from 1 kV/cm to 3 kV/cm. The average diameters of the electrospun fibers range from 200 nm to 30 nm when the concentration decreasing from 10 wt% to 4 wt%.