• Journal of Adhesion and Interface
• /
• v.11 no.3
• /
• pp.112-119
• /
• 2010

Poly(methyl methacrylate)/poly(butyl acrylate) PMMA/PBA core-shell composite particles were prepared by the emulsion polymerization of MMA and BA in the presence of different concentration of sodium dodecyl benzene sulfonate (SDBS). The following conclusions are drawn from the measured conversion and particle size distribution, morphology, average molecular weight distribution, observation of film formation and particle formation, glass transition temperature and physical properties of polymerized core-shell composition particles for using adhesive binder. When the concentration of 0.03 wt% surfactant, the conversions of PMMA and PBA core polymerization are excellent as 95.8% for PMMA core and 92.3% for PBA core. Core-shell composite particles are obtained 90.0% for PMMA/PBA core-shell composite particles and 89.0% for PMMA/PBA core-shell composite particles. It is considered that the core and shell particles are polymerized to be confirmed FT-IR spectra and average molecular weight measured with a GPC, formation of the composite particles is confirmed by the film formation from normal temperature, and composition of inside and outside of the composite particle is confirmed by TEM photograph. The synthesized polymer has two glass transition temperatures, suggesting that the polymer is composed of core polymer and shell polymer unlike general copolymers. It is considered that each core-shell composite particle can be used as a high functionality adhesion binder by the measurement of tensile strength and elongation.

• Journal of the Korean Ceramic Society
• /
• v.32 no.1
• /
• pp.131-139
• /
• 1995

In order to improve transmittance and response properties, various compositions of light controllable films were prepared by phase separation method. The optical and response properties were measured with the variation of PMMA/suspension ratio and block copolymer/light polarizing particles. According to the increase of the PMMA/suspension ratio, the separated droplets of suspension were interconnected in the film. Decay time was 2.6 sec when PMMA/suspension ratio was 0.5 : 1 and ΔT(difference of the transmittance at OFF/ON states) was reduced with increasing of the ratio of PMMA/suspension. On block copolymer/light polarizing particles ratio variation, the highest transmittance of the film was 67.4% when its ratio was 0.6 : 1 and decay time was varied from 2.15 to 46.6 sec as block copolymer content increased 0.2 : 1 to 1 : 1.

• Applied Chemistry for Engineering
• /
• v.8 no.4
• /
• pp.575-581
• /
• 1997

UDs were synthesized from two different polyols(PTMG, PBEAG), ionic chain extender(DMPA), EDA with $H_{12}-MDI$. PU/PMMA hybrids were prepared with free radical polymerization of MMA monomer in MMA-swelled PUD. PUD particle size and film properties were investigated ionic content and polyol type. Mechanical and thermal properties of PU/PMMA hybrid film were studied in terms of PU's ionic content and the venation of PU/PMMA compositions. As DMPA content increased from 2wt% to 10wt% in PUD, particle size of PUD decreased. PUD's particle size with ester type polyol was found to be smaller then ether type polyol used. Phase separation between hard segment(HS) and soft segment(SS) with ionic contents in PU was shown by the thermal, mechanical property measurement. Although the composition of MMA was changed from 0 to 40 wt% in PU/PMMA hybrid, the particle size of the hybrid did not increase. Using the ester type polyol, tensile strength of hybrid was found to increase by 2wt% - 6wt% DPMA content, but as higher content the strength of hybrid decreased. Moreover with the ether type polyol, tensile strength of hybrid was observed to increase by 2wt% - 4wt% DMPA content, while decreasing at higher content. PU and PMMA polymer molecule being mixed in molecular level was confirmed from the pattern of $T_g$ in DSC thermogram.

• Composites Research
• /
• v.24 no.4
• /
• pp.1-4
• /
• 2011

In this work, we successfully fabricated graphene oxide (GO) and GO-based PMMA composite fiber and nylon films. Dynamic mechanical and tensile properties of PMMA-GO composite fiber showed that GO is efficient reinforcement for polymer matrices. However, Nylon 6,6-GO composite films showed low reinforcement efficiency in terms of dynamic mechanical and tensile properties due to the colloid instability of GO in formic acid at a low pH level.

• Proceedings of the Korean Fiber Society Conference
• /
• 2003.04a
• /
• pp.60-63
• /
• 2003

Smart 재료는 외부의 환경으로부터 자극을 받을 경우 형상, 색, 전기적 또는 광학적 특성 등이 변할 수 있는 소재를 말한다. 기존의 재료들은 단지 주어진 환경변화를 수동적으로 받아들이는 데 대하여 smart 재료는 이런 한계를 넘어 생물체처럼 환경에 반응한다는 점에서 앞으로 새로운 소재로 각광받을 수 있을 것이다. 변색성 재료도 이와 같은 중요한 smart 소재에 해당하는데, 물질에 따라 광, 온도, 화학물질, 전기장 등의 외부 환경조건에 응답할 수 있다. (중략)

• Applied Chemistry for Engineering
• /
• v.21 no.3
• /
• pp.317-322
• /
• 2010

In this study, poly(methyl methacrylate) (PMMA) was treated with changing mixing ratios of $F_2$ and $O_2$ using oxyfluorination method for hydrophilic modification of PMMA film. For the characterizations of oxyfluorinated PMMA surface, contact angle, surface free energy, X-ray photoelectron spectroscopy (XPS) and optical transmittance (UV-vis) were carried out. After the oxyfluorination, PMMA surface became more hydrophilic showing the decrease of water contact angle from $69^{\circ}$ to $44^{\circ}$. So, surface free energy of oxyfluorinated PMMA film was increased from 46 to $58\;mN\;m^{-1}$. These results are attributed to hydrophilic functional groups such as hydroxyl group formed oxyfluorination method on the PMMA surface. From XPS results, it was confirmed that O/C concentration ratio on the surface of PMMA was increased, the amount of C-OH bonding which shows hydrophilicity was also largely increased from 6.7 to 24.8% with increasing fluorine partial-pressure via the oxyfluorination, The oxyfluorination conditions, room temperature, 1 bar with one mixture ratio of $F_2$ to $O_2$ had little influence on optical transmittance properties of PMMA film but enhanced its surface hydrophilicity. This result suggests that oxyfluorination method could be useful to change hydrophobic PMMA surface to hydrophilic.

• Proceedings of the Optical Society of Korea Conference
• /
• 2000.02a
• /
• pp.134-135
• /
• 2000

LCD의 전력소모중 약 70%를 차지하는 부분이 백라이트 유닛이다. 전세계적으로 저전력, 고화질, 대면적의 LCD 디스플레이를 개발하기 위한 연구가 활발히 진행중이다. 주로 백라이트 유닛을 구성하는 입사광학계와 도광체 및 프리즘 필름 등을 기존 제작공정 내에서 개선하는 것에 연구 개발의 초점이 맞추어져 있다. 본 연구는 기존의 개선 방법에서 벗어나 도광판의 형태와 산란입자의 크기에 따른 산란정도를 조절하여 기존의 도광판보다 더 나은 산란효율을 얻고자 한다. 이를 위해 투명도와 경도가 우수한 PMMA(polymethyl methacrylate)에 다양한 산란자를 투입하여 도광판을 제작한다. 도광판의 실제 제작 이전에 고효율 도광판속에서의 정확한 산란전산모사를 필수적으로 선행하여야 한다. 따라서 광산란 측정장치를 제작하여 산란자의 종류에 따른 원통형 도광체에서 측정한 산란강도와 산란전산모사에서의 결과를 비교 분석하여 저전력, 고화질, 대면적의 백라이트 유닛을 개발하기 위한 기초 자료로 사용하고자 한다. (중략)

• Polymer(Korea)
• /
• v.37 no.6
• /
• pp.744-752
• /
• 2013

The miscibility between poly(L-lactide) (PLLA) and poly(methyl methacrylate) (PMMA) was investigated using thermal analyses for the purpose of developing birefringence-free material at oriented state. The effect of methyl acrylate (MA) units as comonomer of PMMA on the miscibility was also studied. All the blends prepared in this study show composition-dependent single $T_g$'s between those of blend components and high transparency over the visible region, indicating the miscibility at molecular level and no discernible effect of MA units on it. No phase separation was observed at elevated temperature of $280^{\circ}C$, higher than the degradation of PLLA and PMMA. The interaction energy density in PLLA/PMMA blends with 17 mol% of MA was measured to be $-0.74J/cm^3$ from the equilibrium melting temperature depression based on the Hoffman-Weeks method. The blends show zero-${\Delta}$n behavior at a specific mixing ratio and the drawing ratio of 3 due to compensation of intrinsic orientation birefringence. Birefringence dispersion of PLLA/PMMA5 blends was also measured to examine the possibility for quarter-wave plates or polarizer protective films.

• Journal of the Korean Applied Science and Technology
• /
• v.21 no.3
• /
• pp.259-266
• /
• 2004

Film properties of monodispersed model composite latexes with particle size of 190 nm, which consist of n-butyl acrylate as a soft phase monomer and methyl methacrylate as a hard phase monomer with different morphology was examined. Five different types of model latexes were used in this study such as random copolymer particle, soft-core/hard-shell particle, hard-core/soft-shell particle, gradient type particle, and mixed type particle. Tensile strength and tensile elongation at break of final films were evaluated. Those properties can be interpreted in terms of PBA/PMMA phase ratio and their morphology. The interfacial adhesion strength was also evaluated using $180^{\circ}$ peel strength measurement and cross hatch cutting test.

• Applied Chemistry for Engineering
• /
• v.22 no.6
• /
• pp.691-696
• /
• 2011

Organic-inorganic hybrid coating solutions were prepared by using a sol-gel method for transparent film. In this study, colloidal silica (CS) and alkoxy silane such as vinyltrimethoxysilane (VTMS), and [3-(methacryloyloxy)]propyltri methoxy silane (MAPTMS) were used in various conditions such as types of organic silane, weight ratios of CS to silane and reaction times. Coating solutions which were bar coated on the PET (polyethyleneterephthalate) film and cured were investigated on the chemical and physical properties. The pencil hardness and adhesion of coating films were increased with increasing the organic silane content in the coating solution compared to that of PMMA (polymethamethylcrylate) coating solution.