• Journal of the Korea institute for structural maintenance and inspection
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• v.25 no.1
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• pp.25-32
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• 2021

For developing the durable eco-concrete, water-repellent and hydrophobic emulsion were prepared by stirring and mixing polymethyl hydrosiloxane and polyvinyl alcohol. After adding the PMHS emulsion cement paste, the hydration reaction characteristics and the change in chemical composition were analyzed through BSE and EDS analysis, and the micropores were evaluated by MIP test. Cement mixed with PMHS emulsion was analyzed to increase the hydration reactivity and to decrease the capillary porosity, but it was found that the capillary porosity varies depending on the degree of dispersion of the emulsion in the cement paste. In the case of the emulsion containing metakaolin, there was little difference in hydration degree and porosity from the case of using only the PMHS emulsion. However, when the cement surface was coated with PMHS emulsion, the contact angle was found to increase significantly compared to OPC, and it was analyzed that especially when PVA fiber was used together, it changed to a hypohydrophobic surface.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.2
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• pp.127-134
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• 2021

A hydrophobic emulsion consisting of PMHS and PVA was mixed into a cement mortar to observe changes in cement hydrate and microstructure, and to experimentally evaluate compressive strength and flexural strength. The hydrophobic emulsion was added with metakaolin and PVA fibers, and the stirring speed and sequence were adjusted to prepare a shell-concept hydrophobic emulsion. It was then mixed when mixing mortar to enhance filling of the internal pores and change of the hydrates. It was observed that the mortar mixed with a hydrophobic emulsion was filled with micropores and a coating film was formed on the surface of the hydrates by the emulsion. It was analyzed that the total pore area and porosity of the mortar mixed with the emulsion decreased from 30% to 60% compared to OPC, excluding the 50MK variable, which was extremely reduced and the median pore diameter decreased in some variables. It was also found that the compressive strength of the mortar mixed with emulsion 1% was increased up to 20%, but the strength of the mortar specimen mixed with 2% decreased to 50%.