• Title/Summary/Keyword: PL 스펙트럼

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(Morphology and Optical Properties of $Sm^{2+}$-doped $10Al_2O_3-90SiO_2$ Thin Films Prepared by Sol-Gel Process and Spin Coating Technique) (솔-젤법과 스핀 코팅에 의해 제조된 $Sm^{2+}$가 도핑된 $10Al_2O_3-90SiO_2$ 박막의 구조 및 광학적 특성)

  • 장기완;김상수;김일곤;조은진;정용화;박성태;이용일;김창대;서효진
    • Proceedings of the Optical Society of Korea Conference
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    • 2002.07a
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    • pp.134-135
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    • 2002
  • Sm$^{2+}$가 도핑된 불화물 결정은 실온에서 영구적 스펙트럼 홀 생성이 나타나며, 이러한 실온에서의 영구적 스펙트럼 홀 생성은 새로운 광 메모리의 개발에 매우 중요하므로 많은 관심을 받고 있다. 본 연구에서는 Sm$^{2+}$가 도핑된 10Al$_2$O$_3$.90SiO$_2$ 박막을 제조하여 SEM 및 발광 스펙트럼(Photo-Luminescence; PL)을 측정함으로서 제조된 박막의 구조적, 광학적 특성을 조사하였다. (중략)

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Characteristics of c-axis oriented sol-gel derived ZnO films (C-축으로 정렬된 sol-gel ZnO 박막의 특성)

  • 김상수;장기완;김인성;송호준;박일우;이건환;권식철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.2
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    • pp.49-55
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    • 2001
  • ZnO films were fabricated on p-type Si(100) wafer ITO glass and quartz glass by the sol-gel process using zinc acetate dihydrate as starting material. A homogeneous and stable solution was prepared by dissolving the zinc acetate dihydrate in a solution of 2-methoxyethanol and monoethanolamine (MEA). ZnO films were deposited by spin-coating at 2800 rpm for 25 s and were dried on a hot plate at $250^{\circ}C$ for 10 min. Crystallization of the films was carried out at $400^{\circ}C$~$800^{\circ}C$ for 1 h in air. X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), UV-vis transmittance spectroscopy, FTIR transmittance spectroscopy and Photoluminescence (PL) spectroscopy measurements have been used to study the structural and optical properties of the films. ZnO films highly oriented along the (002)plane were obtained. In all cases the films were found to be transparent (above 70%) in visible range with a sharp absorption edge at wavelengths of about 380nm, which is very close to the intrinsic band-gap of ZnO(3.2 eV). The low temperature band-edge photoluminescence revealed a complicated multi-line structure in terms of bound exciton complexes and the phonon replicas.

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Ordering in InGaAsP Epitaxial Layers Grown by low Pressure metalorganic Chemical Vapor Deposition (저압 MOCVD 방법으로 성장된 InGaAsP 에피층에서의 ordering 현상)

  • 김대연;문영부;이태완;윤의준;이정용;정현식
    • Journal of the Korean Vacuum Society
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    • v.7 no.3
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    • pp.187-194
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    • 1998
  • InGaAsP epitaxial layers lattice matched to InP were grown at 600 and $620^{\circ}C$ by low pressure metalorganic chemical vapor deposition. Solid phase composition of group III was controlled by the diffusion flux gas phase to the reachion surface. For the case of group V, the difference of As and P vapor pressure and pyrolysis efficiency of $PH_3$and $AsH_3$ mainly determined their in corporation into solid. An abnormal behavior of peak energy shift was observed below 75K in temperature variant photoluminescence study. This abnormal behavior was explained by the difference in order of ordering which makes spatial variation of energy gap in InGaAsP layer and this explanation was supported by the analyses of transmission electron microscopy and transmission spectroscopy.

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Effect of aging on the optoelectronic properties of a single ZnO nanowire (단일 ZnO 나노선의 광전 특성에 대한 에이징 효과)

  • Keem, Ki-Hyun;Kang, Jeong-Min;Jeong, Dong-Young;Kim, Sang-Sig
    • Journal of IKEEE
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    • v.10 no.2 s.19
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    • pp.161-167
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    • 2006
  • The effect of aging on the optoelectronic properties of a single ZnO nanowire is investigated in this study. The photoluminescence (PL), photocurrent spectrum, current-voltage characteristics, and photoresponse were measured for the as-grown ZnO nanowire and for the same nanowire exposed to air for three months. For the aged nanowire, the broad PL band is weaker, the intensity of the photocurrent is strengthened, and the photoresponse is slower, compared with the as-grown nanowire. It Is suggested in this paper that the observed aging effect on the PL is due to the reduction in the number of oxygen vacancies within the nanowire and that the aging effect on the photocurrent and photoresponse originates from the formation of oxygen vacancies near the surface.

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Preparation and Properties of Eu3+ Doped Y2O3 Nanoparticles with a Solvothermal Synthesis Using the Ethylene Glycol (에틸렌 글리콜을 이용하여 용매열 합성으로 Eu3+가 도핑된 Y2O3 나노 입자의 제조 및 특성)

  • 신수철;조태환
    • Journal of the Korean Ceramic Society
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    • v.40 no.7
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    • pp.709-714
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    • 2003
  • Eu doped $Y_2$ $O_3$ nanoparticles were prepared with the solvothermal synthesis using the ethyleneglycol solvent at 20$0^{\circ}C$ for 3-5 h and then annealed in air at 1000-140$0^{\circ}C$ for 2-4 h. The X-ray diffraction pattern of annealed crystals at 100$0^{\circ}C$ for 2 h could be indexed as pure cubic cell of $Y_2$ $O_3$ phase with lattice parameters a=10.5856 $\AA$ which is very close to the reported data (JCPDS Card File, 41-1105 a=10.6041 $\AA$). Average size of prepared phosphor particles have about 100 nm, which were spherical morphology. The phosphor particle sizes decreased and the emission intensity increased at the annealing temperature. Though PL spectrum analysis, the 3% Eu doped $Y_{2-x}$ $O_3$:E $u_{x}$ $^{3+}$(x=0.06) phosphor showed the excitation spectrum at 250 nm wavelength and the maximum emission spectrum at 611 nm wavelength.

높은 In 조성을 갖는 InGaN 구조의 열처리 변수에 따른 구조 및 광학적 특성

  • Lee, Gwan-Jae;Jo, Byeong-Gu;Lee, Hyeon-Jung;Kim, Jin-Su;Lee, Jin-Hong;Im, Jae-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.228.2-228.2
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    • 2013
  • 본 논문은 InN와 GaN를 교대로 증착하는 교번성장법(Alternate Growth Method)을 이용해 형성한 높은 인듐(Indium) 조성을 갖는 InGaN (HI-InGaN) 구조의 열처리(Rapid Thermal Annealing, RTA) 온도 및 시간에 대한 구조와 광학적 특성을 Double Crystal X-ray Diffraction (DCXRD), Transmission Electron Microscopy와 Photoluminescence (PL) 장비를 사용하여 분석한 결과를 보고한다. DCXRD 스펙트럼에서 HI-InGaN 박막은 GaN(0002)로부터 $2.98^{\circ}$ 분리된 위치에서 회절 신호를 관찰 할 수 있다. 그리고 GaN와 HI-InGaN 신호 사이의 넓은 범위에서 미약하지만 신호가 관찰 되는데, 이는 InN와 GaN 계면에서 발생하는 상호확산 확률의 차이에 기인한 In 조성이 다른 InGaN 신호로 해석할 수 있다. 열처리 온도를 $775^{\circ}C$로 고정하고 시간을 10, 20, 30초로 각각 변화시켜 RTA를 진행한 DCXRD 스펙트럼에서 GaN(0002)로부터 $0.7{\sim}1.1^{\circ}$ 떨어진 위치에서 InGaN 피크를 확인 할 수 있다. RTA 시간이 증가 할수록 HI-InGaN 신호의 위치가 GaN 피크 방향으로 이동하며, 세기가 증가하는 것을 확인 할 수 있다. HI-InGaN의 PL 스펙트럼에서 상온 발광파장은 1369 nm 이며, 반치폭(Line-width)은 51.02 nm을 보였다. RTA 수행 후 발광파장에 따른 광세기가 각각 달라졌으며, 특히 900 nm 부근의 신호가 상대적으로 크게 증가하는 것을 확인할 수 있었다. RTA에 따른 HI-InGaN의 구조 및 광학적 특성 변화를 InN와 GaN 계면에서 In, Ga 원자의 상호확산 효과현상으로 논의할 예정이다.

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Temperature-dependent photoluminescence properties of amorphous and crystalline V2O5 films (비정질과 결정질 V2O5 박막의 온도에 따른 발광특성)

  • Kang, Manil;Chu, Minwoo;Kim, Sok Won
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.5
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    • pp.202-206
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    • 2014
  • In order to investigate the photoluminescence (PL) properties of $V_2O_5$ films, amorphous and crystalline films were prepared by using RF sputtering system, and the PL spectra of the films were measured at the temperatures ranging from 300 K to 10 K. In the amorphous $V_2O_5$ film grown at room temperature, a PL peak centered at ~505 nm was only observed, and in the crystalline $V_2O_5$ film, two peaks centered at ~505 nm and ~695 nm, which is known to correspond to oxygen defects, were revealed. The position of PL peak centered at 505 nm for both the amorphous and crystalline $V_2O_5$ films showed a strong dependence on temperature, and the positions were 2.45 eV at 300 K and 2.35 eV at 10 K, respectively. The PL at 505 nm was due to the band energy transition in $V_2O_5$, and also, the reduction of the peak position energy with decreasing temperature was caused by a decrement of the lattice dilatation effect with reducing electron-phonon interaction.

Optical Properties of HVPE Grown Thick-film GaN on $MgAl_2O_4$ Substrate ($MgAl_2O_4$ 기판위에 HVPE법으로 성장된 후막 GaN의 광학적 특성)

  • Lee, Yeong-Ju;Kim, Seon-Tae
    • Korean Journal of Materials Research
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    • v.8 no.6
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    • pp.526-531
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    • 1998
  • A hydride vapor phase epitaxy (HVPE) method was performed to grow the $10~240\mu{m}$ thick GaN films on (111) spinel $MgAl_2O_4$ substrate. The GaN films on $MgAl_2O_4$ substrate revealed a photoluminescence (PL) characteristics of the impurity doped GaN by the out-diffusion and auto-doping of Mg from $MgAl_2O_4$ substrate during GaN growth. The PL spectrum measured at 10K consists of free and bound excitons related recombination transitions and impurity-related donor-acceptor pair recombination and its phonon replicas. However, the deep-level related yellow band emission was not observed. The peak energy of neutral donor bound excitonic emission and the frequency of Raman $E_2$ mode were exponentially decreased with increasing the GaN thicknesses. and the frequency of E, Raman mode was shifted with the relation of $\Delta$$\omega$=3.93$\sigma$($cm^{-1}$/GPa), where l1 (GPa) is the residual strain in the GaN epilayers.

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A new Implementation of Perceptual LPC Cepstrum and its Application to Speech Recognition (인지 LPC cepstrum의 새로운 구현 및 음성인식에의 적용)

  • Kim, Jin-Young;Choi, Seong-Ho
    • The Journal of the Acoustical Society of Korea
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    • v.15 no.5
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    • pp.61-64
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    • 1996
  • To improve the performance of a recognition system, namely the recognition rate, we propose a hew implementation of perceptual distance using LPC cepstrum(perceptual cepstrum, PLC). The PLC is caculated by convolution of a usual LPC cepstrum and a perceptual lifter(PL). To caculate PL, we define a new weighting function in the linear frequency domain considering the frequency scale(Bark-scale) characteristics. The PL is the inverse Fourier transform of the exponents of the weighting function. We verified our method through the speech recognition experiments. The performance of PLC was compared with that of the rasied sine liftering method.

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Optoelectrical Characteristics of Electrospun PVP Nanofibers Incorporated with ZnS:Mn Nanoparticles (전기방사법으로 제작된 ZnS:Mn/PVP 하이브리드 나노사의 발광특성)

  • Kim, Kwang-Eun;Cho, Kyoung-Ah;Kwak, Ki-Yeol;Yoon, Chang-Joon;Kim, Sang-Sig
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1599_1600
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    • 2009
  • ZnS:Mn 나노입자가 포함된 PVP 고분자 하이브리드 나노사를 전기방사법으로 제작하였다. 하이브리드 나노사의 표면 특성은 주사 전자 현미경으로 관측하였으며, 형광분광광도계와 공초점 주사현미경 (CLSM)을 이용하여 하이브리드 나노사의 발광특성을 조사하였다. 순수한 PVP 나노사와 하이브리드 나노사의 photoluminescence (PL) 스펙트럼 비교를 통하여, 586 nm에서 관찰된 PL 피크는 ZnS:Mn 나노입자에서 기인되었음을 알 수 있었으며, CLSM을 이용하여 ZnS:Mn 나노입자의 발광을 이미지화 하였다.

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