• 한국염색가공학회지
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• 제31권1호
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• pp.14-24
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• 2019

In this study, dyeability of PET fabric was investigated depending on dyeing temperature, pressure, and leveling time using laboratory scale supercritical $CO_2(scCO_2)$ dyeing machine. Dyeing temperature, pressure, leveling time were varied from 100, 120, $130^{\circ}C$, 150, 200, 250bar, 40, 60, 80, 100min, respectively. It is proved that the higher temperature of $scCO_2$ dyeing process, the higher K/S value and the lower $L^*$ value, which in turn means the lower amount of dyeing molecules remained after process done. Compared 200bar with 250bar of dyeing pressure, $scCO_2$ dyeing fabrics under 250bar appeared to have a lower $L^*$ value, a higher K/S value than those from 200bar, meaning that dyeing color turns to darker with higher dyeing pressure. The experiments showed that the most ideal condition for $scCO_2$ dyeing process is $120^{\circ}C$, 250bar for 60 - 100min of leveling time.

• 한국염색가공학회지
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• 제14권1호
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• pp.51-57
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• 2002

In the prior study, the mechanical properties and the dyeability of the easily dyeable polyester grim(EDY) were investigated. In this study, to interpret the dyeing behavior of EDY with C. I. Disperse Violet 1, the thermodynamic parameters of dyeing, such as the standard affinity, the heat of dyeing(the enthalpy change), the entropy change, the diffusion coefficient, and the activation energy of diffusion, were obtained from adsorption isotherms and dyeing rate at various temperatures and compared to these of regular polyester (REG-PET). The heat of dyeing(the enthalpy change) and the entropy change for EDY showed smaller negative values than those for REG-PET. This means that the dye molecules in the EDY are combined more loosely than in the REG-PET and that is due to the flexibility of polymer chains of EDY. The diffusion coefficients of C. I. Disperse Violet 1 into the EDY were larger than those for REG-PET, and the activation energy of diffusion on EDY was smaller than that on REG-PET.

• 한국의류산업학회지
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• 제10권4호
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• pp.560-565
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• 2008

Plantae of the natural material has been broadly used on cloth dyeing by it's specific properties such as eco-friendly and innoxious. However dyeing with natural material on synthetic fiber is nearly impossible due to poor affinity between natural material and synthetic fiber. The method which is binding with micro-capsulized natural material to cloth, used in this study, has low change on quality by external influence. Also this method has high ability in spray effect by broken capsule which comes to pressure and friction when the treated cloth was dressed. And this method is applicable widely from natural fiber to synthetic fiber. The purpose of this study is to develop the multi-functional synthetic material with micro-capsulized Ginseng on PET. Moreover, it was driven by comparison of colormetric properties and fastness between regular dip-dyeing method and binding with micro-capsulized material method. Dyeability showed a little bit low exhaustion but the PET treated by micro-capsule was more or less better than the dip dyed PET. Through the SEM(Scanning Electron Microscope) of PET treated by micro-capsule, it has good residence of capsules even after 5 or 10 times washing. Wash and light fastness were revealed some different grades by each condition but showed high level, in most and the micro-capsulized PET was more improver than regular dip dyed PET.

• 한국의류산업학회지
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• 제10권6호
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• pp.1045-1050
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• 2008

Developing of high technology, productivity of the fiber product has being rapidly increased and also various kinds of advanced treatment process lead consumer's needs to more high functional, clean and healthy goods. Moreover, increasing in the concern of eco-friendly material and processing, it has been getting popular that the dyeing method like as using natural dyes is more eco-friendly and natural-friendly treatment process. The method, used in this study, adhesion by binding with micro-capsulized natural material to fabric has low change in quality by external influence and high ability in spray effect by broken capsule which comes to pressure and friction when it dressed. Also it has wide application from natural fiber to synthetic fiber. The purpose of this study is development of multi-functional synthetic material with micro-capsulized Scutellaria baicalensis on PET. Moreover, it was driven by comparison of colormetric properties and fastness between regular dip-dyeing method and binding with micro-capsulized material method. Dye ability was arranged mostly low exhaustion but the PET treated by micro-capsule was more or less better than the dip-dyeing PET. Through the SEM(Scanning Electron Microscope) of PET treated by micro-capsule, it has good residence of capsules even after 5 or 10 times washing. Wash and light fastness was arranged some different grade by each condition but mostly high achievement and the micro-capsulized PET was more improved than regular dip-dyed PET.

• 한국의류산업학회지
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• 제11권4호
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• pp.661-666
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• 2009

The purpose of this study is to analyze the dyeability of polyester(PET) fabric by thermal bonding with low melting component of bicomponent fiber and to describe the change of physical properties of thermal bonded PET fabrics. The PET fabrics were prepared with regular PET fiber as warp and bicomponent fiber as weft. The bicomponent fiber of sheath-core type was composed with a regular PET core and low melting PET sheath. The thermal bonding of PET fabric was carried out in pin tenter($195^{\circ}C$) for 60 seconds. In this study, we investigated the dye ability and fastness of the dyed PET fabric. Dye ability of E-type dyestuff is higher than S-type dyestuff. In the case of E- type dyestuff, the saturated dyeing time was 10minutes at $130^{\circ}C$. The washing fastness and light fastness were excellent as 4-5grade.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2008년도 제39차 학술발표회
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• pp.49-50
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• 2008

Dyeing and levelness properties of dyed PET woven fabric using a ultra low liquor ratio laboratory dyeing machine have been compared with those of PET woven fabric using a regular laboratory dyeing machine. The dyeing and levelness properties of dyed fabrics using a ultra low liquor ratio laboratory were better than those of dyeing using regular laboratory.

• 한국염색가공학회지
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• 제14권5호
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• pp.277-283
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• 2002

Poly(ethylene terephthalate)(PET) filaments of regular(monodenier 2.08d) and ultramicrofiber (monodenier 0.05d) were treated with dimethylformamide(DMF) to observe the structure change of the PET such as shrinkage, density, X-ray diffraction of the UMF treated with DMF were measured. Also, dyeing experiments were performed to see the effects of DMF. The dyeability was improved by DMF treatments, and the equilibrium dye uptake increased in spite of the increase in the density and birefringence and crystallinity. The heat shrinkage appeared in PET UMF treated PET UMF treated with DMF at $80^\circ{C}$ by TMA, DSC, and Reovibron analysis and $T_m$ peak was shown by DSC analysis.

• Fibers and Polymers
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• 제5권2호
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• pp.134-138
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• 2004

Dyeing properties of a series of 4-amino-4'-fluorosulfonylazobenzene disperse dyes on poly(ethylene terephthalate) (PET) were investigated. Build-up properties and color properties on PET were examined. In particular, the 4-aminoazobenzene dyes containing a nitro group instead of a fluorosulfonyl group at 4'-position were also synthesized in order to compare their dyeing properties on PET with that of 4'-fluorosulfonyl analogues.

• 한국염색가공학회지
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• 제13권3호
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• pp.197-202
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• 2001

The mechanical properties and dyeability of Poly(trimethylene terephthalate)(PTT) were investigated and compared to PET. Glass transition temperature of PTT was lower than that of PET, because amorphous region of PTT is mote flexible. n has smaller molecular and specific stress and larger strain than those of PET, due to the difference of molecular structure. Dyeing transition temperature of PTT was lower by $20^\circ{C}$ than that of PET. Because PTT has flexible chain and zigzag structure, dyeing Fate of PTT is faster than PET and dyeing of PTT is begun at lower temperature. As the hydrophobicity of disperse dyes increased, the ratio of equilibrium dye uptake on PTT to that on PET was increased.

• 한국염색가공학회지
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• 제1권1호
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• pp.26-34
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• 1989

The selective chemical degradation or etching of PET based on an organic amine attack on the ester group. The techniques involves the chemical removal of loss ordered amorphous regions or crystalline regions, which are essentially unaffected by the degradative etchant. Thus, most of previous studies have limited to consideration which has been given to structural changes taking place. Therefore, this study was carried out to investigate surface characterization, dyeing properties of PET film hydrazinolyzed with hydrazine hydrate in methanol. PET film was treated with 30% hydrazine hydrate in methanol at $30^\circ{C}$ for various time intervals. The total surface tension of treated PET increased, the dispersion force decreased and the hydrogen bonding force increased. The equilibrium dye adsorption, dyeing rate and apparent diffusion coefficient of acid dyes increased, and the apparent activation energies of diffusion decreased.