• Title/Summary/Keyword: PET(polyethylene-terephthalate)

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Diffusion of CO2 Molecules in Polyethylene Terephthalate/Polylactide Blends Estimated by Molecular Dynamics Simulations

  • Liao, Li-Qiong;Fu, Yi-Zheng;Liang, Xiao-Yan;Mei, Lin-Yu;Liu, Ya-Qing
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.753-758
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    • 2013
  • Molecular dynamics (MD) simulations have been used to study the diffusion behavior of small gas molecules ($CO_2$) in polyethylene terephthalate (PET)/polylactide (PLA) blends. The Flory-Huggins interaction parameters (${\chi}$) determined from the cohesive energy densities are smaller than the critical value of Flory-Huggins interaction parameters (${\chi}_{critical}$), and that indicates the good compatibility of PET/PLA blends. The diffusion coefficients of $CO_2$ are determined via MD simulations at 298 K. That the order of diffusion coefficients is correlated with the availably fractional free volume (FFV) of $CO_2$ in the PET/PLA blends means that the FFV plays a vital role in the diffusion behavior of $CO_2$ molecules in PET/PLA blends. The slopes of the log (MSD) as a function of log (t) are close to unity over the entire composition range of PET/PLA blends, which confirmes the feasibility of MD approach reaches the normal diffusion regime of $CO_2$ in PET/PLA blends.

Monte Carlo simulation and study of REE/PET composites with wide γ-ray protection

  • Tongyan Cui;Ruixin Chen;Shumin Bi;Rui Wang;Zhongjian Ma;Qingxiu Jia
    • Nuclear Engineering and Technology
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    • v.55 no.8
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    • pp.2919-2926
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    • 2023
  • In this paper, rare earth element (REE)/polyester composites were designed with lanthanum oxide, gadolinium oxide, and lutetium oxide as ray shielding agents, and polyethylene terephthalate (PET) as the base. Monte Carlo simulation was carried out using FLUKA software. We found that the radiation protection performance of the composite is affected by the type and amount of REE; a higher amount of REE equated to a better radiation protection performance of the composite. When the thickness of the composite and total thickness of the REE is constant, the number of superimposed layers inside the composite does not affect its shielding performance. Compared with a single-type REE/PET composite, a mixed-type REE/PET composite has a wider range of γ-ray absorption and better radiation protection performance. When the mass ratio of PET to REE is 2:8 and different types of REE are mixed with equal mass, several 0.2 cm-thick mixed-type REE/PET composites can shield >70% of 60 and 80 KeV γ-rays.

A study on the characteristics of interlace and Mobility of Movable Ion in polyethylene Terephthalate (Polyethylene terephthalate 중의 가동이온의 계면특성과 이동도에 관한 연구)

  • Lee, Ho-Sub;Oh, Keum-Kwon;Kook, Sang-Hoon
    • Proceedings of the KIEE Conference
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    • 1988.11a
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    • pp.233-235
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    • 1988
  • This study investigate that the behavior of movable ion in PET effect on the characteristics of the insulting materials. This examine that movable ion signal to. participation of $Ca^2\;Sb^3$ resulting catalyst refuse and characteristics of activation energy that is need to reionization of movable ion type and neutralized case as measuring characteristics of polarity reversal current or thermally stimulated current.

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Excimer Laser Ablation of Polymer for Electroformed Mold (전주금형 제작을 위한 폴리머의 엑시머 레이저 어블레이션)

  • Lee Jae Hoon;Shin Dong Sig;Suh Jeong;Kim To Hoon
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.12
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    • pp.13-20
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    • 2004
  • Manufacturing process for the microfluidic device can include such sequential steps as master fabrication, electroforming, and injection molding. The laser ablation using masks has been applied to the fabrication of channels in microfluidic devices. In this study, manufacturing of polymer master and mold insert for micro injection molding was investigated. Ablation of PET (polyethylene terephthalate) by the excimer laser radiation could be used successfully to make three dimensional master fur nickel mold insert. The mechanism fur ablative decomposition of PET with KrF excimer laser $({\lambda}: 248 nm, pulse duration: 5 ns)$ was explained by photochemical process, while ablation mechanism of PMMA (polymethyl methacrylate) is dominated by photothermal process, the .eaction between PC (polycarbonate) and KrF excimer laser beam generate too much su.face debris. Thus, PET was adopted in polymer master for nickel mold insert. Nickel electroforming using laser ablated PET master was preferable for replication method. Finally, it was shown that excimer laser ablation can substitute for X-ray lithography of LIGA process in microstructuring.

Comparison of postharvest quality of Aralia elata shoot according to packaging methods

  • Yonghyun Kim;Narae Han;Hyowon Park;Uk Lee;Hyun Ji Eo
    • Food Science and Preservation
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    • v.30 no.4
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    • pp.562-572
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    • 2023
  • In this study, we aimed to evaluate the quality of Aralia elata shoots according to different packaging methods during storage at 2℃. The highest level of dehydration and wilting incidences were observed in polypropylene containers with polyvinyl chloride wrap (PP+PVC), and these levels continually increased during the entire storage period, compared to other packaging methods. The overall marketability of A. elata shoot packaged in polyethylene terephthalate container (PET) and PP with the mineral-coted functional warp (PP+F) constantly declined during storage with a similar level of 38.6 and 36.0% at 15 days in storage, respectively. PP with PET cover packaging (PP+PET) showed the lowest decay and wilting rates during the entire storage, and the wilting score at 10th day was 51.9, 58.0, 51.8% suppressed, as compared to PET, PP+PVC, and PP+F, respectively. Consequently PP+PET packaging effectively decreased the deterioration of A. elata and maintained marketability for 10 days of storage at 2℃.

Electret Characteristics of polyethylene terephthalate for electret installation (전기설비용 polyethylene terephthalate의 electret 특성연구)

  • 국상훈;서장수
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.10 no.3
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    • pp.78-85
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    • 1996
  • This paper experience the mechanism for the electret of polyethyleneterephthalate(PET) by using surface potentail measurement means. We investigated the internal charge production and becoming week by evaporating electrode in sample structure of electret coexist with hetero charge and homo charge, as the study based on two charge theory. We expects that the hetero charge consists of the dipole and ion displacement of internality, the homo charge consists of injected charge of externality.

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