• Korean Chemical Engineering Research
• /
• v.49 no.3
• /
• pp.342-347
• /
• 2011

The effects of compatibilizers on the mechanical and rheological properties of PP/PCL and TPO/PCL blends have been studied. The thermoplastic polyolefin (TPO) consists of PP (80 wt%), EPDM (15 wt%) and Talc (5 wt%). Maleic anhydride grafted polypropylene (PP-g-MAH) and maleic anhydride grafted styrene-(ethylene-co-butene)-styrene copolymer (SEBS-g-MAH) were used as compatibilizers. In mechanical properties of PP/PCL and TPO/PCL blends, tensile strength was increased when PP-g-MAH was used as a compatibilizer, and impact strength was increased when SEBS-g-MAH was used as a compatibilizer. From the results of SEM morphology of PP/PCL blend, PCL droplet size was decreased by the addition of PP-g-MAH. From the results of rheological property, complex viscosity of the PP/PCL and TPO/PCL blends did not change appreciably when the compatibilizers were added. From the results of mechanical, morphological and rheological properties of the blends, PP-g-MAH acted as a compatibilizer to increase the tensile strength of the PP/PCL and TPO/PCL blends. While SEBS-g-MAH acted as a impact modifier to increase the impact strength of the PP/PCL and TPO/PCL blends.

• Journal of the Korean Society of Industry Convergence
• /
• v.8 no.1
• /
• pp.5-10
• /
• 2005

PCL were intercalated into organically modified MMT (PCL-MMT) at $80^{\circ}C$ for 4hrs to prepare the PCL-MMT nanocomposite. PCL-MMT and PCL were mixed mechanically with two-roll mill at $150^{\circ}C$ for 15mins. From the results of XRD and TEM, it were found that PCL-MMT nanocomposite were prepared. And mechanical properties and biodegradation of nanocomposite have been investigated by tensile meter and biodegradability analysis experiment. Because of MMT dispersed homogeneously in PCL matrix, the Young's modulus of the nanocomposite was found to be excellent. But the tensile strength and elongation were decreased as increase of MMT. And MMT dispersed in PCL matrix was almost not affected on the biodegradation of PCL.

• Journal of Veterinary Clinics
• /
• v.27 no.4
• /
• pp.325-329
• /
• 2010

The osteogenic potential of hydroxyapatite/poly $\varepsilon$-caprolactone composite (HA/PCL) scaffolds with matrigel was evaluated in a rat calvarial defect model. Calvarial defect formation was surgically created in Sprague Dawley rats (n = 18). HA/PCL scaffold was grafted with matrigel (M-HA/PCL group, n = 6) or without matrigel (HA/PCL group, n = 6). A critical defect group (CD group, n = 6) did not received a graft. Four weeks after surgery, bone formation was evaluated with radiography, micro computed tomography (micro CT) scanning, and histologically. No bone tissue formation was radiographically evident in the CD group. Bone tissue was radiographically evident in the HA/PCL and M-HA/PCL groups, however, there was more bone-similar opacity in the M-HA/PCL group. Micro CT analysis revealed that the bone volume of the M-HA/PCL group was higher than the HA/PCL group, however, no significant difference was found between the HA/PCL and M-HA/PCL groups. Bone mineral density in the M-HA/ PCL group was significantly higher than in the HA/PCL group (p < 0.05). Histologically, new bone was formed only from existing bone in the CD group, showing concavity without bone formation in the defect. In the HA/PCL group, new bone formation was only derived from existing bone, while in the M-HA/PCL group the largest bone formation was observed, with new bone tissue forming at the periphery of existing bone and around the HA/PCL scaffold with matrigel. The results indicate that the combination of HA/PCL scaffold with matrigel may be an effective means of enhancing bone formation in critical-sized bone defects.

• Polymer(Korea)
• /
• v.25 no.4
• /
• pp.521-527
• /
• 2001

The miscibility, molecular interaction and tensile properties of the blends of poly (${\varepsilon}$-caprolactone) (PCL) with poly(vinyl chloride) (PVC) have been studied. The measured glass transition temperature values of PCL/PVC blends were found to be well fitted by Fox equation. We found that PCL/PVC blends are amorphous up to 23% PCL content. The blends showed the highest Young's modulus and yield strength at 5% PCL content and the highest tensile strength at 11% PCL content. The blends with low contents of PCL(up to 13%) show increased tensile strength and decreased elongation of PCL/PVC blends. Consequently, the antiplasticization phenomenon is observed in the PCL/PVC blends.

• Polymer(Korea)
• /
• v.24 no.1
• /
• pp.48-57
• /
• 2000

Polycaprolactone (PCL) and thermoplastic starch (TPS) blends were prepared. Mechanical properties, thermal property, water absorption, biodegradability by composting and surface morphology of PCL/TPS blends were investigated. The compositions of PCL/TPS blends were 90/10, 80/20, 70/30, 60/40, 50/50, 40/60, 30/70, 20/80, and 10/90. Strength and elongation at break decreased as the content of TPS increased, while modulus increased. DSC thermogram of TPS showed two glass transition temperatures (T$_{g}$ ) at 23$^{\circ}C$ and 126$^{\circ}C$. And TPS proved to be an amorphous polymer because there was no endothermic peak due to the melting of starch crystal. The unchanged melting temperatures and T$_{g}$ 's of PCL/TPS blends revealed that PCL and TPS were not miscible. All of the blends were found to be mechanically compatible but phase separated in each other. After 45 days composting, the biodegradability of PCL was 44% and that of PCL/TPS blends increased as the contents of TPS increased.

• Journal of the Korean Geotechnical Society
• /
• v.17 no.5
• /
• pp.197-207
• /
• 2001

1980년대 이래 국내 터널의 시공법은 원지반의 강성을 활용한 NATM이 주를 이루고 있다. 그러나 NATM은 터널내부에 설치되는 내부라이닝의 여러 가지 문제점을 내포하고 있기 때문에 노르웨이에서는 조립식 터널 라이닝(Pre-Cast Concrete Lining, PCL)을 개발하여 현장타설 콘크리트 라이닝의 문제점을 해결하고자 하였다. 그러나 노르웨이와 같은 북유럽지역에서는 지진이 거의 발생되지 않고 있기 때문에 PCL공법 개발당시에 지진에 대한 영향을 고려하지 못하였다. 따라서 PCL공법을 국내에 도입하기 위해서는 먼저 지진에 대한 영향을 분석하여야 할 것으로 판단되므로 본 연구에서는 PCL공법 적용시 지진에 대한 안정성 평가 및 합리적 내진해석을 위한 연구를 수행하고자 하였다. PCL의 내진성능을 판단하기 위하여 먼저 국내에서 주로 많이 사용되고 있는 해석기법인 유사정적해석법과 응답스펙트럼해석법을 이용하여 분석하였으며 지반과 구조물의 상호작용에 대한 영향을 분석하기 위해 시간이력해석을 수행하여 터널심도별 PCL의 내진성능을 분석하였다. 이와 같은 방법으로 PCL의 내진해석을 수행한 결과, 부재에 발생된 응력이 허용응력 이내에서 발생되어 PCL의 내진성능을 확보된 것으로 판단된다. 또한 시간이력해석에 의한 지반-구조물 해석을 수행한 결과에 의하면 PCL의 내진성능을 확보하기 위한 터널의 최소 토피고가 터널직경에 2배 이상인 것으로 확인되었다. 또한 단순 구조물의 내진해석만으로는 PCL의 내진성능을 과소평가할 우려가 있는 것으로 나타났다.

• Polymer(Korea)
• /
• v.24 no.1
• /
• pp.128-132
• /
• 2000

The miscibility between poly(vinyl chloride) (PVC) and polycaprolactone (PCL)-polyamide block copolymer whose content of PCL block is 62.7 wt%, was studied by differential scanning calorimetry. The PCL segment in the block copolymer and PVC has the miscibility showing single glass transition temperature (T$_{g}$). The miscible PVC molecule inhibited the crystallization of PCL segment, making an amorphous homogeneous phase of PCL and PVC segments at high PVC content. The blends had rubber elasticity at the temperature range between the T$_{g}$ of amorphous homogeneous phase of PCL and PVC segments and the melting temperature of polyamide segment, when both phases coexist.ist.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.6 no.1
• /
• pp.61-70
• /
• 2004

Precast Concrete Lining (PCL) is invented in order to resolve the problem of the cast-in-place concrete lining in Norway, However PCL could not consider the effect of earthquake because an earthquake rarely occurs in the region of Northern Europe, Consequently, the analysis of the effect of earthquake on PCL should be made before introducing PCL to Korea. The purpose of this research is to evaluate the stability of tunnel applying PCL in the case of earthquake. To evaluate the seismic performance of PCL, we used shaking table apparatus by 1/5 scale down model. The result of this research is as shows that deep tunnells satisfied for Korea seismic design criteria.

• Proceedings of the KSME Conference
• /
• 2008.11a
• /
• pp.1692-1696
• /
• 2008

In this paper, we characterize the mechanical properties of PCL strand which is made by oscillating nozzle for tissue engineering scaffold. In order to increase the mechanical properties of the PCL strand, we designed an oscillating nozzle system for the 3D plotting system. First, we check the effect of the nozzle speed (3 to 8 mm/sec), frequency (0 or 300 Hz) and the oscillating amplitude (0 or 100 V) on the diameter of the PCL strand. Second, we observe the effect of the frequency (0, 100, 200 and 300 Hz) and the oscillating amplitude (0, 50 and 100 V) on the mechanical property of PCL strand. The mechanical properties and surface morphology of PCL strand made by oscillating nozzle are compared with the PCL strand made by normal nozzle using Nano-UTM and SEM.

• Journal of the Korean Arthroscopy Society
• /
• v.2 no.1
• /
• pp.1-3
• /
• 1998

The PCL reconstruction in chronic isolate PCL reconstruction was still controversy. 1) In isolate PCL deficient knee, functionally not so bad as like ACL deficient knee. 2) The result of the PCL reconstruction was not as good as ACL reconstruction. Therefore, isolate PCL injuries has been treated as nonoperatively. Hey Grovere, who was the first to attempt an intra-articular reconstruction of the PCL, utilized the semi-tendinous tendon other static procedures have been described in only a few cases with very limited follow-up. Dynamic procedures utilizing the medial head of the gastrocnemius has been reported by Hugston and Degenhardt, Kennedy and Grainger, and Insall and Hood. These procedures did not improve static stability. Dr Clancy, who was introduce the use of BPTB for the PCL reconstruction transtibial and femoral tunnel. From 1995, untill early 1990 PCL reconstruction was done as tend as placement of the isometric point. Physiometic placement of Anatomical placement of the femoral tunnel in PCL reconstruction were introduced in 1995. Tibial Inlay Technique was reported by Dr Berg in 1995. The main advantage of the tibial Inlay Technique was to avoid fraying of the graft at the posterior tibial tunnel orifice. In complete PCL ruptured and severely posterior unstable knee, dual femoral tunnel technique will be to get better result than one bundle technique. To achieve restoration of normal posterior laxity, it is critical to address the posterior as well as the posterolateral structures. Futher research is necessary to evaluate new surgical approches such as double-bundle reconstructions and tibial inlay techniques as well as improved techniques for capsular and collateral ligament injuries.