• Title/Summary/Keyword: PCH

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Effect of Conjugation of Mesogenic Core of Nematic Liquid Crystals for Polar Anchoring Strength on Rubbed Polyimide Films. (극각 방향의 결합강도와 표면질서도에 관한 네마틱 액정의 분자구조 변화의 효과)

  • 서대식;곽희로
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.265-268
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    • 1995
  • We have studied the effect of the mesogenic core of nematic liquid crystals (NLCs) for polar (out-of-plane tilt) anchoring strength and surface order parameter on rubbed polyimide (PI) films. The order of polar anchoring strength for NLCs on rubbed PI films is 5CB > PCH5 > CCH5. This order is the same for all rubbing strengths investigated. The surface order parameter for NLCs is 5CB > PCH-5 > CCH5 on rubbed PI films. From these results, we suggest that the polar anchoring strength is strongly related to the surface order parameter.

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A Case of Pulmonary Capillary Hemangiomatosis-Like Lesion Followed for Seven Years

  • Rhee, Chin-Kook;Yim, Nam-Yeol;Shim, So-Yeon;Kim, Hui-Jung
    • Tuberculosis and Respiratory Diseases
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    • v.70 no.3
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    • pp.242-246
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    • 2011
  • Pulmonary capillary hemangiomatosis (PCH) is a rare disease of unknown etiology that is characterized by nodules composed of infiltrating capillary blood vessels. Herein, we describe a case of a PCH-like lesion that was detected by chest computed tomography. Transthoracic needle aspiration resulted in life-threatening hemorrhage. The patient was followed for seven years. He remained in good health and a follow up image showed little interval change.

$[Ni(dppe)_2]$의 합성 및 구조 (Synthesis and Structure of $[Ni(dppe)_2] (dppe=Ph_2PCH_2CH_2PPh_2)$)

  • Kim, Wan -Sung;Lee, Ji-Hwa;Lee, Soon W.
    • Korean Journal of Crystallography
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    • v.11 no.2
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    • pp.80-83
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    • 2000
  • Compound [Ni(P(OEt)3)4] (1) reacted with bis(diphenylphosphino)ethane (Ph2PCH2CH2Ph2, dppe) to give bis(bis(diphenylphosphine)ethane)nickel(0), [Ni(dppe)2] (2). Compound 2 was characterized by spectroscopy (1H-and 31P{1H}-NMR) and X-ray crystallography. Crystallographic data for 2: monoclinic space group P21/n, a=9.826(1)Å, b=21.167(2)Å, c=21.425(2)Å, β=91.957(9)°, Z=4, R(wR2)=0.0377(0.0882).

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Formation and Properties of Dimethylamine Complexes of Palladium(II) Having trans Phosphorus Spanning Terdentate Ligands

  • 류상열;양웅강;김훈식;박순흠
    • Bulletin of the Korean Chemical Society
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    • v.18 no.11
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    • pp.1183-1185
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    • 1997
  • Dimethylamine complexes of palladium(Ⅱ) [(PCP)Pd(NHMe2)](OTf) (PCP = 2,6-(R2PCH2)2C6H3); R = Ph (1), R = Cy (2)), have been prepared from the reaction of (PCP)Pd(OTf) and dimethylamine. The complex 1 is stable both in solution and in the solid state, while 2 is stable only in solution in the presence of dimethylamine although the formation of 2 in solution is quantitative by NMR Spectroscopy. A solution NMR spectroscopic study shows that dimethylamine favors over carbon monoxide in the coordination sphere of palladium(Ⅱ) having rigid terdentate ligands. The complexes 1 and 2 in chlorinated solvents undergo a chlorine abstract reaction yielding Pd(2,6-(R2PCH2)2C6H3)Cl in the presence of a base such as dimethylamine and DABCO (diazabicyclooctane), in which a transient dimethylamido palladium(Ⅱ) species likely involves.

Radiation Exposure Evaluation Depending on Radiation Workers' Locations during Dental Radiography (치과방사선 검사 시 방사선작업종사자의 위치에 따른 방사선 노출 평가)

  • Jeong, Cheonsoo;Kim, Jiyoung
    • Journal of the Korean Society of Radiology
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    • v.9 no.7
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    • pp.433-438
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    • 2015
  • To evaluate the radiation exposure level based on radiation workers' locations in dental radiography, the radiation dose rate in the radiographic room, lead glass, and operation system was measured. To that end, various devices were used, such as a Standard(Max-GLS, Shinhung), a panorama (PCH-2500, Vatech), a cephalometric radiography (PCH-2500), and a cone beam CT (PHT-30LFO, Vatech), as well as a PM1405 equipment as a radiation meter. Radiography conditions were set the same as the factors used in the clinical setting. As the result, the cone beam CT turned out the highest with 98 uSv and the standard showed the lowest level with 0.4 uSv/h. The panorama was measured to be higher than the Cephalo due to its different focus mode. On the lead glass surface and in the operation stand, the oral radiography device, panoramic, and Cephalo all were measured below the recording level. However, the cone beam CT was measured to have the leakage dose. Thus, radiation involved workers should be equipped with appropriate protection tools and reduce radiography time as much as possible. In addition, the structure of the radiation chamber should be also designed efficiently. Dental radiography has continued to grow in recent years, so it is necessary take appropriate protection measures for patients and radiation workers.

Preparation and Structure of [1,2-Bis(diphenylphosphino)ethane](nitrato)(trifluoromethylsulfonato)platinum(II): [Pt(dppe)($NO_3$)($CF_3SO_3$)] ([1,2-Bis(diphenylphosphino)ethane](nitrato)(trifluoromethylsulfonato)platinum(II)의 합성 및 구조: [Pt(dppe)($NO_3$)($CF_3SO_3$)])

  • Huh, Hyun-Sue;Lee, Soon-W.
    • Korean Journal of Crystallography
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    • v.19 no.1
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    • pp.21-24
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    • 2008
  • The title complex [Pt(dppe)($NO_3$)($CF_3SO_3$)] (dppe=1,2-bis(diphenylphosphino)ethane, $Ph_2PCH_2CH_2PH_2$) was prepared by sequentially treating [Pt(dppe)$Cl_2$] with 1 equiv of $AgNO_3$ and 1 equiv AgOTf (OTf=$CF_3SO_3$). The Pt metal is coordinated by two phosphorous atoms of the dppe ligand, one oxygen atom of the nitrato ($NO^-_3$) ligand, and one oxygen atom of the triflato(trifluoromethylsulfonato, $OTf^-$) ligand. The coordination sphere of Pt metal can be described as a distorted square plane.

Fe-H…H-C Dihydrogen Bondings: Synthesis and Structure of trans-[FeH(NCSe)(dppe)2](dppe=Ph2 PCH2 CH2 PPh2 (Fe-H…H-C 이수소 결합: trans-[FeH(NCSe)(dppe)2](dppe=Ph2 PCH2 CH2 PPh2의 합성 및 구조)

  • Baek, Ji Yeong;Han, Won Seok;Lee, Sun Won
    • Journal of the Korean Chemical Society
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    • v.46 no.5
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    • pp.427-436
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    • 2002
  • Reaction of $trans-[FeHCl(dppe)_2]$ (1) with KSeCN led to the formation of $trans-[FeH(NCSe)(dppe)_2](2).$ Compound 2 $·CH_2Cl_2$ was structurally characterized by X-ray diffraction, in which the hydride ligand appears to be involved in the dihydrogen bonding of the type M-H${\cdot}$${\cdot}$${\cdot}$H-C.

Analysis of 1,4-Dioxane and Chlorohydrins in Food Additives by Purge & Trap GC (퍼지앤트랩-기체크로마토그래피(PT-GC)를 이용한 식품첨가물 중 1,4-디옥산 및 클로로히드린류 분석)

  • 조태용;신영민;반경녀;오세동;이창희;이영자;문병우
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.7
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    • pp.965-970
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    • 2003
  • This study has been performed to develope a method for the simultaneous determination of 1,4-dioxane (DOX), epichlorohydrin (EPC), propylene chlorohydrin (PCH), ethylene chlorohydrin (ECH) and 1,3-dichloro-2-pro-panol (DCP) in polysorbates, chloline chloride, choline bitartrate, modified starch and spices by purge and trapgas chromatography. Experimental design was used to select a suitable trap by measuring the limit of detection (LOD) and to investigate the effect of temperature and salt of extraction, and the percentage of recovery in various matrix. The LOD of DOX, EPC, PCH, ECH and DCP were 1.38$\mu\textrm{g}$, 0.23$\mu\textrm{g}$, 3.30$\mu\textrm{g}$, 3.97$\mu\textrm{g}$, 20.43$\mu\textrm{g}$ respectively, by means of using Vorcarb 3000 trap with 5$0^{\circ}C$ sample sparger. Excluding EPC, the recoveries of target compounds were above 90% in all matrix. Target compounds in polysorbates (17), choline chloride (5), choline bitartrate (5), modified starch (8) and spices (25) were not detected. But 2.5 ppm of DOX was detected in Tween 80.