• Title/Summary/Keyword: PB-22

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A Study on the Feasibility of Lead(II) Iodide and Gd2O2S:Tb Overlapping Sensors in Gamma Source Conditions using FLUKA Simulation (FLUKA 전산 모사를 통한 감마선원 조건에서의 요오드화납(II)과 Gd2O2S:Tb가 결합된 센서의 적용가능성 연구)

  • Yang, Seung-Woo;Park, Yoon-Hee;Park, Ji-Koon;Heo, Ye-Ji
    • Journal of the Korean Society of Radiology
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    • v.16 no.4
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    • pp.381-386
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    • 2022
  • Non-Destruction Test (NDT) is a method to check internal defects without destroying the product. Among them, radiographic testing (RT) uses high-energy radiation, so it is very important to prevent radiation exposure of workers. Therefore, in this study, in this study, a radiation sensor structure that improves radiation detection performance compared to the existing PbI2 and can immediately detect accidents in RT was presented. For evaluation, the conversion efficiency was analyzed in the gamma ray source through FLUKA simulation. PbI2 with overlapping Gd2O2S:Tb presented in this study showed a higher radiation sensitivity from 1.22 to 3.22 times than that of non-overlapping PbI2. This indicates that the presented sensor is suitable for use as a radiation sensor for source detection in RT.

Removal of Cu and Pb Ions from Aqueous Solution by Waste Citrus Peel-based Activated Carbon (폐감귤박으로 합성한 활성탄에 의한 수용액 중의 Cu 및 Pb 이온의 제거)

  • Moon, Myung-Jun;Kam, Sang-Kyu;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.27 no.6
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    • pp.401-410
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    • 2018
  • Waste citrus peel-based activated carbon (WCAC) was prepared from waste citrus peels by activation with KOH. The removal of Cu and Pb ions from aqueous solution by the prepared WCAC was investigated in batch experiments. The solution pH significantly influenced Cu and Pb adsorption capacity and the optimum pH was 4 to 6. The adsorption of Cu and Pb ions by WCAC followed pseudo-second-order kinetics and the Langmuir isotherm model. The maximum adsorption capacity calculated by Langmuir isotherm model was 31.91 mg/g for Cu and 92.22 mg/g for Pb. As the temperature was increased from 303 K to 323 K, the ${\Delta}G^{\circ}$ value decreased from -7.01 to -8.57 kJ/mol for Cu ions and from -0.87 to -2.06 kJ/mol for Pb ions. These results indicated that the adsorption of Cu and Pb by WCAC is a spontaneous process.

The assessment of the adsorption and movement of Pb in mixed soil with food compost using model (모델을 이용한 음식물퇴비 혼합토양에서의 Pb 흡착 및 이동성 평가)

  • Joo, You-Yoen;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.2
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    • pp.251-257
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    • 2008
  • Food compost, having a higher organic contents than soil, could be an alternative material to prevent the proliferation of heavy metals contamination in soil. In this study we used a convection-dispersion local equilibrium sorption model(CDE) and a two-site non-equilibrium sorption model to find the effects on the adsorption and transportation of Pb by mixing food compost with soil and we also tried to find the effect of velocity and concentration of the injected solution on the characteristics of Pb. We measured Pb concentrations in injection-liquid and in effluent, and then applied them to CXTFIT program. As a result of column experiments, some parameters(D, R, ${\beta}$, ${\omega}$) used in two-site non-equilibrium adsorption model were obtained. Characteristics of Pb adsorption and transport were analyzed using the parameters(D, R, ${\beta}$, ${\omega}$) obtained from the CXTFIT program, We could know that mixed soil with food compost showed a higher adsorption capacity from the retardation factor(R) calculated from the breakthrough curve(BTCs) of Pb. Rs of soil and mixed soil are 20.45, 37.45 respectively, indicating that the adsorption and the transportation characteristics could be accessed quantitatively by using of two-site non-equilibrium adsorption model.

Degradation Behavior of Solder Joint and Implementation Technology for Lead-free Automotive Electronics (자동차 전장제품의 무연솔더 적용기술 및 솔더 접합부 열화거동)

  • Hong, Won Sik;Oh, Chul Min
    • Journal of Welding and Joining
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    • v.31 no.3
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    • pp.22-30
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    • 2013
  • Due to ELV banning, automotive electronics cannot use four kinds of heavy metal element (Pb, Hg, Cd, $Cr^{6+}$) from 2016. Therefore, this study was focused on degradation characteristics of Sn-3.0Ag-0.5Cu Lead-free solder joint with OSP and ENIG finsh under various reliability assessment method, as like to thermal shock test and high temeprature/high humidity test with test duration for cabin electronics. Also, we compared bonding strength degradation to other advanced research results of electronic control unit for engine room because of difference service temperature with mount location in automotive. Whisker growth phenomenon and mitigation method which were essentially consideration items for Pb-free car electronics were examined. Conformal coating is a strong candidate for mitigating whisker growth in automotive electronics. Necessary condition to adapt Pb-free in car electronics was shown.

Distributions of Dissolved Pb and Cd in the Surface Water of East Sea, Korea (동해 표층수중 용존 Pb, Cd의 분포 특성)

  • Yoon, Sang Chol;Yoon, Yi Yong
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.18 no.2
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    • pp.64-73
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    • 2015
  • The distributions of Pb and Cd concentrations in the surface seawater of the East Sea were investigated during the R/V Lavrentyev cruise (July 2009) in which four transects from Russia shore to South were conducted to collect 26 surface water samples. The total dissolved concentrations of Pb and Cd were measured using ICP-MS (Perkin Elmer, DRC-e). In the coastal area, their concentrations of Russia shore (Pb, 0.08; Cd, 0.10 nM) were comparable for Cd but on the other hand, 6 times lower for Pb than Korea shore (Pb, 0.49; Cd, 0.11 nM). In the subregion, their concentrations of Warm region (Pb, 0.22; Cd, 0.01 nM) were about 1.7 times higher for Pb but 0.4 lower for Cd than Cold region (Pb, 0.13; Cd, 0.14 nM). The distributions of Pb and Cd concentrations were divided by lowest level at $10^{\circ}C$ of water temperature. Below $10^{\circ}C$, Pb and Cd concentrations increased when surface water temperatures decreased. Above $10^{\circ}C$, their concentrations increased with temperature, which showed highest concentrations in the Ulleung basin, directly influenced by flux from East Korean Warm Current and neighboring countrys (Korea and Japan). Specially, in the case of Pb, the concentrations decrease remarkablely with temperatures decrease from D10 directly influenced by flux from East Korean Warm Current, which shows highest Pb level. By comparing with other sea areas (Western Mediterranean, East Pacific), Pb concentrations in the East Sea were a little higher. The influence of East Korean Warm Current and neighboring countrys (Korea and Japan) may be relatively important. Therefore, the distribution of Cd may primarily be influenced by mixing of different water masses while the distribution of Pb may mainly be influenced by flux from East Korean Warm Current and atmospheric inputs. River inputs and interaction with particulate materials may also some roles for the distribution of these elements.

Detoxification Study with Different Dietary Protein Levels and Detoxifying Periods in Lead Poisoned Rats (납 중독된 흰쥐에서 식이 단백질 수준 및 제독기간에 따른 제독효과 비교 연구)

  • 김미경
    • Journal of Nutrition and Health
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    • v.22 no.3
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    • pp.185-193
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    • 1989
  • This study was performed to investigate lead(Pb) detoxification with different dietary protein levels and detoxifying periods in Pb poisoned rats. Forty nine male rats of Sprague-Dawley strain weighing 114$\pm$4g were used and they were fed 1% Pb-15% casein diet ad libitum for 2 weeks. After sacrifying 7 animals as control group, remaining forty two rats were blocked into 6 groups according to body weight. Three groups were fed each detoxifying diet(5%, 15% or 40% casein diet without Pb) for 1 week and the other 3 groups were fed same diets for 3 weeks. The results obtained were summerized as follows ; 1) Liver and kidney weight, bone weight, and bone length were increased with increasing dietary protein level and detoxifying period. 2) Hematocrit values were recovered to normal level during detoxifiying periods but hemoglobin contents in detoxifying diet groups showed no significant difference from those in control group. 3)Pb contents in blood were decreased with increasing dietary protein level, and Pb contents in liver were significantly decreased in high protein diet groups. Pb contents in kidney were significantly decreased during detoxifying period compared to control group, but no significant difference was shown within the detoxifying diet groups. Pb contents in femur were significantly decreased after 3 weeks of detoxifying period but no difference was shown with different dietary protein level. 4) Urinary Pb excretions were significantly increased with increasing dietary protein level. Fecal Pb excretions were remarkably decreased after 3 weeks of detoxifying period, but no difference was showen in fecal Pb excretions with different dietary protein level. Above results suggest that high protein diet improves Pb detoxification by increasing urinary Pb excretion.

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Chemical Preparation of $PbTiO_3$ Powder from Aqueous Solution (습식반응에 의한 $PbTiO_3$ 분말제조에 관한 연구)

  • 이경희;이병하;고영래
    • Journal of the Korean Ceramic Society
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    • v.22 no.2
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    • pp.39-43
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    • 1985
  • This study presents the results of an overall effort to detemine the applicability of the chemical wet process informing lead titanate electronic ceramics. Although pure lead titanate has not proven to be an important technological materials when prepared via conventional processing procedures this work is interesting as a study of chemical wet processing and a way of preparing pbTiO3 for study. The result obtained from this experiment were as follows ; Optimum synthesis condition which synthesize PbTiO3 by chemical wet process was obtained by firing at 50$0^{\circ}C$ after mixing $Pb(OH)_2$- gel and $Ti(OH)_4$ -gel at 7$0^{\circ}C$ for 4 hours.

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Effects of Some Heavy Metals(Al, Cd, Hg, and Pb) on ATP Content in Plant Leaves (식물엽의 ATP함량에 미치는 중금속(Al, Cd, Hg 및 Pb)의 영향)

  • 성민웅
    • Journal of Plant Biology
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    • v.22 no.4
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    • pp.107-113
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    • 1979
  • The present study was carried out to estimate the comparative effects of hydroponic heavy metals (Al, Cd, Hg, and Pb) on ATP content in plant leaves grown with Hoagland solution under green house condition. The two plants, kidneybean(Phaseolus vulgaris L.) and buckwheat(Fagopyrum esculentum M nch), showed similar inhibitory effect of heavy metals on ATP content in order of Hg, Cd, Pb, and Al. But the overall inhibitory effect was greater in kidneybean than in buckwheat. The affinity of heavy metals, in vitro, toward the enzyme (luciferin-luciferase) is in order of Hg, Al, Cd, and Pb, similar to that toward ATP. The results showed that the inhibitory effect of heavy metals on ATP hydrolysis is mainly due to the coordination of heavy metals with enzyme than ATP.

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The Change of Composition and the Throwing Power of Pb-Sn Alloy Electrodeposits in Pulse Plating (파형전류전해에 의한 Pb-Sn합금의 조성변화 및 균일전착력)

  • 예길촌;김용웅
    • Journal of the Korean institute of surface engineering
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    • v.22 no.4
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    • pp.197-206
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    • 1989
  • The Composition and throwing power-of Pb-Sn alloy deposits are investigated in tems of the pulse parameters in pulse plating. Microhardness and intermal srress of alloy deposots are measured. The current efficiency of pulse plating is lower than that of D.C.plating while cathode overpotential and macro-throwing power noticebly increase with increasing peak current density. The Pb content of P.C. plated alloy deposits with increasing average current density, is relatively lower than of D.C. plated deposits at the same average current density. The internal stress of Pb-Sn alloy is not detected and the microhardness are 9.0kg/mm2 and 11kg/mm2 for D.C. plated P.C. plated deposits, respectively.

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Composition and Microstrure of Pb-Sn Alloy Electrodeposit (Pb-Sn합금 전착층의 조성 및 조직특성)

  • 예길촌;조성제;김용응;김광수
    • Journal of the Korean institute of surface engineering
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    • v.22 no.4
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    • pp.168-178
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    • 1989
  • The compositions and microstructures of Pb-Sn alloy electrodeposits were investigated in terms of the electrolysis conditions conditions by using fluoborate bath. The Pb content of alloy deposit decreased with increasing dreasing current density until the limting content was obtained. The proferred orientation of Pb-phase in the alloy changed in the sequence of (110)longrightarrow(100)longrightarrow(100)+(110)(311)longrightarrowrandom distribution of crystals with increasing cathode overpotential, while that of $\beta$-Sn phase was (110)(301)(211)n mixed texture. The smooth surface with granular crystallites was obtained below medium current desity, while the rough surface texture was formed at high current density.

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