• Composites Research
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• 제31권6호
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• pp.385-391
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• 2018

본 연구에서는 oxi-PAN 섬유를 이용하여 각각의 온도와 각 온도에서의 섬유에 부가되는 장력을 조절하여 탄소섬유를 제조하고 단섬유 인장실험과 라만 분광분석을 수행하여 결과를 바탕으로 oxi-PAN 섬유의 탄화 조건에 따른 구조적 변화와 그에 따른 물성의 변화를 관찰하고자 하였다. 라만 분광분석을 통해 계산된 $I_D/I_G$ 측정값들은 탄소섬유의 탄성율과 동일한 변화양상을 보여주었으며 특히 탄화온도는 일반적으로 고온일수록 흑연구조가 발달하여 섬유의 탄성율이 증가하는 양상이 나타난다고 알려져 있으나 결과를 통해 분석한 바에 따르면 일정한 장력(${\geq}25MPa$) 이상에서만 그러한 결과가 관찰되는 것으로 나타났다. 이와는 대조적으로 인장강도의 경우 라만분광분석 결과와의 연관성을 찾을 수 없었으며 또한 부가되는 장력에 의해 증가혹은 감소하는 상반된 경향이 다양하게 나타나 특정 변수에 따른 영향을 판단하기 어려웠다. 따라서 본 연구의 결과를 통해 특히 고탄성율의 탄소섬유의 제조를 위한 oxi-PAN 섬유의 탄화 온도 최적화를 위해서는 최적의 섬유장력 조건 또한 중요하게 고려되어야 함을 알 수 있었다.

• 공업화학
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• 제18권5호
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• pp.467-474
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• 2007

팔라듐과 금 나노입자 등이 첨착된 높은 비표면적을 갖는 Polyacrylonitrile (PAN)계 활성탄소섬유(ACF: Activated Carbon Fiber)를 제조하였다. 여러 첨착 ACF에 대하여 BET, FE-SEM, TEM, XPS 등으로 비표면적과 기공부피, 미세구조, 시간에 따른 산소관능기의 표면변화를 관찰하였으며 $SO_2$에 대한 흡착성능을 연구하였다. 그 결과 첨착과정으로 인하여 총 기공부피 대비 미세기공 부피는 95.5%에서 30.5~43.7%로 대부분 감소하였으며, 산소관능기의 표면변화는 대기중에서 시간이 경과함에 따라 나노입자보다 금속염의 산소관능기 변화가 컸음을 알 수 있었다. 또한 Au 나노입자와 금속염을 첨착한 ACF의 $SO_2$ 파과시간은 무첨착 ACF에 비하여 크게 변하지 않았으나, 100 ppm의 Pd 나노입자를 첨착한 ACF는 $SO_2$ 파과시간이 880 s로 흡착성능이 우수하였다. 이러한 결과로 볼 때 $SO_2$ 흡착성능은 시간에 따른 산소관능기의 표면 변화와 연관성이 있다고 볼 수 있으며, PAN계 활성탄소섬유에 적정한 농도의 Pd 나노입자 첨착은 촉매작용으로 인하여 $SO_2$ 흡착 성능을 증가시키는 것으로 판단된다

• Korean Membrane Journal
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• 제9권1호
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• pp.1-11
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• 2007

To prepare chemically stable asymmetric microporous membranes with a hydrophilic surface, which would be expected to have better antifouling properties, poly(vinylidene fluoride) (PVDF) blend membranes were prepared by the phase inversion process. PVDF mixture solutions in N-methylpyrrolidone (NMP) blended with several polar potential ionic polymers such as polyacrylonitrile (PAN), poly(methylmethacrylate) (PMMA) and poly(N-isopropylacrylamide) (NIPAM) were used for the formation of the PVDF blend membranes. They were then characterized with several analytical methods such as FESEM, FTIR, contact angle measurement, pore size distribution and permeability measurement. Regardless of different polar polymers blended, they all showed a finger-like structure with more hydrophilic surface than the pristine PVDF membrane. For all the PVDF blend membrane, due to the polar potential ionic polymers used, the flux of those was improved. Especially the PVDF blend membrane with NIPAM showed the highest flux among the membranes prepared. Also antifouling property of the PVDF membrane was improved by the use of the polar polymers.

• 대한화학회지
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• 제55권5호
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• pp.819-823
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• 2011

The relationship between the microstructure, mechanical properties, and oxidation behavior of pitch-, polyacrylonitrile (PAN)-, and Rayon-based carbon fibers (CFs) has been studied in detail. Three types of carbon fiber were exposed to isothermal oxidation in air and the weight change was measured by thermogravimetric analyzer (TGA) apparatus. After activation energy was gained according to the conversion at reacting temperature, the value of specific surface area and the surface morphology was compared, and the reaction mechanism of oxidation affecting development of pores of carbon fibers was examined. This study will lead to a new insight into the relationship between the microstructure and mechanical properties of carbon fibers.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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• pp.1432-1435
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• 2006

We report on carbon nano-fibers (CNFs) for applying to epoxy as a highly thermal conductive adhesive. In order to fabricate CNFs, electro-spinning process was performed with polyacrylonitrile (PAN) solutions. The sample was stabilized at the annealing temperature of $360^{\circ}C$, and carbonized from 900 to $1100^{\circ}C$. It is shown that the synthesized CNFs have a good thermal conductivity of several hundred W/m K. LED backlight units (BLUs) fabricated with MPCB using CNF-mixed epoxy give a better heat dissipation and higher performance than normal LED BLUs. On the basis of SEM, XRD, and FTIR, the characteristics of CNFs are described.

• 한국염색가공학회지
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• 제14권2호
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• pp.109-109
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• 2002

A study has been made of the dry-jet-wet spinning of PAN copolymer fibers using 60% aqueous zinc chloride solution as solvent and 25∼40% aqueous zinc chloride solution as non-solvent. The technological characteristics of this method were that small streams of dope were extruded from the die and allowed to pass through a short distance of air gap(about 10mm) before entering the spinning bath for full coagulation. This work showed the importances which coagulation condition, stretch ratio and fiber tenacity up to 10.5 g/d could be obtained with elongation of 11∼16%. Individual fibers were evaluated on the basis of density and mechanical properties such as tenacity and elongation etc.

• 한국염색가공학회지
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• 제14권2호
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• pp.33-39
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• 2002

A study has been made of the dry-jet-wet spinning of PAN copolymer fibers using 60% aqueous zinc chloride solution as solvent and 25∼40% aqueous zinc chloride solution as non-solvent. The technological characteristics of this method were that small streams of dope were extruded from the die and allowed to pass through a short distance of air gap(about 10mm) before entering the spinning bath for full coagulation. This work showed the importances which coagulation condition, stretch ratio and fiber tenacity up to 10.5 g/d could be obtained with elongation of 11∼16%. Individual fibers were evaluated on the basis of density and mechanical properties such as tenacity and elongation etc.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2003년도 가을 학술발표회 논문집
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• pp.134-137
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• 2003

탄소섬유나 활성탄소섬유(activated carbon fiber, ACF)는 일반적으로 출발물질에 따라 polyacrylonitrile(PAN)계, 아크릴(acryl)계, 피치(pitch)계, 페놀(phenol)계 등으로 분류할 수 있다. 보통 습식, 용융 혹은 용융분사(melt-blown) 방사 방법에 의해 섬유 형태로 형성한 다음 산화성 가스 분위기에서 불융화 과정을 거쳐 열에 대한 안정성을 부여하여 불활성 분위기에서 탄소화하여 탄소섬유를 제조하거나, 수증기나 이산화 탄소와 같은 산화성 분위기에서 활성화하여 활성탄소섬유를 제조한다. (중략)

• Carbon letters
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• 제11권4호
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• pp.304-310
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• 2010

To manufacture a carbon/carbon composite the coal tar pitch was used as the matrix precursor and the PAN (polyacrylonitrile)-based carbon fiber was used as the reinforcing material to weave 3-directional preform. For pressure carbonization HIP equipment was used to produce a maximum temperature of $1000^{\circ}C$ and a maximum pressure of 100 MPa. The carbonization was induced by altering the dwell temperature between $250^{\circ}C$ and $420^{\circ}C$, which is an ideal temperature for the moderate growth of the mesophase nucleus that forms within the molten pitch during the pressure carbonization process. The application of high pressure during the carbonization process inhibits the mesophase growth and leads to the formation of spherical carbon particles that are approximately 30 nm in size. Most particles were spherical, but some particles were irregularly shaped. The spread of the carbon particles was larger on the surface of the carbon fiber than in the interior of the matrix pocket.

• Journal of Industrial and Engineering Chemistry
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• 제68권
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• pp.140-145
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• 2018

Bulky carbon layer uniformly distributed with nanoscale $Fe_2O_3$ was prepared via a direct carbonation of $Fe^{3+}$-polyacrylonitrile complexes at $700^{\circ}C$ under $N_2$ flow. The iron oxide carbon composites exhibited an excellent cycling performance for lithium storage with a reversible capacity of ${\sim}810mAh\;g^{-1}$ after 250 cycles at a current rate of $100mA\;g^{-1}$. The enhancement was mainly attributed to dual functions of bulky carbon layer which facilitated the lithium-ion diffusion and accommodated the volume changes of active $Fe_2O_3$ during charge/discharge process. Our novel chemical strategy is quite effective for scalable fabrication of high capacity lithium-storage materials.