• Title/Summary/Keyword: PAH formation

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NEAR-INFRARED PAH FEATURES IN GALACTIC PLANETARY NEBULAE

  • Ohsawa, R.;Onaka, O.;Sakon, I.;Mori, T. I.;Kaneda, H.;Matsuura, M.
    • Publications of The Korean Astronomical Society
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    • v.32 no.1
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    • pp.87-91
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    • 2017
  • Polycyclic aromatic hydrocarbons (PAHs) are considered to be carriers of the unidentified infrared bands, which are ubiquitously observed in the Universe. PAHs are mainly formed around evolved carbon-rich stars and injected into interstellar space. Planetary nebulae (PNe), a late stage of low- and intermediate stellar mass evolution, are suitable objects to investigate the formation and evolution of PAHs. The shortest PAH feature is located in $3.3{\mu}m$, which is important to examine the excitation and size distribution of PAHs. While the number of samples had been limited before, the high sensitivity of AKARI /IRC has drastically increased the number of samples. We obtained the $2-5{\mu}m$ spectra of Galactic PNe with AKARI /IRC and compiled a near-infrared spectral catalog, containing 73 PNe. We investigate the detection rate and the evolution of the PAH features. The characteristics of the catalog are illustrated and the origin of the evolution of the PAH features is discussed.

The Interplay between Star Formation and AGN Activities : A Case Study of LQSONG

  • Kim, Ji Hoon;Im, Myungshin;Kim, Dohyeong
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.84.1-84.1
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    • 2012
  • One of the most intriguing questions regarding black hole (BH)-galaxy co-evolution picture is how the BH accretion, or active galactic nucleus (AGN) activity is linked to star formation (SF) activity. While it is suggested that AGN luminosity of quasars correlates with SF luminosity, it is still unclear how AGN activity is connected to SF activity based on host galaxy properties. Utilizing AKARI's unique slit-less spectroscopic capability and wavelength coverage, we probed star formation activity of several types of AGNs by measuring the PAH 3.3 ${\mu}m$ emission. First, we detected the PAH 3.3 ${\mu}m$ emission from seven out of 27 Seyfert type-1 galaxies at z~0.36. While these galaxies deviate significantly from the local Mbh-${\sigma}$ relation meaning their black holes proceed the host galaxies in terms of evolution, they appear to follow the correlation between nuclear SF and AGN activities of local Seyfert type-1 galaxies. This implies that SF and AGN activities are directly connected at the nuclear region for these Seyfert type-1 AGNs. We also obtained 2-5 ${\mu}m$ spectra for subsamples of Quasar Spectroscopic Observation in Near-infrared Grism (QSONG) which consists of reverberation-mapped AGNs and PG-QSOs. We detected the PAH 3.3 ${\mu}m$ emission from 16 out of 31 reverberation-mapped AGNs and 10 out of 49 PG-QSOs and measured their line strengths. We present the correlations between SF and AGN activities and discuss if there is any dependency of the correlations on properties of host galaxies, such as morphology, or the presence of radio jets.

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Role of Arbuscular Mycorrhizal Fungi in Phytoremediation of Soil Rhizosphere Spiked with Poly Aromatic Hydrocarbons

  • Gamal, H. Rabie
    • Mycobiology
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    • v.33 no.1
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    • pp.41-50
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    • 2005
  • Results from an innovative approach to improve remediation in the rhizosphere by encouraging healthy plant growth and thus enhancing microbial activity are reported. The effect of arbuscular mycorrhizal fungi (Am) on remediation efficacy of wheat, mungbean and eggplant grown in soil spiked with polyaromatic hydrocarbons (PAH) was assessed in a pot experiment. The results of this study showed that Am inoculation enhanced dissipation amount of PAHs in planted soil, plant uptake PAHs, dissipation amount of PAHs in planted versus unplanted spiked soil and loss of PAHs by the plant-promoted biodegradation. A number of parameters were monitored including plant shoot and root dry weight, plant tissue water content, plant chlorophyll, root lipid content, oxido-reductase enzyme activities in plant and soil rhizosphere and total microbial count in the rhizospheric soil. The observed physiological data indicate that plant growth and tolerance increased with Am, but reduced by PAH. This was reflected by levels of mycorrhizal root colonization which were higher for mungbean, moderate for wheat and low for eggplant. Levels of Am colonization increased on mungbean > wheat > eggplant. This is consistent with the efficacy of plant in dissipation of PAHs in spiked soil. Highly significant positive correlations were shown between of arbuscular formation in root segments (A)) and plant water content, root lipids, peroxidase, catalase polyphenol oxidase and total microbial count in soil rhizosphere as well as PAH dissipation in spiked soil. As consequence of the treatment with Am, the plants provide a greater sink for the contaminants since they are better able to survive and grow.

Development of a Novel Experimental Model for Nephrotoxicity Assessment Using Membrane Vesicles of Rabbit Renal Proximal Tubules (신장근위곡세뇨관 막소포를 이용한 신장독성 실험모델 개발)

  • 이영재;이창업;이문한;성하정;류판동
    • Journal of Food Hygiene and Safety
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    • v.8 no.4
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    • pp.195-204
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    • 1993
  • Basolateral and brush border membrane (BLM and BBM) vesicles of renal proximal tubules were prepared from adult male New Zealand White rabbits to evaluate as a potential model for assessment of nephrotoxicity. PAH uptakes using BLMV, glucose and leucine uptakes using BBMV were measured in the rabbits treated cephaloridine. In addition, urinalysis and histopathological studies were performed to investigate the correlationship with membrane vesicle uptakes. The results were as follows: (1) the activite of Na+, K+ -ATPase was enriched 12.3-fold in vasolateral memvrane vesicles (BLMV) and the specific activity of alkaline phosphatase in purified brush border memvrane vesicles (BBMV) was enriched 10.1-fold compared with each of microsomal homogenate. (2) In the uptake experiments, cephaloridine decreased initial and probenecid-sensitive PAH uptakes in BLMV. (3) Cephaloridine tested decreased initial and phlorizin-sensitive glucose uptakes in BBMV. (4) Cephaloridine tested decreased initial and Na+-dependent leucine uptakes in BBMV. (5) Cephaloridine tested significantly increased the urinary excretion of glucose and activity of ${\gamma}$-GTP. (6) Cephaloridine tested caused moderate necrotic changes in renal tubular cells and formation of urinary cast in the lumina of Henle's loop and collecting tubules besides the swelling of renal tubules.

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AKARI INFRARED CAMERA OBSERVATIONS OF THE 3.3 ㎛ PAH FEATURE IN Swift/BAT AGNs

  • Castro, Angel;Miyaji, Takamitsu;Shirahata, Mai;Ichikawa, Kohei;Oyabu, Shinki;Clark, David;Imanishi, Masatoshi;Nakagawa, Takao;Ueda, Yoshihiro
    • Publications of The Korean Astronomical Society
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    • v.32 no.1
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    • pp.197-199
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    • 2017
  • Using the InfraRed Camera (IRC) on board the infrared astronomical satellite AKARI we study the ${3.3{\mu}m}$ polycyclic aromatic hydrocarbon (PAH) feature and its connection to active galactic nucleus (AGN) properties for a sample of 54 hard X-ray selected bright AGN, including both Seyfert 1 and Seyfert 2 type objects. The sample is selected from the 9-month Swift/BAT survey in the 14-195 keV band and all of the sources have known neutral hydrogen column densities ($N_H$). The ${3.3{\mu}m}$ PAH luminosity ($L_{3.3{\mu}m}$) is used as a proxy for star-formation (SF) activity and hard X-ray luminosity ($L_{14-195keV}$) as an indicator of the AGN power. We explore for possible difference of SF activity between type 1 (un-absorbed) and type 2 (absorbed) AGN. We use several statistical analyses taking the upper-limits of the PAH lines into account utilizing survival analysis methods. The results of our log($L_{14-195keV}$) versus log($L_{3.3{\mu}m}$) regression shows a positive correlation and the slope for the type 1/unobscured AGN is steeper than that of type 2/obscured AGN at a $3{\sigma}$ level. Also our analysis shows that the circum-nuclear SF is more enhanced in type 2/absorbed AGN than type 1/un-absorbed AGN for low $L_{14-195keV}$ luminosity/low Eddington ratio AGN, while there is no significant dependence of SF activity on the AGN type in the high $L_{14-195keV}$ luminosities/Eddington ratios.

A COSMOLOGICAL PAH SURVEY WITH SPICA

  • Wada, Takehiko;Egami, Eiichi;Fujishiro, Naofumi;Goto, Tomotsugu;Imanishi, Masatoshi;Inami, Hanae;Ishihara, Daisuke;Kaneda, Hidehiro;Kohno, Kotaro;Koyama, Yusei;Matsuhara, Hideo;Matsuura, Shuji;Nagao, Tohru;Ohyama, Youichi;Onaka, Takashi;Oyabu, Shinki;Pearson, Chiris;Sakon, Itsuki;Takeuchi, Tsutomu T.;Tomita, Keisuke;Yamada, Toru;Yamagishi, Mitsuhosi
    • Publications of The Korean Astronomical Society
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    • v.32 no.1
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    • pp.317-319
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    • 2017
  • We propose a cosmological survey to probe star formation and nuclear activity in galaxies at redshifts of z=2-4 by polycyclic aromatic hydrocarbon (PAH) features using the SPICA mid-infrared instrument (SMI) with a spectral resolution of R=20. We will cover a wavelength range of $20-36{\mu}$ that corresponds to z=2-4 for the PAH features (11.3, 7.7, and $6.2{\mu}$). The sensitivity will be $1{\times}10^{-19}W/m^2(5{\sigma})$ in case of a reference survey that covers 4 arcmin2 field in a one-hour observation. It corresponds to $L_{IR}=2{\times}10^{11}L_{\odot}$ at z=3 and will give us more than 10000 galaxies in a 450 hour survey.

Soot Reduction in Diffusion Flames Using Dielectric Barrier Discharge (유전체 방전을 이용한 확산화염에서의 매연저감 특성)

  • Cha, Min-Suk;Kim, Kwan-Tae;Chung, Suk-Ho;Lee, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.27-32
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    • 2003
  • The effect of non-thermal plasma on diffusion flames in co-flow jets has been studied experimentally by adopting a dielectric barrier discharge technique. The generation of streamers was enhanced with a flame due to increased reduced electric fields by high temperature burnt gas and the abundance of ions in the flame region. The effect of streamers on flame behavior reveals that the flame length was significantly decreased as the applied voltage increased and the yellow luminosity by the radiation of soot particles was also significantly reduced. The formation of PAH and soot was influenced appreciably by the non-thermal plasma, while the flame temperature and the concentration of major species were not influence much with the plasma generation. The results demonstrated that the application of non-thermal plasma can be a viable technique in controlling soot generation in flames with low power consumption in the order of 1 W.

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Numerical Analysis for the Soot Formation Processes in Acetylene-Air Nonpremixed Turbulent Jet Flame (아세틸렌/공기 비예혼합 난류 제트화염의 Soot 생성에 대한 수치해석)

  • 김후중;김용모;윤명원
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.6
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    • pp.80-89
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    • 2002
  • The flame structure and soot formation in Acetylene-Air nonpremixed jet flame are numerically analyzed. We employed two variable approach to investigate the soot formation and oxidation processes. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of pyrene and acetylene. We also employed laminar flamelet model to calculate the thermo-chemical properties and the proper soot source terms from the information of detailed chemical kinetic model. The numerical and physical model used in this study successfully predict the essential features of the combustion processes and soot formation characteristics in the reaction flow field.

Influence of Roasting Conditions on Polycyclic Aromatic Hydrocarbon Contents in Ground Coffee Bean (원두커피의 로스팅 조건이 polycyclic aromatic hydrocarbons 생성에 미치는 영향)

  • Nam, He-Jung;Seo, Il-Won;Shin, Han-Seung
    • Korean Journal of Food Science and Technology
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    • v.41 no.4
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    • pp.362-368
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    • 2009
  • Roasting may lead to the formation of undesired compounds, such as polycyclic aromatic hydrocarbons (PAHs). In this study, green coffee beans were roasted under controlled conditions and the formation of PAHs during the roasting process was monitored. Roasting was performed in a hot air roaster, with an inlet air temperature varying from 150 to $250^{\circ}C$ for 5, 10, and 20 min. The PAH content of the roasted coffee was then evaluated by HPLC-FLD. The levels of total PAHs in Arabica (Colombia, Brazil) and Robusta (India) coffee samples were 1.26-215.07, 1.85-178.14, and 0.18-2.61 ${\mu}g$/kg, respectively.

Experimental Study on the Soot Formation Characteristics of Alkane-based Single Fuel Droplet (알케인계 단일 연료 액적의 Soot 생성 특성에 관한 실험적 연구)

  • Lim, Young Chan;Suh, Hyun Kyu
    • Journal of ILASS-Korea
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    • v.22 no.2
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    • pp.80-86
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    • 2017
  • The soot formation characteristics of various alkane-based single fuel droplets were studied in this work. Also, This study was performed to provide the database of the soot behavior and formation of alkane-based single fuel droplet. The experimental conditions were set to 1.0 atm of ambient pressure ($P_{amb}$), 21% of oxygen concentration ($O_2$) and 79% of nitrogen concentration ($N_2$). Combustion and soot formation of single fuel droplet was visualized by visualization system with high speed camera. At the same time, ambient pressure, oxygen concentration and nitrogen concentration were maintained by ambient condition control system. Soot formation characteristics was analyzed and compared on the basis of intensity ratio ($I/I_0$) of background image. The results of toluene fuel droplet showed the largest soot generation. Soot volume fraction ($f_v$) was almost the same under the identical fuel types regardless of various initial droplet diameter ($d_0$) since thermophoretic flux was not much changed under the same ambient conditions.